C16-


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   (2) 2Πu


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 9100 ± 100 gas Ohara, Kasuya, et al., 2000

State:   (1) 2Πu


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 5800 ± 100 gas (1) 2Πu-X 1587 1725 Ohara, Kasuya, et al., 2000
To = 5784 ± 5 Ne (1) 2Πu-X 1658 1730 Freivogel, Fulara, et al., 1995
To = 5732 ± 2 Ar (1) 2Πu-X 1668 1745 Szczepanski, Fuller, et al., 2001


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Σg+ 8 245 ± 5 Ne AB Freivogel, Fulara, et al., 1995
8 263 ± 3 Ar AB Szczepanski, Fuller, et al., 2001

Additional references: Jacox, 1998, page 357; Jacox, 2003, page 385

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ohara, Kasuya, et al., 2000
Ohara, M.; Kasuya, D.; Shiromaru, H.; Achiba, Y., Resonance-Enhanced Multiphoton Electron Detachment (REMPED) Study of Carbon Anions up to C, J. Phys. Chem. A, 2000, 104, 38, 8622, https://doi.org/10.1021/jp0010637 . [all data]

Freivogel, Fulara, et al., 1995
Freivogel, P.; Fulara, J.; Jakobi, M.; Forney, D.; Maier, J.P., Electronic absorption spectra of linear carbon chains in neon matrices. II. C-2n, C2n, and C2nH, J. Chem. Phys., 1995, 103, 1, 54, https://doi.org/10.1063/1.469621 . [all data]

Szczepanski, Fuller, et al., 2001
Szczepanski, J.; Fuller, J.; Ekern, S.; Vala, M., Electronic absorption and resonance Raman spectra of large linear carbon clusters isolated in solid argon, Spectrochim. Acta A, 2001, 57, 4, 775, https://doi.org/10.1016/S1386-1425(00)00443-1 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]


Notes

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