Benzenemethanol, α,α,4-trimethyl-


Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSCP-Sil PONA GBDB-5DB-5DB-Petro
Column length (m) 30.100.30.30.50.
Carrier gas HeHeHe  
Substrate      
Column diameter (mm) 0.250.250.250.220.2
Phase thickness (μm) 0.250.250.250.250.5
Tstart (C) 60.140.60.60.50.
Tend (C) 250.230.240.240.270.
Heat rate (K/min) 2.5.3.3.2.
Initial hold (min) 8.10. 2. 
Final hold (min) 30.25.   
I 1185.1172.1184.1183.1158.9
ReferenceBenkaci-Ali, Baaliouamer, et al., 2007Cunicao, Lopes, et al., 2007Flamini, Cioni, et al., 2007Martins, Santos, et al., 2007Pang T., Zhu S., et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-PetroHP-5Equity-5HP-5MSZB-5
Column length (m) 50.30.60.30.30.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.20.250.250.250.25
Phase thickness (μm) 0.50.251.0.250.25
Tstart (C) 50.50.40.60.50.
Tend (C) 270.250.260.280.250.
Heat rate (K/min) 2.4.5.4.3.
Initial hold (min)  4.1.5. 
Final hold (min)  10.15.  
I 1158.91183.1213.1182.1183.
ReferencePang T., Zhu S., et al., 2007Quijano, Salamanca, et al., 2007Rocha, Coelho, et al., 2007Saroglou, Marin, et al., 2007Simoniatto, Bonani, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSBP-1BP-15 % Phenyl methyl siloxaneDB-5
Column length (m) 30.50.50.25.30.
Carrier gas He HeHeN2
Substrate      
Column diameter (mm) 0.250.220.220.250.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 280.220.220.280.240.
Heat rate (K/min) 3.2.2.3.3.
Initial hold (min)     3.
Final hold (min)  20.20.20.5.
I 1183.1159.1156.1183.1182.
ReferenceVagionas, Ngassapa, et al., 2007Blanc, Bradesi, et al., 2006Boti, Bighelli, et al., 2006Djarri, Medjroubi, et al., 2006Dob, Dahmane, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5BP-1HP-5MSDB-1
Column length (m) 30.30.50.20.30.
Carrier gas N2N2He N2
Substrate      
Column diameter (mm) 0.250.250.220.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.50.
Tend (C) 240.220.220.240.220.
Heat rate (K/min) 3.5.2.5.4.
Initial hold (min) 3.10. 4. 
Final hold (min) 3. 20.15. 
I 1185.1187.1160.1186.1179.
ReferenceDob, Dahmane, et al., 2006, 2Flamini, Tebano, et al., 2006Gonny, Cavaleiro, et al., 2006Kallio, Jussila, et al., 2006Kuiate, Bessière, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1DB-1HP-5SPB-1HP-5MS
Column length (m) 30.30.25.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.250.250.20.25
Phase thickness (μm) 0.20.250.250.20.25
Tstart (C) 70.60.60.70.60.
Tend (C) 220.240.240.220.280.
Heat rate (K/min) 3.4.4.3.4.
Initial hold (min)     5.
Final hold (min) 15.  15. 
I 1158.1191.1183.1158.1180.
ReferencePinto, Pina-Vaz, et al., 2006Rezazadeh, Hamedani, et al., 2006Rezazadeh, Hamedani, et al., 2006Salgueiro L.R., Pinto E., et al., 2006Saroglou, Dorizas, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5SE-54RTX-1DB-1
Column length (m) 30.30.50.60.30.
Carrier gas HeHeH2 N2
Substrate      
Column diameter (mm) 0.250.250.250.220.32
Phase thickness (μm) 0.250.250.270.250.25
Tstart (C) 50.50.50.60.50.
Tend (C) 250.250.300.220.260.
Heat rate (K/min) 5.5.5.2.2.
Initial hold (min) 2.2.  3.
Final hold (min)    20.5.
I 1183.1183.1184.1162.1183.
ReferenceSu, Ho, et al., 2006Su, Ho, et al., 2006, 2Brantner, Pfeifhofer, et al., 2005Cozzani, Muselli, et al., 2005Dob, Berramdane, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1HP-5HP-5MSDB-5DB-5MS
Column length (m) 30.30.30.30.60.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.40.40.
Tend (C) 250.260.250.260.200.
Heat rate (K/min) 2.3.4.2.2.
Initial hold (min) 8. 2.5. 
Final hold (min)   20.20.20.
I 1164.1186.1183.1182.1199.
ReferenceDob, Dahmane, et al., 2005Javidnia, Miri, et al., 2005Pino, Mesa, et al., 2005Senatore, Napolitano, et al., 2005Seo and Baek, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1SE-54SPB-1SPB-1HP-5
Column length (m) 30.30.30.30.30.
Carrier gas N2HeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.20.25
Phase thickness (μm) 0.250.250.250.20.25
Tstart (C) 50.60.70.70.60.
Tend (C) 200.260.220.220.220.
Heat rate (K/min) 5.2.3.3.5.
Initial hold (min)  5.  10.
Final hold (min)   15.15. 
I 1170.1182.1158.1157.1185.
ReferenceTchoumbougnang, Zollo, et al., 2005Alma, Nitz, et al., 2004Antunes, Sevinate-Pinto, et al., 2004Cavaleiro, Salgueiro, et al., 2004Ceccarini, Macchia, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5DB-5BP-1HP-5MS
Column length (m) 30.30.30.50.30.
Carrier gas HeN2N2 He
Substrate      
Column diameter (mm) 0.250.250.250.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.50.
Tend (C) 280.240.240.220.250.
Heat rate (K/min) 3.3.3.2.3.
Initial hold (min)      
Final hold (min)    20. 
I 1180.1185.1184.1162.1188.
ReferenceChorianopoulos, Kalpoutzakis, et al., 2004Flamini, Cioni, et al., 2004Flamini, Cioni, et al., 2004Gonny, Bradesi, et al., 2004Salido, Valenzuela, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5BP-1Optima 5DB-5DB-5
Column length (m) 25.50.25.30.30.
Carrier gas HeHeHeN2He
Substrate      
Column diameter (mm) 0.20.220.250.250.25
Phase thickness (μm) 0.330.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 240.220.280.220.240.
Heat rate (K/min) 3.2.3.5.3.
Initial hold (min)    10. 
Final hold (min) 7.20.20.  
I 1182.1158.1182.1184.1185.
ReferenceSartoratto, Machado, et al., 2004Tam, Thuam, et al., 2004Vérité, Nacer, et al., 2004Bader, Caponi, et al., 2003Bader, Flamini, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5SPB-1RTX-1HP-5DB-1
Column length (m) 30.30.60.30.30.
Carrier gas N2HeHeN2He
Substrate      
Column diameter (mm) 0.250.20.220.250.25
Phase thickness (μm) 0.250.20.250.250.25
Tstart (C) 60.70.60.60.40.
Tend (C) 220.220.230.220.250.
Heat rate (K/min) 5.3.2.5.2.
Initial hold (min) 10.  10.5.
Final hold (min)  15.45. 20.
I 1185.1158.1157.1185.1152.
ReferenceCampeol, Flamini, et al., 2003Cavaleiro, Salgueiro, et al., 2003Cavalli, Tomi, et al., 2003Dural, Bagci, et al., 2003de Feo, Bruno, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5DB-5HP-5MSHP-5
Column length (m) 30.30.30.60.30.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.25 0.250.250.25
Tstart (C) 60.25.75.40.60.
Tend (C) 240.150.230.310.240.
Heat rate (K/min) 3.3.3.3.3.
Initial hold (min)  5.10.1. 
Final hold (min)   20.20. 
I 1185.1183.1180.1189.1185.
ReferenceFlamini, Luigi Cioni, et al., 2003Isidorov, Vinogorova, et al., 2003Jantan, Ling, et al., 2003Lalel, Singh, et al., 2003Macchioni, Cioni, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-1RTX-5HP-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.330.250.250.25
Tstart (C) 50.40.45.60.50.
Tend (C) 250.260.250.280.280.
Heat rate (K/min) 3.2.3.4.3.
Initial hold (min)  5.6.5.5.
Final hold (min)  20.   
I 1185.1184.1192.1182.1183.
ReferenceSalido, Altarejos, et al., 2003Senatore, Rigano, et al., 2003Shellie, Marriott, et al., 2003Skaltsa, Demetzos, et al., 2003Economakis, Skaltsa, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5RTX-5CP Sil 5 CBSPB-5CP Sil 5 CB
Column length (m) 30.30.25.30.50.
Carrier gas HeHeN2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.32
Phase thickness (μm) 0.250.250.250.250.4
Tstart (C) 60.45.60.60.60.
Tend (C) 260.300.280.250.280.
Heat rate (K/min) 4.3.4.4.3.
Initial hold (min)  6.6.2.10.
Final hold (min)  10. 20.60.
I 1183.1187.1158.1183.1158.
ReferenceJavidnia, Miri, et al., 2002Mondello, Zappia, et al., 2002Pino, Marbot, et al., 2002Pino, Marbot, et al., 2002, 2Pino, Marbot, et al., 2002, 3
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-5RTX-5HP-5BP-1HP-5MS
Column length (m) 30.30.30.50.30.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.250.250.250.220.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 45.45.60.60.50.
Tend (C) 250.250.380.220.250.
Heat rate (K/min) 3.3.3.2.3.
Initial hold (min) 6.6.   
Final hold (min)    20. 
I 1183.1190.1183.1158.1188.
ReferenceShellie, Mondello, et al., 2002Shellie, Mondello, et al., 2002Couladis, Tsortanidou, et al., 2001Rezzi, Cavaleiro, et al., 2001Salido, Altarejos, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5DB-1OV-1DB-5
Column length (m) 30.30.30.25.30.
Carrier gas HeHe  He
Substrate      
Column diameter (mm) 0.250.250.250.250.26
Phase thickness (μm) 0.250.250.250.30.25
Tstart (C) 60.50.50.50.50.
Tend (C) 280.280.220.200.225.
Heat rate (K/min) 4.4.3.3.2.
Initial hold (min) 5.5.3.1. 
Final hold (min)    20.20.
I 1182.1182.1163.1163.1181.
ReferenceSkaltsa, Mavrommati, et al., 2001Skaltsa, Lazari, et al., 2000Muselli, Hoi, et al., 1999Bicchi, Rubiolo, et al., 1998Sagrero-Nieves, Bartley, et al., 1997
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1Methyl SiliconeDB-1DB-5DB-5
Column length (m) 30.25.60.60.0.32
Carrier gas N2HeHeHeH2
Substrate      
Column diameter (mm) 0.320.20.320.321.
Phase thickness (μm) 0.250.30.251. 
Tstart (C) 150.40.40.40.30.
Tend (C) 280.200.280.220.180.
Heat rate (K/min) 3.2.2.3.1.5
Initial hold (min)   3. 5.
Final hold (min)   10.  
I 1159.1187.1169.1186.1181.
ReferenceCoen, Engel, et al., 1995Píry, Príbela, et al., 1995Adedeji, Hartman, et al., 1992Le Quere and Latrasse, 1990Guichard and Souty, 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillary
Active phase OV-1OV-1
Column length (m) 30.30.
Carrier gas HeHe
Substrate   
Column diameter (mm) 0.50.5
Phase thickness (μm) 0.80.8
Tstart (C) 40.40.
Tend (C) 220.220.
Heat rate (K/min) 2.2.
Initial hold (min)   
Final hold (min)   
I 1159.1162.
ReferenceDe Pooter, Omar, et al., 1985De Pooter, Omar, et al., 1985
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References