Ethene, tetrafluoro-

• Formula: C₂F₄
• Molecular weight: 100.0150
• IUPAC Standard InChI: InChI=1S/C2F4/c3-1(4)2(5)6 Copy

  
• IUPAC Standard InChIKey: BFKJFAAPBSQJPD-UHFFFAOYSA-N Copy
• CAS Registry Number: 116-14-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Ethylene, tetrafluoro-; Perfluoroethene; Perfluoroethylene; Tetrafluoroethene; Tetrafluoroethylene; TFE; C2F4; Fluoroplast 4; Tetrafluorethylene; 1,1,2,2-Tetrafluoroethylene; Tetrafluorethene; Ethene, 1,1,2,2-tetrafluoro-
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• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • References
  • Notes
• Other data available:
  • Phase change data
  • Henry's Law data
  • Gas phase ion energetics data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Vibrational and/or electronic energy levels
  • Gas Chromatography
• Data at other public NIST sites:
  • Computational Chemistry Comparison and Benchmark Database
  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Gas Phase Heat Capacity (Shomate Equation)

C_p° = A + B*t + C*t² + D*t³ + E/t²
H° − H°_298.15= A*t + B*t²/2 + C*t³/3 + D*t⁴/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t²/2 + D*t³/3 − E/(2*t²) + G
    C_p = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  = C₂ClF₄^-

By formula: Cl^- + C₂F₄ = C₂ClF₄^-

 +  = C₂BrF₄^-

By formula: Br^- + C₂F₄ = C₂BrF₄^-

C₇CrF₄O₅ (g) =  (g) + C₅CrO₅ (g)

By formula: C₇CrF₄O₅ (g) = C₂F₄ (g) + C₅CrO₅ (g)

C₂ClF₄^- + 2 = C₄ClF₈^-

By formula: C₂ClF₄^- + 2C₂F₄ = C₄ClF₈^-

C₄ClF₈^- + 3 = C₆ClF₁₂^-

By formula: C₄ClF₈^- + 3C₂F₄ = C₆ClF₁₂^-

C₆ClF₁₂^- + 4 = C₈ClF₁₆^-

By formula: C₆ClF₁₂^- + 4C₂F₄ = C₈ClF₁₆^-

C₂BrF₄^- + 2 = C₄BrF₈^-

By formula: C₂BrF₄^- + 2C₂F₄ = C₄BrF₈^-

 +  =

By formula: HBr + C₂F₄ = C₂HBrF₄

=  + 

By formula: C₂F₄I₂ = C₂F₄ + I₂

 +  =

By formula: C₂F₄ + Cl₂ = C₂Cl₂F₄

 + 2 = 2 + 4

By formula: C₂F₄ + 2H₂ = 2C + 4HF

 +  =

By formula: C₂F₄ + Br₂ = C₂Br₂F₄

 + 4 = 4 + 2

By formula: C₂F₄ + 4Na = 4FNa + 2C

2 =  + 2

By formula: 2CHClF₂ = C₂F₄ + 2HCl

2 =

By formula: 2C₂F₄ = C₄F₈

 + 2 = 2

By formula: C₂F₄ + 2F₂ = 2CF₄

=  + 

By formula: C₂Br₂F₄ = C₂F₄ + Br₂

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Kolesov, Zenkov, et al., 1962
Kolesov, V.P.; Zenkov, I.D.; Skuratov, S.M., The standard enthalpy of formation of tetrafluoroethylene, Russ. J. Phys. Chem. (Engl. Transl.), 1962, 36, 45-47. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Neugebauer and Margrave, 1956
Neugebauer, C.A.; Margrave, J.L., The heats of formation of tetrafluoroethylene, tetrafluoromethane and 1,1-difluoroethylene, J. Phys. Chem., 1956, 60, 1318-1321. [all data]

Wartenberg and Schiefer, 1955
Wartenberg, H.V.; Schiefer, J., Bildungswarmen von fluor-chlor-kohlenstoff-verbindungen, Z. Anorg. Chem., 1955, 278, 326-332. [all data]

Kirkbride and Davidson, 1954
Kirkbride, F.W.; Davidson, F.G., Heats of formation of gaseous fluoro- and fluorochloro-carbons, Nature (London), 1954, 174, 79-80. [all data]

Furukawa, McCoskey, et al., 1953
Furukawa, G.T.; McCoskey, R.E.; Reilly, M.L., Heat capacity, heats of fusion and vaporization, and vapor pressure of tetrafluoroethylene, J. Res., 1953, NBS 51, 69-72. [all data]

Hiraoka, Mochizuki, et al., 2008
Hiraoka, K.; Mochizuki, N.; Wada, A.; Okada, H.; Ichikawa, T.; Asakawa, D.; Yazawa, I., Gas-phase ion/molecule reactions in C2F4, Int. J. Mass Spectrom., 2008, 272, 1, 22-28, https://doi.org/10.1016/j.ijms.2007.12.013 . [all data]

Curtiss, Raghavachari, et al., 7374
Curtiss, L.A.; Raghavachari, K.; Redfern, P.C.; Pople, J.A., Assesment of Gaussian-3 and density Functional Theories for a larger experimental test set, J. Chem. Phys. 112 (2000), 7374. [all data]

Wells, House, et al., 1994
Wells, J.R.; House, P.G.; Weitz, E., J. Phys. Chem., 1994, 98, 8343. [all data]

Lacher, Lea, et al., 1950
Lacher, J.R.; Lea, K.R.; Walden, C.H.; Olson, G.G.; Park, J.D., Reaction heats of organic fluorine compounds. III. The vapor phase heats of hydrobromination of some simple fluoroolefins, J. Am. Chem. Soc., 1950, 72, 3231-3234. [all data]

Wu, Pickard, et al., 1975
Wu, E.C.; Pickard, J.M.; Rodgers, A.S., Thermochemistry of the gas-phase reaction tetrafluoroethylene + iodine = 1,2-diiodoperfluoroethane. Heat of formation of 1,2-diiodoperfluoroethane and of iodoperfluoroethane, J. Phys. Chem., 1975, 79, 1078-1081. [all data]

Lacher, McKinley, et al., 1949
Lacher, J.R.; McKinley, J.J.; Snow, C.M.; Michel, L.; Nelson, G.; Park, J.D., Reaction heats of organic fluorine compounds. I. Apparatus and the heat of chlorination of tetrafluoroethylene, J. Am. Chem. Soc., 1949, 71, 1330-1334. [all data]

Lacher, Casali, et al., 1956
Lacher, J.R.; Casali, L.; Park, J.D., Reaction heats of organic halogen compounds V. The vapor phase bromination of tetrafluoroethylene and trifluorochloroethylene, J. Phys. Chem., 1956, 60, 608-610. [all data]

Edwards and Small, 1965
Edwards, J.W.; Small, P.A., Kinetics of the pyrolysis of chlorodifluoromethane, Ind. Eng. Chem. Fundam., 1965, 4, 396-400. [all data]

Atkinson and Trenwith, 1953
Atkinson, B.; Trenwith, A.B., 424. The thermal decomposition of tetrafluorethylene, J. Chem. Soc. London, 1953, 2082-2087. [all data]

Domalski and Armstrong, 1967
Domalski, E.S.; Armstrong, G.T., The heats of combustion of polytetrafluoroethylene (teflon) and graphite in elemental fluorine, J. Res. NBS, 1967, 71, 105-118. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References

• Symbols used in this document:
  

  Cp,liquid	Constant pressure heat capacity of liquid
  S°gas,1 bar	Entropy of gas at standard conditions (1 bar)
  S°liquid	Entropy of liquid at standard conditions
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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