Anthracene

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas223. ± 10.kJ/molAVGN/AAverage of 6 values; Individual data points

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
41.3850.Dorofeeva O.V., 1988S(T) values calculated by [ Kudchadker S.A., 1979] are 3.6-4.1 J/mol*K greater than recommended ones. Cp(T) values from two calculations agree within 0.3 J/mol*K. Recommended values are also reproduced in the reference book [ Frenkel M., 1994].; GT
61.44100.
87.80150.
118.55200.
167.75273.15
184.7 ± 1.0298.15
185.99300.
249.74400.
302.90500.
345.39600.
379.33700.
406.84800.
429.48900.
448.321000.
464.171100.
477.581200.
489.011300.
498.801400.
507.221500.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid121. ± 10.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δcsolid-7061. ± 10.kJ/molAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
solid,1 bar207.15J/mol*KN/AGoursot, Girdhar, et al., 1970DH
solid,1 bar207.15J/mol*KN/AGoursot, Girdhar, et al., 1968DH
solid,1 bar207.5J/mol*KN/AHuffman, Parks, et al., 1931Extrapolation below 90 K, 14.98 cal/mol*K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
211.7298.15Radomska and Radomski, 1980T = 180 to 430 K. Data given graphically. Cp calculated from equation.; DH
210.50298.15Goursot, Girdhar, et al., 1970T = 5 to 500 K.; DH
210.50298.15Goursot, Girdhar, et al., 1968T = 5 to 520 K. Only 6 points given; summary article.; DH
217.5298.15Ueberreiter and Orthmann, 1950T = 293 to 368 K. Equation only.; DH
207.1297.2Huffman, Parks, et al., 1931T = 94 to 297 K. Value is unsmoothed experimental datum.; DH
221.8298.15Hildebrand, Duschak, et al., 1917T = 293 to 593 K. From heat content data.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil613.2KN/AWeast and Grasselli, 1989BS
Tboil613.0KN/ABuckingham and Donaghy, 1982BS
Tboil613.1KN/ABurriel, 1931Uncertainty assigned by TRC = 0.3 K; TRC
Tboil613.KN/AKirby, 1921Uncertainty assigned by TRC = 5. K; TRC
Quantity Value Units Method Reference Comment
Tfus490. ± 3.KAVGN/AAverage of 27 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple488.93KN/AGoursot, Girdhar, et al., 1970, 2Uncertainty assigned by TRC = 0.01 K; TRC
Quantity Value Units Method Reference Comment
Δvap78.5kJ/molCGCZhao, Unhannanant, et al., 2008AC
Δvap79.5 ± 1.2kJ/molGCHaftka, Parsons, et al., 2006Based on data from 413. - 473. K.; AC
Δvap79.1kJ/molCGCPuri, Chickos, et al., 2001AC
Δvap79.8kJ/molCGCChickos, Hesse, et al., 1998AC
Δvap79.6kJ/molCGCChickos, Hosseini, et al., 1995Based on data from 453. - 503. K.; AC
Quantity Value Units Method Reference Comment
Δsub98. ± 10.kJ/molAVGN/AAverage of 12 values; Individual data points

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
66.7498.N/ARojas and Orozco, 2003See also Hanshaw, Nutt, et al., 2008.; AC
72.4398.GCLei, Chankalal, et al., 2002Based on data from 323. - 473. K.; AC
69.7398.GCHinckley, Bidleman, et al., 1990Based on data from 343. - 453. K.; AC
58.6519.AStephenson and Malanowski, 1987Based on data from 504. - 615. K.; AC
62.1500.N/AKudchadker, Kudchadker, et al., 1979See also Hanshaw, Nutt, et al., 2008.; AC
59.2558.IMortimer and Murphy, 1923Based on data from 500. - 616. K.; AC
60.3515.IMortimer and Murphy, 1923Based on data from 500. - 616. K. See also Boublik, Fried, et al., 1984.; AC
59.6555.INELSON and SENSEMAN, 1922Based on data from 496. - 614. K.; AC
60.7511.INELSON and SENSEMAN, 1922Based on data from 496. - 614. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
496.4 - 613.84.729972759.53-30.753Mortimer and Murphy, 1923Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
97.9 ± 0.6320. - 355.MEOja, Chen, et al., 2009AC
98.4 ± 0.7320. - 350.MEOja, Chen, et al., 2009AC
97.6 ± 1.3369.MESiddiqi, Siddiqui, et al., 2009Based on data from 339. - 399. K.; AC
95.6 ± 1.2337.N/AChen, Oja, et al., 2006Based on data from 320. - 354. K.; AC
91.2338.GSGrayson and Fosbraey, 2006Based on data from 323. - 353. K.; AC
98.8 ± 0.4350.MERibeiro da Silva, Monte, et al., 2006Based on data from 340. - 360. K.; AC
102.5 ± 1.9358.MEVerevkin, 2004Based on data from 348. - 368. K.; AC
96. ± 6.283. - 323.LEMcEachern and Sandoval, 2001AC
94.5423. - 488.MEMEmmenegger and Piccand, 1999AC
102.5338. - 353.MEKloc and Laudise, 1998AC
100.0 ± 2.8341.MEOja and Suuberg, 1998Based on data from 318. - 363. K.; AC
99.7383.GSNass, Lenoir, et al., 1995Based on data from 313. - 453. K.; AC
102.6338.GSHansen and Eckert, 1986Based on data from 313. - 363. K.; AC
98.7346.GSRordorf, 1986Based on data from 318. - 373. K.; AC
94.3353. - 399.GSBender, Bieling, et al., 1983AC
91.8 ± 0.9303.GSSonnefeld, Zoller, et al., 1983Based on data from 283. - 323. K.; AC
94.8376.GSMacknick and Prausnitz, 1979Based on data from 358. - 393. K.; AC
98.8 ± 0.4363. - 448.HSADygdala, Stefanski, et al., 1977AC
97.2328. - 372.METaylor and Crookes, 1976AC
101.0 ± 0.5353. - 432.MEMalaspina, 1973AC
99.7393.CMalaspina, 1973AC
84.1290. - 358.ME,CWiedemann, 1972See also Beech and Lintonbon, 1971.; AC
98.49342.VKelley and Rice, 1964ALS
98.3 ± 2.1342. - 359.N/AKelley and Rice, 1964, 2See also Cox and Pilcher, 1970.; AC
90. ± 1.3337.TEBudurov, 1960Based on data from 327. - 346. K.; AC
103.4 ± 2.9303. - 373.N/AHoyer and Peperle, 1958See also Cox and Pilcher, 1970.; AC
103.3 ± 2.9303.VHoyer and Peperle, 1958, 2Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 102. kJ/mol; ALS
102.1 ± 2.1338. - 353.N/ABradley and Cleasby, 1953See also Cox and Pilcher, 1970.; AC
102.1346.N/ABradley and Cleasby, 1953, 2Based on data from 339. - 353. K.; AC
102.09338.7VBradley and Cleasby, 1953, 3ALS
98. ± 2.396. - 421.HSAStevens, 1953AC
97. ± 2.396.VStevens, 1953, 2ALS
92.0 ± 2.1364.MEInokuchi, Shiba, et al., 1952AC
90.4353.MEInokuchi, 1951AC
97.3 ± 1.2378. - 398.RGSears and Hopke, 1949AC
93.3 ± 4.2353.N/AWolf and Weghofer, 1938AC
93.3 ± 0.8353.VWolf and Weghofer, 1938, 2ALS

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
29.372488.93N/AGoursot, Girdhar, et al., 1970Note that table of smoothed values indicates Hm = 6485 J/mol and Sm = 251 J/mol*K.; DH
29.8492.DSCRojas and Orozco, 2003Based on data from 463. - 503. K.; AC
31.5491.DSCStoroniak, Krzyminski, et al., 2003AC
28.8489.4DSCLisicki and Jamróz, 2000AC
29.37488.9N/ADomalski and Hearing, 1996AC
28.830490.N/AUeberreiter and Orthmann, 1950DH
28.870489.7N/AHildebrand, Duschak, et al., 1917DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
60.07488.93Goursot, Girdhar, et al., 1970Note; DH
58.0490.Ueberreiter and Orthmann, 1950DH
59.0489.7Hildebrand, Duschak, et al., 1917DH

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
29.000490.6crystaline, IliquidRadomska and Radomski, 1980DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
59.1490.6crystaline, IliquidRadomska and Radomski, 1980DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C14H11+ + Anthracene = (C14H11+ • Anthracene)

By formula: C14H11+ + C14H10 = (C14H11+ • C14H10)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.352.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M

Anthracene photodimer = 2Anthracene

By formula: C28H20 = 2C14H10

Quantity Value Units Method Reference Comment
Δr-67.0kJ/molCmBendig, Buchwitz, et al., 1981liquid phase; solvent: Cyclohexane; Dimerization, see Bendig and Kreysig, 1981; ALS
Δr28.9 ± 6.1kJ/molCmDonati, Guarini, et al., 1981solid phase; ALS

C14H10+ + Anthracene = (C14H10+ • Anthracene)

By formula: C14H10+ + C14H10 = (C14H10+ • C14H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr68.6kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSMeot-Ner (Mautner), 1980gas phase; M

Maleic anhydride + Anthracene = Anthracene-maleic anhydride Diels-Alder adduct

By formula: C4H2O3 + C14H10 = C18H12O3

Quantity Value Units Method Reference Comment
Δr-93. ± 2.kJ/molCmKiselev, Mavrin, et al., 1982liquid phase; solvent: Benzene; ALS
Δr-93.7kJ/molEqkLenz, Hegedus, et al., 1982liquid phase; solvent: 1,2,4-C6H3Cl3; ALS

1,4-Dewar anthracene = Anthracene

By formula: C14H10 = C14H10

Quantity Value Units Method Reference Comment
Δr-324. ± 1.kJ/molEqkDreeskamp, Kapahnke, et al., 1988liquid phase; solvent: Heptane; Isomerization; ALS

Anthracene + 2,5-Furnadione, 3-(1-methylethyl)- = C21H18O3

By formula: C14H10 + C7H8O3 = C21H18O3

Quantity Value Units Method Reference Comment
Δr-87.5kJ/molEqkLenz, Hegedus, et al., 1982liquid phase; solvent: 1,2,4-C6H3Cl3; ALS

9,10-Dihydro-9,10-ethanoanthracene-11,11,12,12-tetracarbonitrile = Anthracene + Tetracyanoethylene

By formula: C20H10N4 = C14H10 + C6N4

Quantity Value Units Method Reference Comment
Δr40.5 ± 2.1kJ/molCmRogers, 1972solid phase; ALS

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference
15. XN/A
35.4000.XN/A
17. LN/A
1.4 MN/A
56. VN/A

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C14H10+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)7.439 ± 0.006eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)877.3kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity846.6kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
0.530 ± 0.020LPESAndo, Mitsui, et al., 2007B
0.5300 ± 0.0050LPESScheidt and Weinkauf, 1997B
0.60 ± 0.10TDEqHeinis, Chowdhury, et al., 1993ΔGea(343 K) = -13.2 kcal/mol; ΔSea = -1.1 eu.; B
0.660 ± 0.060ECDRuoff, Kadish, et al., 1995Revised data, work of Becker and Chen, 1966; B
0.570 ± 0.020ECDLyons, Morris, et al., 1968B
0.5560 ± 0.0080ECDBecker and Chen, 1966B
<0.481 ± 0.039ECDWojnarovits and Foldiak, 1981EA is an upper limit: Chen and Wentworth, 1989.; B
0.41998ECDWentworth and Becker, 1962B

Proton affinity at 298K

Proton affinity (kJ/mol) Reference Comment
869.4Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Gas basicity at 298K

Gas basicity (review) (kJ/mol) Reference Comment
842.7Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Ionization energy determinations

IE (eV) Method Reference Comment
7.439 ± 0.006LSHager and Wallace, 1988LL
7.47EIStahl and Maquin, 1984LBLHLM
7.43PEKlasinc, Kovac, et al., 1983LBLHLM
7.45 ± 0.05EQMautner(Meot-Ner), 1980LLK
7.47PEStreets and Williams, 1974LLK
7.47SKoch, Otto, et al., 1973LLK
7.40PIAihara and Inokuchi, 1973LLK
7.41 ± 0.05PEEland, 1972LLK
7.47 ± 0.01PEDewar and Goodman, 1972LLK
7.40PEClark, Brogli, et al., 1972LLK
7.47 ± 0.01PEBoschi, Murrell, et al., 1972LLK
7.41PERowland, 1971Unpublished result of J.H.D. Eland; LLK
7.414SKitagawa, 1968RDSH
7.5PIKitagawa, 1968RDSH
7.15SAngus and Morris, 1966RDSH
7.42CTSKuroda, 1964RDSH
7.2CTSFinch, 1964RDSH
7.43CTSBriegleb, 1964RDSH
7.40CTSKinoshita, 1962RDSH
7.4PITerenin, 1961RDSH
7.35CTSBriegleb, Czekalla, et al., 1961RDSH
7.37CTSBirks and Stifkin, 1961RDSH
7.55EIWacks and Dibeler, 1959RDSH
21.1EIWacks and Dibeler, 1959RDSH
7.4CTSFoster, 1959RDSH
7.4CTSBriegleb and Czekalla, 1959RDSH
7.23CTSMatsen, 1956RDSH
7.43 ± 0.03PEKlasinc, Kovac, et al., 1978Vertical value; LLK
7.41 ± 0.02PESchmidt, 1977Vertical value; LLK
7.41PEClar and Schmidt, 1976Vertical value; LLK
7.40PEJongsma, Vermeer, et al., 1975Vertical value; LLK
7.42 ± 0.02PEHush, Cheung, et al., 1975Vertical value; LLK
7.44 ± 0.03PEMarschner and Goetz, 1974Vertical value; LLK
7.40PESchafer, Schweig, et al., 1972Vertical value; LLK

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C14H10+ + Anthracene = (C14H10+ • Anthracene)

By formula: C14H10+ + C14H10 = (C14H10+ • C14H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr68.6kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSMeot-Ner (Mautner), 1980gas phase

C14H11+ + Anthracene = (C14H11+ • Anthracene)

By formula: C14H11+ + C14H10 = (C14H11+ • C14H10)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
26.352.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW- 132
NIST MS number 228201

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


UV/Visible spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Eugeny B. Stern, Antonina A. Goncharova, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Ferguson, Reeves, et al., 1957
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 1240
Instrument Beckman DU
Melting point 215
Boiling point 339.9

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dorofeeva O.V., 1988
Dorofeeva O.V., Thermodynamic Properties of Polycyclic Aromatic Hydrocarbons in the Gaseous Phase. Institute for High Temperatures, USSR Academy of Sciences, Preprint No.1-238 (in Russian), Moscow, 1988. [all data]

Kudchadker S.A., 1979
Kudchadker S.A., Chemical thermodynamic properties of anthracene and phenathrene, J. Chem. Thermodyn., 1979, 11, 1051-1059. [all data]

Frenkel M., 1994
Frenkel M., Thermodynamics of Organic Compounds in the Gas State, Vol. I, II, Thermodynamics Research Center, College Station, Texas, 1994, 1994. [all data]

Goursot, Girdhar, et al., 1970
Goursot, P.; Girdhar, H.L.; Westrum, E.F., Jr., Thermodynamics of polynuclear aromatic molecules. III. Heat capacities and enthalpies of fusion of anthracene, J. Phys. Chem., 1970, 74, 2538-2541. [all data]

Goursot, Girdhar, et al., 1968
Goursot, P.; Girdhar, H.L.; Westrum, E.F., Jr., Mesure de la capacite calorifique de l'anthracene de 5 a 520K, Compt. rend., 1968, C266, 949-950. [all data]

Huffman, Parks, et al., 1931
Huffman, H.M.; Parks, G.S.; Barmore, M., Thermal data on organic compounds. X. Further studies on the heat capacities, entropies and free energies of hydrocarbons, J. Am. Chem. Soc., 1931, 53, 3876-3888. [all data]

Radomska and Radomski, 1980
Radomska, M.; Radomski, R., Calorimetric studies of binary systems of 1,3,5-trinitrobenzene with naphthalene, anthracene, and carbazole. I. Phase transitions and heat capacities of the pure components and charge-transfer complexes, Thermochim. Acta, 1980, 40, 405-414. [all data]

Ueberreiter and Orthmann, 1950
Ueberreiter, K.; Orthmann, H.-J., Specifische Wärme, spezifisches Volumen, Temperatur- und Wärme-leittähigkeit einiger disubstituierter Benzole und polycyclischer Systeme, Z. Natursforsch. 5a, 1950, 101-108. [all data]

Hildebrand, Duschak, et al., 1917
Hildebrand, J.H.; Duschak, A.D.; Foster, A.H., and Beebe, C.W. The specific heats and heats of fusion of triphenylmethane, anthraquinone and anthracene, J. Am. Chem. Soc., 1917, 39, 2293-2297. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Burriel, 1931
Burriel, F., Physico-Chemical Study of Some Solid Organic Compounds at Ordinary Temperatures, and Their COrrelationo with Temperature, An. R. Soc. Esp. Fis. Quim., 1931, 29, 89. [all data]

Kirby, 1921
Kirby, W., Determination of the Melting and Boiling Points of Anthracene, Phenanthrene and Carbazole, J. Soc. Chem. Ind., London, Trans. Commun., 1921, 40, 274T. [all data]

Goursot, Girdhar, et al., 1970, 2
Goursot, P.; Girdhar, H.L.; Westrum, E.F., Thermodynamics of Polynuclear Aromatic Molecules III. Heat Capacities and Enthalpies of Fusion of Anthracene, J. Phys. Chem., 1970, 74, 2538. [all data]

Zhao, Unhannanant, et al., 2008
Zhao, Hui; Unhannanant, Patamaporn; Hanshaw, William; Chickos, James S., Enthalpies of Vaporization and Vapor Pressures of Some Deuterated Hydrocarbons. Liquid-Vapor Pressure Isotope Effects, J. Chem. Eng. Data, 2008, 53, 7, 1545-1556, https://doi.org/10.1021/je800091s . [all data]

Haftka, Parsons, et al., 2006
Haftka, Joris J.H.; Parsons, John R.; Govers, Harrie A.J., Supercooled liquid vapour pressures and related thermodynamic properties of polycyclic aromatic hydrocarbons determined by gas chromatography, Journal of Chromatography A, 2006, 1135, 1, 91-100, https://doi.org/10.1016/j.chroma.2006.09.050 . [all data]

Puri, Chickos, et al., 2001
Puri, Swati; Chickos, James S.; Welsh, William J., Determination of Vaporization Enthalpies of Polychlorinated Biphenyls by Correlation Gas Chromatography, Anal. Chem., 2001, 73, 7, 1480-1484, https://doi.org/10.1021/ac001246p . [all data]

Chickos, Hesse, et al., 1998
Chickos, James; Hesse, Donald; Hosseini, Sarah; Nichols, Gary; Webb, Paul, Sublimation enthalpies at 298.15K using correlation gas chromatography and differential scanning calorimetry measurements, Thermochimica Acta, 1998, 313, 2, 101-110, https://doi.org/10.1016/S0040-6031(97)00432-2 . [all data]

Chickos, Hosseini, et al., 1995
Chickos, James S.; Hosseini, Sarah; Hesse, Donald G., Determination of vaporization enthalpies of simple organic molecules by correlations of changes in gas chromatographic net retention times, Thermochimica Acta, 1995, 249, 41-62, https://doi.org/10.1016/0040-6031(95)90670-3 . [all data]

Rojas and Orozco, 2003
Rojas, Aarón; Orozco, Eulogio, Measurement of the enthalpies of vaporization and sublimation of solids aromatic hydrocarbons by differential scanning calorimetry, Thermochimica Acta, 2003, 405, 1, 93-107, https://doi.org/10.1016/S0040-6031(03)00139-4 . [all data]

Hanshaw, Nutt, et al., 2008
Hanshaw, William; Nutt, Marjorie; Chickos, James S., Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons, J. Chem. Eng. Data, 2008, 53, 8, 1903-1913, https://doi.org/10.1021/je800300x . [all data]

Lei, Chankalal, et al., 2002
Lei, Ying Duan; Chankalal, Raymond; Chan, Anita; Wania, Frank, Supercooled Liquid Vapor Pressures of the Polycyclic Aromatic Hydrocarbons, J. Chem. Eng. Data, 2002, 47, 4, 801-806, https://doi.org/10.1021/je0155148 . [all data]

Hinckley, Bidleman, et al., 1990
Hinckley, Daniel A.; Bidleman, Terry F.; Foreman, William T.; Tuschall, Jack R., Determination of vapor pressures for nonpolar and semipolar organic compounds from gas chromatograhic retention data, J. Chem. Eng. Data, 1990, 35, 3, 232-237, https://doi.org/10.1021/je00061a003 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kudchadker, Kudchadker, et al., 1979
Kudchadker, Shanti A.; Kudchadker, Arvind P.; Zwolinski, Bruno J., Chemical thermodynamic properties of anthracene and phenanthrene, The Journal of Chemical Thermodynamics, 1979, 11, 11, 1051-1059, https://doi.org/10.1016/0021-9614(79)90135-6 . [all data]

Mortimer and Murphy, 1923
Mortimer, F. Spencer.; Murphy, Ray v., The Vapor Pressures of Some Substances Found in Coal Tar., Ind. Eng. Chem., 1923, 15, 11, 1140-1142, https://doi.org/10.1021/ie50167a012 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

NELSON and SENSEMAN, 1922
NELSON, O.A.; SENSEMAN, C.E., Vapor Pressure Determinations on Naphthalene, Anthracene, Phecanthrene, and Anthraquinone between Their Melting and Boiling Points, J. Ind. Eng. Chem., 1922, 14, 1, 58-62, https://doi.org/10.1021/ie50145a028 . [all data]

Oja, Chen, et al., 2009
Oja, Vahur; Chen, Xu; Hajaligol, Mohammad R.; Chan, W. Geoffrey, Sublimation Thermodynamic Parameters for Cholesterol, Ergosterol, β-Sitosterol, and Stigmasterol, J. Chem. Eng. Data, 2009, 54, 3, 730-734, https://doi.org/10.1021/je800395m . [all data]

Siddiqi, Siddiqui, et al., 2009
Siddiqi, M. Aslam; Siddiqui, Rehan A.; Atakan, Burak, Thermal Stability, Sublimation Pressures, and Diffusion Coefficients of Anthracene, Pyrene, and Some Metal β-Diketonates, J. Chem. Eng. Data, 2009, 54, 10, 2795-2802, https://doi.org/10.1021/je9001653 . [all data]

Chen, Oja, et al., 2006
Chen, Xu; Oja, Vahur; Chan, W. Geoffrey; Hajaligol, Mohammad R., Vapor Pressure Characterization of Several Phenolics and Polyhydric Compounds by Knudsen Effusion Method, J. Chem. Eng. Data, 2006, 51, 2, 386-391, https://doi.org/10.1021/je050293h . [all data]

Grayson and Fosbraey, 2006
Grayson, B. Terence; Fosbraey, Lynda A., Determination of the vapour pressure of pesticides, Pestic. Sci., 2006, 13, 3, 269-278, https://doi.org/10.1002/ps.2780130308 . [all data]

Ribeiro da Silva, Monte, et al., 2006
Ribeiro da Silva, Manuel A.V.; Monte, Manuel J.S.; Santos, Luís M.N.B.F., The design, construction, and testing of a new Knudsen effusion apparatus, The Journal of Chemical Thermodynamics, 2006, 38, 6, 778-787, https://doi.org/10.1016/j.jct.2005.08.013 . [all data]

Verevkin, 2004
Verevkin, Sergey P., Vapor pressure measurements on fluorene and methyl-fluorenes, Fluid Phase Equilibria, 2004, 225, 145-152, https://doi.org/10.1016/j.fluid.2004.08.037 . [all data]

McEachern and Sandoval, 2001
McEachern, D.M.; Sandoval, O., A molecular flow evaporation apparatus for measuring vapour pressures and heats of sublimation of organic compounds, J. Phys. E: Sci. Instrum., 2001, 6, 2, 155-161, https://doi.org/10.1088/0022-3735/6/2/026 . [all data]

Emmenegger and Piccand, 1999
Emmenegger, F.; Piccand, M., Organometallics, 1999, 57, 1, 235-240, https://doi.org/10.1023/A:1010100531350 . [all data]

Kloc and Laudise, 1998
Kloc, Ch.; Laudise, R.A., Vapor pressures of organic semiconductors:, Journal of Crystal Growth, 1998, 193, 4, 563-571, https://doi.org/10.1016/S0022-0248(98)00467-9 . [all data]

Oja and Suuberg, 1998
Oja, Vahur; Suuberg, Eric M., Vapor Pressures and Enthalpies of Sublimation of Polycyclic Aromatic Hydrocarbons and Their Derivatives, J. Chem. Eng. Data, 1998, 43, 3, 486-492, https://doi.org/10.1021/je970222l . [all data]

Nass, Lenoir, et al., 1995
Nass, Karen; Lenoir, Dieter; Kettrup, Antonius, Calculation of the Thermodynamic Properties of Polycyclic Aromatic Hydrocarbons by an Incremental Procedure, Angew. Chem. Int. Ed. Engl., 1995, 34, 16, 1735-1736, https://doi.org/10.1002/anie.199517351 . [all data]

Hansen and Eckert, 1986
Hansen, Philip C.; Eckert, Charles A., An improved transpiration method for the measurement of very low vapor pressures, J. Chem. Eng. Data, 1986, 31, 1, 1-3, https://doi.org/10.1021/je00043a001 . [all data]

Rordorf, 1986
Rordorf, Berchtold F., Thermal properties of dioxins, furans and related compounds, Chemosphere, 1986, 15, 9-12, 1325-1332, https://doi.org/10.1016/0045-6535(86)90407-8 . [all data]

Bender, Bieling, et al., 1983
Bender, R.; Bieling, V.; Maurer, G., The vapour pressures of solids: anthracene, hydroquinone, and resorcinol, The Journal of Chemical Thermodynamics, 1983, 15, 6, 585-594, https://doi.org/10.1016/0021-9614(83)90058-7 . [all data]

Sonnefeld, Zoller, et al., 1983
Sonnefeld, W.J.; Zoller, W.H.; May, W.E., Dynamic coupled-column liquid-chromatographic determination of ambient-temperature vapor pressures of polynuclear aromatic hydrocarbons, Anal. Chem., 1983, 55, 2, 275-280, https://doi.org/10.1021/ac00253a022 . [all data]

Macknick and Prausnitz, 1979
Macknick, A. Brian; Prausnitz, John M., Vapor pressures of high-molecular-weight hydrocarbons, J. Chem. Eng. Data, 1979, 24, 3, 175-178, https://doi.org/10.1021/je60082a012 . [all data]

Dygdala, Stefanski, et al., 1977
Dygdala, R.S.; Stefanski, K.; Wonikowski, J., Bull. Acad. Pol. Sci., Ser. Sci., Math., Astron. Phys., 1977, 25, 439. [all data]

Taylor and Crookes, 1976
Taylor, John Watson; Crookes, Roy J., Vapour pressure and enthalpy of sublimation of 1,3,5,7-tetranitro-1,3,5,7-tetra-azacyclo-octane (HMX), J. Chem. Soc., Faraday Trans. 1, 1976, 72, 0, 723, https://doi.org/10.1039/f19767200723 . [all data]

Malaspina, 1973
Malaspina, L., Microcalorimetric determination of the enthalpy of sublimation of benzoic acid and anthracene, J. Chem. Phys., 1973, 59, 1, 387, https://doi.org/10.1063/1.1679817 . [all data]

Wiedemann, 1972
Wiedemann, H.G., Applications of thermogravimetry for vapor pressure determination, Thermochim. Acta, 1972, 355-366. [all data]

Beech and Lintonbon, 1971
Beech, Graham; Lintonbon, Roger M., The measurement of sublimation enthalpies by differential scanning calorimetry, Thermochimica Acta, 1971, 2, 1, 86-88, https://doi.org/10.1016/0040-6031(71)85027-X . [all data]

Kelley and Rice, 1964
Kelley, J.D.; Rice, F.O., The vapor pressures of some polynuclear aromatic hydrocarbons, J. Phys. Chem., 1964, 68, 3794. [all data]

Kelley and Rice, 1964, 2
Kelley, J. Daniel; Rice, Francis Owen, The Vapor Pressures of Some Polynuclear Aromatic Hydrocarbons 1, J. Phys. Chem., 1964, 68, 12, 3794-3796, https://doi.org/10.1021/j100794a043 . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]

Budurov, 1960
Budurov, S., Izv. Khim. Inst. Bulg. Akad. Nauk, 1960, 7, 281. [all data]

Hoyer and Peperle, 1958
Hoyer, H.; Peperle, W., Z. Elektrochem., 1958, 62, 61. [all data]

Hoyer and Peperle, 1958, 2
Hoyer, H.; Peperle, W., Dampfdrunkmessungen an organischen substanzen und ihre sublimationswarmen, Z. Electrochem., 1958, 62, 61-66. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Bradley and Cleasby, 1953
Bradley, R.S.; Cleasby, T.G., 346. The vapour pressure and lattice energy of hydrogen-bonded crystals. Part I. Oxamide, oxamic acid, and rubeanic acid, J. Chem. Soc., 1953, 1681, https://doi.org/10.1039/jr9530001681 . [all data]

Bradley and Cleasby, 1953, 2
Bradley, R.S.; Cleasby, T.G., 349. The vapour pressure and lattice energy of some aromatic ring compounds, J. Chem. Soc., 1953, 1690, https://doi.org/10.1039/jr9530001690 . [all data]

Bradley and Cleasby, 1953, 3
Bradley, R.S.; Cleasby, T.G., The vapour pressure and lattice energy of some aromatic ring compounds, J. Am. Chem. Soc., 1953, 1690-16. [all data]

Stevens, 1953
Stevens, B., 591. Vapour pressure and the heats of sublimation of anthracene and of 9: 10-diphenylanthracene, J. Chem. Soc., 1953, 2973, https://doi.org/10.1039/jr9530002973 . [all data]

Stevens, 1953, 2
Stevens, B., Vapour pressures and the heats of sublimation of anthracene and of 9:10-diphenylanthracene, J. Chem. Soc., 1953, 76, 2973-29. [all data]

Inokuchi, Shiba, et al., 1952
Inokuchi, Hiroo; Shiba, Sukekuni; Handa, Takashi; Akamatu, Hideo, Heats of Sublimation of Condensed Polynuclear Aromatic Hydrocarbons, Bull. Chem. Soc. Jpn., 1952, 25, 5, 299-302, https://doi.org/10.1246/bcsj.25.299 . [all data]

Inokuchi, 1951
Inokuchi, H., J. Chem. Soc. Jpn. Pure Chem. Sect., 1951, 72, 552. [all data]

Sears and Hopke, 1949
Sears, G.W.; Hopke, E.R., Vapor Pressures of Naphthalene, Anthracene and Hexachlorobenzene in a Low Pressure Region, J. Am. Chem. Soc., 1949, 71, 5, 1632-1634, https://doi.org/10.1021/ja01173a026 . [all data]

Wolf and Weghofer, 1938
Wolf, K.L.; Weghofer, H.Z., Z. Phys. Chem. Abt. B, 1938, 39, 194. [all data]

Wolf and Weghofer, 1938, 2
Wolf, K.L.; Weghofer, H., Uber sublimationswarmen, Z. Phys. Chem., 1938, 39, 194-208. [all data]

Storoniak, Krzyminski, et al., 2003
Storoniak, P.; Krzyminski, K.; Bouzyk, A.; Koval'chuk, E.P.; Blazejowski, J., Melting, volatilisation and crystal lattice enthalpies of acridin-9(10H)-ones, Journal of Thermal Analysis and Calorimetry, 2003, 74, 2, 443-450, https://doi.org/10.1023/B:JTAN.0000005179.91819.6d . [all data]

Lisicki and Jamróz, 2000
Lisicki, Zygmunt; Jamróz, Malgorzata E., (Solid + liquid) equilibria in (polynuclear aromatic+ tertiary amide) systems, The Journal of Chemical Thermodynamics, 2000, 32, 10, 1335-1353, https://doi.org/10.1006/jcht.2000.0685 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Meot-Ner (Mautner), 1980
Meot-Ner (Mautner), M., Dimer Cations of Polycyclic Aromatics: Experimental Bonding Energies and Resonance Stabilization, J. Phys. Chem., 1980, 84, 21, 2724, https://doi.org/10.1021/j100458a012 . [all data]

Bendig, Buchwitz, et al., 1981
Bendig, J.; Buchwitz, W.; Fischer, J.; Kreysig, D., Deactivation behavior of arenes and heteroarenes. XXXII. Effect of endo- and exocyclic substitution on the reversible dimerization behavior of anthracenes, J. Prakt. Chem., 1981, 323, 485-498. [all data]

Bendig and Kreysig, 1981
Bendig, J.; Kreysig, D., Deactivation behavior of arenes and heteroarenes. XXXI. A model of the reversible photodimerization of anthracene and 9-methylanthracene, J. Prakt. Chem., 1981, 323, 471-484. [all data]

Donati, Guarini, et al., 1981
Donati, D.; Guarini, G.G.T.; Sarti-Fantoni, P., Evaluation of the enthalpic change during the monomerization reaction of crystalline anthracene photodimer (AD), Mol. Cryst. Liq. Cryst., 1981, 69, 241-243. [all data]

Kiselev, Mavrin, et al., 1982
Kiselev, V.D.; Mavrin, G.V.; Konovalov, A.I., Thermodynamic principles of the occurrence of a Diels-Alder reaction in the presence of a Lewis acid, Zh. Org. Khim., 1982, 18, 2505-2510. [all data]

Lenz, Hegedus, et al., 1982
Lenz, T.G.; Hegedus, L.S.; Vaughan, J.D., Liquid phase thermochemical energy conversion systems - an application of Diels-Alder chemistry, Int. J. Energy Res., 1982, 6, 357-365. [all data]

Dreeskamp, Kapahnke, et al., 1988
Dreeskamp, H.; Kapahnke, P.; Tochtermann, W., Photo valence isomerization of sterically strained aromatic hydrocarbons: 8,9-dicarbethoxy[6]paracyclophane, Radiat. Phys. Chem., 1988, 32, 537-539. [all data]

Rogers, 1972
Rogers, F.E., Thermochemistry of the Diels-Alder reactions. II. Heat of addition of several dienes to tetracyanoethylene, J. Phys. Chem., 1972, 76, 106-109. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Ando, Mitsui, et al., 2007
Ando, N.; Mitsui, M.; Nakajima, A., Comprehensive photoelectron spectroscopic study of anionic clusters of anthracene and its alkyl derivatives: Electronic structures bridging molecules to bulk, J. Chem. Phys., 2007, 127, 23, 234305, https://doi.org/10.1063/1.2805185 . [all data]

Scheidt and Weinkauf, 1997
Scheidt, J.; Weinkauf, R., Photodetachment photoelectron spectroscopy of Mass Selected Anions: Anthracene and the Anthracene-H2O Cluster, Chem. Phys. Lett., 1997, 266, 1-2, 201, https://doi.org/10.1016/S0009-2614(96)01512-6 . [all data]

Heinis, Chowdhury, et al., 1993
Heinis, T.; Chowdhury, S.; Kebarle, P., Electron Affinities of Naphthalene, Anthracene and Substituted Naphthalenes and Anthracenes, Org. Mass Spectrom., 1993, 28, 4, 358, https://doi.org/10.1002/oms.1210280416 . [all data]

Ruoff, Kadish, et al., 1995
Ruoff, R.S.; Kadish, K.M.; Boulas, P.; Chen, E.C.M., The relationship between the electron affinities and half-wave reduction potentials of fullerenes, aromatic hydrocarbons, and metal complexes, J. Phys. Chem., 1995, 99, 21, 8843, https://doi.org/10.1021/j100021a060 . [all data]

Becker and Chen, 1966
Becker, R.S.; Chen, E., Extension of Electron Affinities and Ionization Potentials of Aromatic Hydrocarbons, J. Chem. Phys., 1966, 45, 7, 2403, https://doi.org/10.1063/1.1727954 . [all data]

Lyons, Morris, et al., 1968
Lyons, L.E.; Morris, G.C.; Warren, L.J., Electron Affinities and the Electron Capture Method for Aromatic Hydrocarbons, J. Phys. Chem., 1968, 72, 10, 3677, https://doi.org/10.1021/j100856a056 . [all data]

Wojnarovits and Foldiak, 1981
Wojnarovits, L.; Foldiak, G., Electron capture detection of aromatic hydrocarbons, J. Chromatogr. Sci., 1981, 206, 511. [all data]

Chen and Wentworth, 1989
Chen, E.C.M.; Wentworth, W.E., Experimental Determination of Electron Affinities of Organic Molecules, Mol. Cryst. Liq. Cryst., 1989, 171, 271. [all data]

Wentworth and Becker, 1962
Wentworth, W.E.; Becker, R.S., Potential Method for the Determination of Electron Affinities of Molecules: Application to Some Aromatic Hydrocarbons., J. Am. Chem. Soc., 1962, 84, 22, 4263, https://doi.org/10.1021/ja00881a014 . [all data]

Aue, Guidoni, et al., 2000
Aue, D.H.; Guidoni, M.; Betowski, L.D., Ab initio calculated gas-phase basicities of polynuclear aromatic hydrocarbons, Int. J. Mass Spectrom., 2000, 201, 283. [all data]

Hager and Wallace, 1988
Hager, J.W.; Wallace, S.C., Two-laser photoionization supersonic jet mass spectrometry of aromatic molecules, Anal. Chem., 1988, 60, 5. [all data]

Stahl and Maquin, 1984
Stahl, D.; Maquin, F., Charge-stripping mass spectrometry of molecular ions from polyacenes and molecular orbital theory, Chem. Phys. Lett., 1984, 108, 613. [all data]

Klasinc, Kovac, et al., 1983
Klasinc, L.; Kovac, B.; Gusten, H., Photoelectron spectra of acenes. Electronic structure and substituent effects, Pure Appl. Chem., 1983, 55, 289. [all data]

Mautner(Meot-Ner), 1980
Mautner(Meot-Ner), M., Ion thermochemistry of low volatility compounds in the gas phase. 3. Polycyclic aromatics: Ionization energies, proton, and hydrogen affinities. Extrapolations to graphite, J. Phys. Chem., 1980, 84, 2716. [all data]

Streets and Williams, 1974
Streets, D.G.; Williams, T.A., Photoelectron spectroscopy of 9,10-dihaloanthracenes, J. Electron Spectrosc. Relat. Phenom., 1974, 3, 71. [all data]

Koch, Otto, et al., 1973
Koch, E.E.; Otto, A.; Radler, K., The absorption spectrum of the anthracene molecule in the vacuum ultraviolet, Chem. Phys. Lett., 1973, 21, 501. [all data]

Aihara and Inokuchi, 1973
Aihara, J.; Inokuchi, H., Ionization potentials of anthracene, Chem. Lett., 1973, 421. [all data]

Eland, 1972
Eland, J.H.D., Photoelectron spectra and ionization potentials of aromatic hydrocarbons, Int. J. Mass Spectrom. Ion Phys., 1972, 9, 214. [all data]

Dewar and Goodman, 1972
Dewar, M.J.S.; Goodman, D.W., Photoelectron spectra of molecules. Part 5.--Polycyclic aromatic hydrocarbons, J. Chem. Soc. Faraday Trans. 2, 1972, 68, 1784. [all data]

Clark, Brogli, et al., 1972
Clark, P.A.; Brogli, F.; Heilbronner, E., The π-orbital energies of the acenes, Helv. Chim. Acta, 1972, 55, 1415. [all data]

Boschi, Murrell, et al., 1972
Boschi, R.; Murrell, J.N.; Schmidt, W., Photoelectron spectra of polycyclic aromatic hydrocarbons, Faraday Discuss. Chem. Soc., 1972, 54, 116. [all data]

Rowland, 1971
Rowland, C.G., Kinetic energy distributions of C12H8 fragment ions in the mass spectra of anthracene, phenanthrene and diphenylacetylene, Intern. J. Mass Spectrom. Ion Phys., 1971, 7, 79. [all data]

Kitagawa, 1968
Kitagawa, T., Absorption spectra and photoionization of polycyclic aromatics in vacuum ultraviolet region, J. Mol. Spectry., 1968, 26, 1. [all data]

Angus and Morris, 1966
Angus, J.A.; Morris, G.C., Ionization potential of the anthracene molecule from Rydberg absorption bands, J.Mol. Spectry., 1966, 21, 310. [all data]

Kuroda, 1964
Kuroda, H., Ionization potentials of polycyclic aromatic hydrocarbons, Nature, 1964, 201, 1214. [all data]

Finch, 1964
Finch, A.C.M., Charge-transfer spectra and the ionization energy of azulene, J. Chem. Soc., 1964, 2272. [all data]

Briegleb, 1964
Briegleb, G., Electron affinity of organic molecules, Angew. Chem. Intern. Ed., 1964, 3, 617. [all data]

Kinoshita, 1962
Kinoshita, M., The absorption spectra of the molecular complexes of aromatic compounds with p-bromanil, Bull. Chem. Soc. Japan, 1962, 35, 1609. [all data]

Terenin, 1961
Terenin, A., Charge transfer in organic solids, induced by light, Proc. Chem. Soc., London, 1961, 321. [all data]

Briegleb, Czekalla, et al., 1961
Briegleb, G.; Czekalla, J.; Reuss, G., Mesomeriemomente und Elektronenuberfuhrungsbanden von Elektronen-donator-akzeptor-komplexen des Chloranils und Tetracyanathylens mit aromatischen Kohlenwasserstoffen, Z. Phys. Chem. (Neue Folge), 1961, 30, 333. [all data]

Birks and Stifkin, 1961
Birks, J.B.; Stifkin, M.A., π-Electronic excitation and ionization energies of condensed ring aromatic hydrocarbons, Nature, 1961, 191, 761. [all data]

Wacks and Dibeler, 1959
Wacks, M.E.; Dibeler, V.H., Electron impact studies of aromatic hydrocarbons. I. Benzene, naphthalene, anthracene, and phenanthrene, J. Chem. Phys., 1959, 31, 1557. [all data]

Foster, 1959
Foster, R., Ionization potentials of electron donors, Nature (London), 1959, 183, 1253. [all data]

Briegleb and Czekalla, 1959
Briegleb, G.; Czekalla, J., Die Bestimmung von lonisierungsenergien aus den Spektren von Elektronenubergangskomplexen, Z.Elektrochem., 1959, 63, 6. [all data]

Matsen, 1956
Matsen, F.A., Electron affinities, methyl affinities, and ionization energies of condensed ring aromatic hydrocarbons, J. Chem. Phys., 1956, 24, 602. [all data]

Klasinc, Kovac, et al., 1978
Klasinc, L.; Kovac, B.; Schoof, S.; Gusten, H., Photoelectron spectroscopy of 9-substituted anthracenes, Croat. Chem. Acta., 1978, 51, 307. [all data]

Schmidt, 1977
Schmidt, W., Photoelectron spectra of polynuclear aromatics. V. Correlations with ultraviolet absorption spectra in the catacondensed series, J. Chem. Phys., 1977, 66, 828. [all data]

Clar and Schmidt, 1976
Clar, E.; Schmidt, W., Correlations between photoelectron and phosphorescence spectra of polycyclic hydrocarbons, Tetrahedron, 1976, 32, 2563. [all data]

Jongsma, Vermeer, et al., 1975
Jongsma, C.; Vermeer, H.; Bickelhaupt, F.; Schafer, W.; Schweig, A., 10-methyl-9-phosphaanthracene, Tetrahedron, 1975, 31, 2931. [all data]

Hush, Cheung, et al., 1975
Hush, N.S.; Cheung, A.S.; Hilton, P.R., Binding energies of π- and "lone pair"-levels in mono- and diaza-phenanthrenes and anthracenes: an He(I) photoelectron spectroscopic study, J. Electron Spectrosc. Relat. Phenom., 1975, 7, 385. [all data]

Marschner and Goetz, 1974
Marschner, F.; Goetz, H., Korrelation zwischen photoelektronen- und elektronen-spektren. II. Untersuchung aromatischer π-systeme mit modifizierten PPP-SCF-CI-parametern, Tetrahedron, 1974, 30, 3159. [all data]

Schafer, Schweig, et al., 1972
Schafer, W.; Schweig, A.; Bickelhaupt, F.; Vermeer, H., Photoelectron spectroscopy and conjugation. Direct proof of the unusual sequence of the two highest occupied π-molecular orbitals in the phosphorin (phosphabenzene) and the arsenin (arsabenzene) system, Angew. Chem. Int. Ed. Engl., 1972, 11, 924. [all data]

Ferguson, Reeves, et al., 1957
Ferguson, J.; Reeves, L.W.; Schneider, W.G., Vapor absorption spectra and oscillator strengths of naphthalene, anthracene, and pyrene, Can. J. Chem., 1957, 35, 1117-1123. [all data]


Notes

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