C9-

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 29720 ± 80 gas Yang, Taylor, et al., 1988
Arnold, Bradforth, et al., 1991

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 34536 ± 24 Ne D-X 281 290 Forney, Grutter, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 3 983 ± 25 Ne AB Forney, Grutter, et al., 1997
4 474 ± 24 Ne AB Forney, Grutter, et al., 1997

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 29334 gas <
To = 29446 ± 17 Ne C-X 295 340 Forney, Grutter, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 2177 ± 19 Ne AB Forney, Grutter, et al., 1997
2 1666 ± 19 Ne AB Forney, Grutter, et al., 1997
4 435 ± 17 Ne AB Forney, Grutter, et al., 1997

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16462 gas B-X 530 608 Ohara, Shiromaru, et al., 1997
Tulej, Kirkwood, et al., 1998
Tulej, Kirkwood, et al., 1998, 2
To = 16468 ± 5 Ne B-X 528 608 Forney, Grutter, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 1991 gas MPD Tulej, Kirkwood, et al., 1998
Tulej, Kirkwood, et al., 1998, 2
1 2001 ± 6 Ne AB Forney, Grutter, et al., 1997

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 13068 gas Ohara, Shiromaru, et al., 1997
Tulej, Kirkwood, et al., 1998
Tulej, Kirkwood, et al., 1998, 2
To = 13082 ± 3 Ne Forney, Grutter, et al., 1997
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1200 ± 40 gas MPD Ohara, Shiromaru, et al., 1997

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σu+ 6 Asym. stretch 1692.6 Ne IR Freivogel, Grutter, et al., 1997
6 Asym. stretch 1686.7 Ar IR Szczepanski, Ekern, et al., 1997
Szczepanski, Hodyss, et al., 1998
7 Asym. stretch 1583.3 Ar IR Szczepanski, Ekern, et al., 1997
Szczepanski, Hodyss, et al., 1998

Additional references: Jacox, 1994, page 398; Jacox, 1998, page 352; Jacox, 2003, page 376

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yang, Taylor, et al., 1988
Yang, S.; Taylor, K.J.; Craycraft, M.J.; Conceicao, J.; Pettiette, C.L.; Cheshnovsky, O.; Smalley, R.E., UPS of 2--30-atom carbon clusters: Chains and rings, Chem. Phys. Lett., 1988, 144, 5-6, 431, https://doi.org/10.1016/0009-2614(88)87291-9 . [all data]

Arnold, Bradforth, et al., 1991
Arnold, D.W.; Bradforth, S.E.; Kitsopoulos, T.N.; Neumark, D.M., Vibrationally Resolved Spectra of C2-C11 by Anion Photoelectron Spectroscopy, J. Chem. Phys., 1991, 95, 12, 8753, https://doi.org/10.1063/1.461211 . [all data]

Forney, Grutter, et al., 1997
Forney, D.; Grutter, M.; Freivogel, P.; Maier, J.P., Electronic Absorption Spectra of Carbon Chain Anions (, J. Phys. Chem. A, 1997, 101, 29, 5292, https://doi.org/10.1021/jp970954k . [all data]

Ohara, Shiromaru, et al., 1997
Ohara, M.; Shiromaru, H.; Achiba, Y., Resonance-enhanced multiphoton electron detachment spectra of C[sub 7][sup -], C[sub 9][sup -], and C[sub 11][sup -], J. Chem. Phys., 1997, 106, 24, 9992, https://doi.org/10.1063/1.474074 . [all data]

Tulej, Kirkwood, et al., 1998
Tulej, M.; Kirkwood, D.A.; Maccaferri, G.; Dopfer, O.; Maier, J.P., Electronic spectra of linear carbon anions, Chem. Phys., 1998, 228, 1-3, 293, https://doi.org/10.1016/S0301-0104(97)00358-3 . [all data]

Tulej, Kirkwood, et al., 1998, 2
Tulej, M.; Kirkwood, D.A.; Pachkov, M.; Maier, J.P., Gas-Phase Electronic Transitions of Carbon Chain Anions Coinciding with Diffuse Interstellar Bands, Astrophys. J., 1998, 506, 1, L69, https://doi.org/10.1086/311637 . [all data]

Freivogel, Grutter, et al., 1997
Freivogel, P.; Grutter, M.; Forney, D.; Maier, J.P., Infrared bands of mass-selected carbon chains Cn (n = 8-12) and Cn- (n = 5-10, 12) in neon matrices, Chem. Phys., 1997, 216, 3, 401, https://doi.org/10.1016/S0301-0104(97)00038-4 . [all data]

Szczepanski, Ekern, et al., 1997
Szczepanski, J.; Ekern, S.; Vala, M., Vibrational Spectroscopy of Small Matrix-Isolated Linear Carbon Cluster Anions, J. Phys. Chem. A, 1997, 101, 10, 1841, https://doi.org/10.1021/jp963200z . [all data]

Szczepanski, Hodyss, et al., 1998
Szczepanski, J.; Hodyss, R.; Vala, M., Isotopic Infrared Absorption Study of C, J. Phys. Chem. A, 1998, 102, 43, 8300, https://doi.org/10.1021/jp982963e . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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