Tetra-tert-butoxy titanium


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap15.8 ± 0.79kcal/molSGBradley and Swanwick, 1958See also Bradley and Hillyer, 1966.

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
13.4401.AStephenson and Malanowski, 1987Based on data from 386. - 486. K.
15.0337.SGBradley and Swanwick, 1958Based on data from 322. - 388. K. See also Boublik, Fried, et al., 1984.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bradley and Swanwick, 1958
Bradley, D.C.; Swanwick, J.D., 650. Vapour pressures of metal alkoxides. Part I. Titanium tetra-tert.-butoxide and -amyloxide, J. Chem. Soc., 1958, 3207, https://doi.org/10.1039/jr9580003207 . [all data]

Bradley and Hillyer, 1966
Bradley, D.C.; Hillyer, M.J., Thermochemistry of metal alkoxides. Part 2.?Heats of formation of some titanium alkoxides, Trans. Faraday Soc., 1966, 62, 2374, https://doi.org/10.1039/tf9666202374 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]


Notes

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