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Propanamide, N-methyl-

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Condensed phase thermochemistry data

Go To: Top, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-76.5 ± 0.2kcal/molCcbVasil'eva and Zhil'tsova, 1982ALS
Quantity Value Units Method Reference Comment
Deltacliquid-607.0 ± 0.2kcal/molCcbVasil'eva and Zhil'tsova, 1982ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
42.8298.15Konicek and Wadso, 1971DH

Phase change data

Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Deltavap15.9 ± 0.05kcal/molGSVerevkin, Emel'yanenko, et al., 2009Based on data from 307. - 371. K.; AC
Deltavap16.0 ± 0.31kcal/molEB,BGMorgan and Kopp, 1998Based on data from 368. - 473. K.; AC
Deltavap15.5 ± 0.07kcal/molCStarzewski, Wadso, et al., 1984AC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
419.20.12Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
15.3 ± 0.05339.GSVerevkin, Emel'yanenko, et al., 2009Based on data from 307. - 371. K.; AC
15.3 ± 0.07420.EB,BGMorgan and Kopp, 1998Based on data from 368. - 473. K.; AC
13.0376.N/ASchmelzer and Pusch, 1995Based on data from 361. - 414. K.; AC
13.0318.AStephenson and Malanowski, 1987Based on data from 303. - 363. K. See also Gopal and Rizvi, 1968.; AC
13.5 ± 0.05431.EBVasil'eva, 1983Based on data from 381. - 480. K. See also Verevkin, Emel'yanenko, et al., 2009.; AC
15.3 ± 0.05431.EBVasil'eva, 1983Based on data from 381. - 480. K. See also Verevkin, Emel'yanenko, et al., 2009.; AC

Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-2881
NIST MS number 231159

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References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vasil'eva and Zhil'tsova, 1982
Vasil'eva, T.F.; Zhil'tsova, E.N., Heat of combustion of two monomethylamides, Termodin. Organ. Soedin., 1982, 108-110. [all data]

Konicek and Wadso, 1971
Konicek, J.; Wadso, I., Thermochemical properties of some carboxylic acids, amines and N-substituted amides in aqueous solution, Acta Chem. Scand., 1971, 25, 1541-1551. [all data]

Verevkin, Emel'yanenko, et al., 2009
Verevkin, Sergey P.; Emel'yanenko, Vladimir N.; Toktonov, Alexey V.; Goodrich, Peter; Hardacre, Christopher, Thermochemistry of Ionic Liquid-Catalyzed Reactions: Theoretical and Experimental Study of the Beckmann Rearrangement---Kinetic or Thermodynamic Control? «8224», Ind. Eng. Chem. Res., 2009, 48, 22, 9809-9816, https://doi.org/10.1021/ie900633r . [all data]

Morgan and Kopp, 1998
Morgan, Kathleen M.; Kopp, Daniel A., Solvent effects on the stability of simple secondary amides «8224», J. Chem. Soc., Perkin Trans. 2, 1998, 12, 2759-2764, https://doi.org/10.1039/a802717j . [all data]

Starzewski, Wadso, et al., 1984
Starzewski, P.; Wadso, I.; Zielenkiewicz, W., Enthalpies of vaporization of some N-alkylamides at 298.15 K, J. Chem. Thermodyn., 1984, 16, 331-334. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Schmelzer and Pusch, 1995
Schmelzer, Jürgen; Pusch, Jens, Phase equilibria in binary systems containing N-monosubstituted amides and hydrocarbons, Fluid Phase Equilibria, 1995, 110, 1-2, 183-196, https://doi.org/10.1016/0378-3812(95)02753-2 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Gopal and Rizvi, 1968
Gopal, R.; Rizvi, S.A., J. Indian Chem. Soc., 1968, 45, 1, 13. [all data]

Vasil'eva, 1983
Vasil'eva, T.F., Vapor pressure of 3-methoxypropylamine and six substituted amides in Teplofiz Svoistva Uglevodororov Nefteprod, G.I. Cherednichenko, ed(s)., Ts NIIT Eneftekhim, Moscow, 1983, 85-94. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References