Cyclobutane, octafluoro-

• Formula: C₄F₈
• Molecular weight: 200.0300
• IUPAC Standard InChI: InChI=1S/C4F8/c5-1(6)2(7,8)4(11,12)3(1,9)10 Copy

  
• IUPAC Standard InChIKey: BCCOBQSFUDVTJQ-UHFFFAOYSA-N Copy
• CAS Registry Number: 115-25-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Cyclooctafluorobutane; Freon C 318; Freon 318; FC-C 318; Octafluorocyclobutane; Perfluorocyclobutane; Propellant C 318; R C318; Halocarbon C-138; UN 1976; Cyclobutane, 1,1,2,2,3,3,4,4-octafluoro-
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• Information on this page:
  • Gas phase thermochemistry data
  • Phase change data
  • Henry's Law data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Gas Chromatography
  • Fluid Properties
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  • Gas Phase Kinetics Database
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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Entropy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Enthalpy of phase transition

Entropy of phase transition

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

k_H(T) = k°_H exp(d(ln(k_H))/d(1/T) ((1/T) - 1/(298.15 K)))
k°_H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(k_H))/d(1/T) = Temperature dependence constant (K)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C₄F₈⁺ (ion structure unspecified)

Electron affinity determinations

Appearance energy determinations

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Andreevskii and Antonova, 1982
Andreevskii, D.N.; Antonova, Z.A., Development of an increment scheme for calculating the thermodynamic properties of organic polyfluoro compounds, J. Appl. Chem. USSR, 1982, 55, 582-587. [all data]

Kolesov, Talakin, et al., 1968
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M., Enthalpy of formation of some specimens of amorphous carbon, Russ. J. Phys. Chem. (Engl. Transl.), 1968, 42, 1218-1220. [all data]

Kolesov, Talakin, et al., 1964
Kolesov, V.P.; Talakin, O.G.; Skuratov, S.M., Standard enthalpy of formation of perfluorocyclobutane, Russ. J. Phys. Chem. (Engl. Transl.), 1964, 38, 930-931. [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Krauss and Stephan, 1989
Krauss, R.; Stephan, K., Thermal Conductivity of Refrigerants in a Wide Range of Temperature and Pressure, J. Phys. Chem. Ref. Data, 1989, 18, 43. [all data]

Park, Benning, et al., 1947
Park, J.D.; Benning, A.F.; Downing, F.B.; Laucius, J.F.; McHarness, R.C., Synthesis of Tetrafluoroethylene. Pyrolysis of Monochlorodifluoromethane, Ind. Eng. Chem., 1947, 39, 343-8. [all data]

Furukawa, McCoskey, et al., 1954
Furukawa, G.T.; McCoskey, R.E.; Reilly, M.L., Heat capacity, heats of transitions, fusion, and vaporization, and vapor pressure of octafluorocyclobutane, J. RES. NATL. BUR. STAN., 1954, 52, 1, 11, https://doi.org/10.6028/jres.052.003 . [all data]

Mousa, Kay, et al., 1972
Mousa, A.H.N.; Kay, W.B.; Kreglewski, A., The critical constants of binary mixtures of certain perfluoro-compounds with alkanes, J. Chem. Thermodyn., 1972, 4, 301-11. [all data]

Douslin, Moore, et al., 1959
Douslin, D.R.; Moore, R.T.; Waddington, G., The pressure-volume-temperature properties of perfluorocyclobutane: equations of state, viral coefficients and intermolecular potential energy functions, J. Phys. Chem., 1959, 63, 1959. [all data]

Furukawa, McCoskey, et al., 1954, 2
Furukawa, G.T.; McCoskey, R.E.; Reilly, M.L., Heat capacity, heats of transitions, fusion and vaporization, and vapor pressure of octafluorocyclobutane, J. Res., 1954, NBS 52, 11-16. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kletskii and Petrik, 1967
Kletskii, A.V.; Petrik, L.E., Zh. Fiz. Khim., 1967, 41, 5, 1183. [all data]

Martin, 1962
Martin, J.J., Thermodynamic Properties of Perfluorocyclobutane., J. Chem. Eng. Data, 1962, 7, 1, 68-72, https://doi.org/10.1021/je60012a020 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Kletskii and Petric, 1967
Kletskii, A.B.; Petric, L.E., Dependence of Vapor Pressure of Perfluorocyclobutane, Zh. Fiz. Khim., 1967, 41, 1183-1184. [all data]

Miller, Freidman, et al., 2004
Miller, T.M.; Freidman, J.F.; Viggiano, A.A., Electron Attachment and detachment and the Electron Affinity of cyclo-C4F8, J. Chem. Phys., 2004, 120, 15, 7024-7028, https://doi.org/10.1063/1.1683082 . [all data]

Hiraoka, Mizuno, et al., 2002
Hiraoka, K.; Mizuno, T.; Eguchi, D.; Takao, K.; Iino, T.; Yamabe, S., Gas-phase ion/molecule reactions in octafluorocyclobutane, J. Chem. Phys., 2002, 116, 17, 7574-7582, https://doi.org/10.1063/1.1400787 . [all data]

Bopp, Roscioli, et al., 2007
Bopp, J.C.; Roscioli, J.R.; Johnson, M.A.; Miller, T.M.; Viggiano, A.A.; Villano, S.M.; Wren, S.W.; Lineberger, Spectroscopic characterization of the isolated SF6- and C4F8- anions: Observation of very long harmonic progressions in symmetric deformation modes upon photodetachment, J. Phys. Chem. A, 2007, 111, 7, 1214-1221, https://doi.org/10.1021/jp0665372 . [all data]

Miller, Morris, et al., 1994
Miller, T.M.; Morris, R.A.; Miller, A.E.S.; Viggiano, A.A.; Paulson, J.F., Observation of Thermal Electron Detachment from Cyclo-C4F8- in FALP Experiments, Int. J. Mass Spectrom. Ion Proc., 1994, 135, 2-3, 195, https://doi.org/10.1016/0168-1176(94)03999-2 . [all data]

Lifshitz, Tiernan, et al., 1973
Lifshitz, C.; Tiernan, T.O.; Hughes, B.M., Electron affinities from endothermic negative-ion charge transfer reactions. IV. SF₆, selected fluorocarbons, and other polyatomic molecules, J. Chem. Phys., 1973, 59, 3182. [all data]

Bibby and Carter, 1963
Bibby, M.M.; Carter, G., Ionization and dissociation in some fluorocarbon gases, J. Chem. Soc. Faraday Trans., 1963, 59, 2455. [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy
  EA	Electron affinity
  Pc	Critical pressure
  Tboil	Boiling point
  Tc	Critical temperature
  Tfus	Fusion (melting) point
  Ttriple	Triple point temperature
  Vc	Critical volume
  d(ln(kH))/d(1/T)	Temperature dependence parameter for Henry's Law constant
  k°H	Henry's Law constant at 298.15K
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔvapH	Enthalpy of vaporization
  ΔvapS	Entropy of vaporization

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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