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nickel dioxide


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   b


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 6210 ± 240 gas Wu and Wang, 1997
Wu and Wang, 1997

State:   a


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

To = 3230 ± 160 gas Wu and Wang, 1997
Wu and Wang, 1997

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Sigmag+ 1 Sym. stretch 745 ± 30 gas PE Wu and Wang, 1997
Ramond, Davico, et al., 2002
1 Sym. stretch 749 T Ne IR Allouti, Manceron, et al., 2006
Piu 2 Bend 129.9 Ne IR Allouti, Manceron, et al., 2006
2 Bend 125.0 Ar IR Danset, Manceron, et al., 2001
Sigmau+ 3 Asym. stretch 967.7 Ne IR Allouti, Manceron, et al., 2006
3 Asym. stretch 954.9 Ar IR Citra, Chertihin, et al., 1997
Danset, Manceron, et al., 2001
3 Asym. stretch 959.5 N2 IR Citra, Chertihin, et al., 1997

Additional references: Jacox, 1998, page 177; Jacox, 2003, page 106

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu and Wang, 1997
Wu, H.; Wang, L.-S., A Study of Nickel Monoxide (NiO), Nickel Dioxide (NiO2) and Ni(O2) Complex by Anion Photoelectron Spectroscopy, J. Chem. Phys., 1997, 107, 1, 16, https://doi.org/10.1063/1.474362 . [all data]

Ramond, Davico, et al., 2002
Ramond, T.M.; Davico, G.E.; Hellberg, F.; Svedberg, F.; Salen, P.; Soderqvist, P.; Lineberger, W.C., Photoelectron Spectroscopy of Nickel, Palladium, and Platinum Oxide Anions, J. Mol. Spectrosc., 2002, 216, 1, 1, https://doi.org/10.1006/jmsp.2002.8669 . [all data]

Allouti, Manceron, et al., 2006
Allouti, F.; Manceron, L.; Alikhani, M.E., The Ni + O2 reaction: A combined IR matrix isolation and theoretical study of the formation and structure of NiO2, Phys. Chem. Chem. Phys., 2006, 8, 4, 448, https://doi.org/10.1039/b513038g . [all data]

Danset, Manceron, et al., 2001
Danset, D.; Manceron, L.; Andrews, L., Vibrational Spectra of Nickel and Platinum Dioxide Molecules Isolated in Solid Argon, J. Phys. Chem. A, 2001, 105, 30, 7205, https://doi.org/10.1021/jp010605x . [all data]

Citra, Chertihin, et al., 1997
Citra, A.; Chertihin, G.V.; Andrews, L.; Neurock, M., Reactions of Laser-Ablated Nickel Atoms with Dioxygen. Infrared Spectra and Density Functional Calculations of Nickel Oxides NiO, ONiO, Ni, J. Phys. Chem. A, 1997, 101, 17, 3109, https://doi.org/10.1021/jp970019x . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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