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Benzophenone

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas49.9 ± 3.0kJ/molCmSabbah and Laffitte, 1978 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-34.kJ/molCcbColomina, Cambeiro, et al., 1959ALS
Deltafsolid-33.kJ/molCcbSpringall and White, 1954ALS
Deltafsolid-32.3 ± 3.3kJ/molCcbParks, Mosley, et al., 1950Reanalyzed by Cox and Pilcher, 1970, Original value = -32.9 ± 0.02 kJ/mol; ALS
Deltafsolid-50.84kJ/molCcbLandrieu and Blatt, 1924ALS
Quantity Value Units Method Reference Comment
Deltacsolid-6508. ± 10.kJ/molAVGN/AAverage of 6 values; Individual data points

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
224.80300.DeKruif, Van Miltenburg, et al., 1983T = 80 to 345 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C13H10NaO (solution) + 0.5Dicobalt octacarbonyl (solution) = C4CoNaO4 (solution) + Benzophenone (solution)

By formula: C13H10NaO (solution) + 0.5C8Co2O8 (solution) = C4CoNaO4 (solution) + C13H10O (solution)

Quantity Value Units Method Reference Comment
Deltar-157. ± 11.kJ/molRSCKiss, Nolan, et al., 1994solvent: Tetrahydrofuran

Benzophenone (solution) + sodium (cr) = C13H10NaO (solution)

By formula: C13H10O (solution) + Na (cr) = C13H10NaO (solution)

Quantity Value Units Method Reference Comment
Deltar-161.1 ± 2.5kJ/molRSCKiss, Nolan, et al., 1994solvent: Tetrahydrofuran

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sabbah and Laffitte, 1978
Sabbah, R.; Laffitte, M., Etude thermodynamique de la molecule de benzophenone, Thermochim. Acta, 1978, 23, 196-198. [all data]

Colomina, Cambeiro, et al., 1959
Colomina, M.; Cambeiro, M.; Perez-Ossorio, R.; Latorre, C., Estudios acerca de calores de combustion II. Calores de combustion de benzofenona y sus p-alquilderivados, Ber. Bunsenges. Phys. Chem., 1959, 509-514. [all data]

Springall and White, 1954
Springall, H.D.; White, T.R., Heats of combustion and molecular structure. Part II. The mean bond energy term for the carbonyl system in certain ketones, J. Chem. Soc., 1954, 2765-27. [all data]

Parks, Mosley, et al., 1950
Parks, G.S.; Mosley, J.R.; Peterson, P.V., Jr., Heats of combustion and formation of some organic compounds containing oxygen, J. Chem. Phys., 1950, 18, 152. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Landrieu and Blatt, 1924
Landrieu, P.; Blatt, H., Thermochemical study of diphenylphenylethinylcarbinol and its derivatives, Bull. Soc. Chim. Fr., 1924, 35, 1424-1236. [all data]

DeKruif, Van Miltenburg, et al., 1983
DeKruif, C.G.; Van Miltenburg, J.C.; Blok, J.G., Molar heat capacities and vapour pressures of solid and liquid benzophenone, J. Chem. Thermodynam., 1983, 15, 129-136. [all data]

Kiss, Nolan, et al., 1994
Kiss, G.; Nolan, S.P.; Hoff, C.D., Inorg. Chim. Acta, 1994, 227, 285. [all data]


Notes

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