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Benzene, hexachloro-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-44.70kJ/molCcrPlatonov and Simulin, 1983 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-141.77kJ/molCcrPlatonov and Simulin, 1983ALS
Deltafsolid-127.6 ± 4.2kJ/molCcbSinke and Stull, 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -131. ± 4.2 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-2361.09kJ/molCcrPlatonov and Simulin, 1983ALS
Deltacsolid-2375.3 ± 4.2kJ/molCcbSinke and Stull, 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -2374.0 kJ/mol; ALS
Quantity Value Units Method Reference Comment
solid,1 bar260.24J/mol*KN/AHildenbrand, Kramer, et al., 1958DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
201.29298.15Hildenbrand, Kramer, et al., 1958T = 15 to 300 K.; DH
257.7299.8Andrews and Haworth, 1928T = 101 to 336 K. Value is unsmoothed experimental datum.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Platonov and Simulin, 1983
Platonov, V.A.; Simulin, Yu.N., Standard enthalpies of formation of 1,2,3-trichlorobenzene, 1,2,4,5-tetrachlorobenzene, and hexachlorobenzene, Russ. J. Phys. Chem. (Engl. Transl.), 1983, 57, 840-842. [all data]

Sinke and Stull, 1958
Sinke, G.C.; Stull, D.R., Heats of combustion of some organic compounds containing chlorine, J. Phys. Chem., 1958, 62, 397-401. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Hildenbrand, Kramer, et al., 1958
Hildenbrand, D.L.; Kramer, W.R.; Stull, D.R., The heat capacities of hexachlorobenzene and pentachlorophenol from 15 to 300K, J. Phys. Chem., 1958, 62, 958-959. [all data]

Andrews and Haworth, 1928
Andrews, D.H.; Haworth, E., An application of the rule of Dulong and Petit to molecules, J. Am. Chem. Soc., 1928, 50, 2998-3002. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References