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Dimethyl ether

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(CH5O+ bullet Methyl Alcohol) + Dimethyl ether = (CH5O+ bullet Dimethyl ether bullet Methyl Alcohol)

By formula: (CH5O+ bullet CH4O) + C2H6O = (CH5O+ bullet C2H6O bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar21.9kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
Deltar25.2cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ bullet 2Methyl Alcohol) + Dimethyl ether = (CH5O+ bullet Dimethyl ether bullet 2Methyl Alcohol)

By formula: (CH5O+ bullet 2CH4O) + C2H6O = (CH5O+ bullet C2H6O bullet 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar17.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
Deltar28.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ bullet 3Methyl Alcohol) + Dimethyl ether = (CH5O+ bullet Dimethyl ether bullet 3Methyl Alcohol)

By formula: (CH5O+ bullet 3CH4O) + C2H6O = (CH5O+ bullet C2H6O bullet 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar13.7kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
Deltar30.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

CH5O+ + Dimethyl ether = (CH5O+ bullet Dimethyl ether)

By formula: CH5O+ + C2H6O = (CH5O+ bullet C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar35.0kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M
Quantity Value Units Method Reference Comment
Deltar24.7cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M

CH6N+ + Dimethyl ether = (CH6N+ bullet Dimethyl ether)

By formula: CH6N+ + C2H6O = (CH6N+ bullet C2H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar21.5kcal/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.3cal/mol*KPHPMSMeot-Ner, 1984gas phase; M

(C2H7O+ bullet Methyl Alcohol) + Dimethyl ether = (C2H7O+ bullet Dimethyl ether bullet Methyl Alcohol)

By formula: (C2H7O+ bullet CH4O) + C2H6O = (C2H7O+ bullet C2H6O bullet CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar20.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar29.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 2Methyl Alcohol) + Dimethyl ether = (C2H7O+ bullet Dimethyl ether bullet 2Methyl Alcohol)

By formula: (C2H7O+ bullet 2CH4O) + C2H6O = (C2H7O+ bullet C2H6O bullet 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar16.6kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar31.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 3Methyl Alcohol) + Dimethyl ether = (C2H7O+ bullet Dimethyl ether bullet 3Methyl Alcohol)

By formula: (C2H7O+ bullet 3CH4O) + C2H6O = (C2H7O+ bullet C2H6O bullet 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar12.5kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar25.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C2H7O+ + Dimethyl ether = (C2H7O+ bullet Dimethyl ether)

By formula: C2H7O+ + C2H6O = (C2H7O+ bullet C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar32.0kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
Deltar30.7kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar31.9cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
Deltar29.6cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(C2H7O+ bullet Dimethyl ether) + Dimethyl ether = (C2H7O+ bullet 2Dimethyl ether)

By formula: (C2H7O+ bullet C2H6O) + C2H6O = (C2H7O+ bullet 2C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar10.1kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.9cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(C2H7O+ bullet Dimethyl ether bullet Water) + Dimethyl ether = (C2H7O+ bullet 2Dimethyl ether bullet Water)

By formula: (C2H7O+ bullet C2H6O bullet H2O) + C2H6O = (C2H7O+ bullet 2C2H6O bullet H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar16.8kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar26.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet Dimethyl ether bullet 2Water) + Dimethyl ether = (C2H7O+ bullet 2Dimethyl ether bullet 2Water)

By formula: (C2H7O+ bullet C2H6O bullet 2H2O) + C2H6O = (C2H7O+ bullet 2C2H6O bullet 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar15.8kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar36.5cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M

(C2H7O+ bullet 2Dimethyl ether bullet Water) + Dimethyl ether = (C2H7O+ bullet 3Dimethyl ether bullet Water)

By formula: (C2H7O+ bullet 2C2H6O bullet H2O) + C2H6O = (C2H7O+ bullet 3C2H6O bullet H2O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar21.7kcal/molPHPMSTholman, Tonner, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar41.6cal/mol*KPHPMSTholman, Tonner, et al., 1994gas phase; M

(C2H7O+ bullet Water) + Dimethyl ether = (C2H7O+ bullet Dimethyl ether bullet Water)

By formula: (C2H7O+ bullet H2O) + C2H6O = (C2H7O+ bullet C2H6O bullet H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar18.5kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar26.3cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 2Water) + Dimethyl ether = (C2H7O+ bullet Dimethyl ether bullet 2Water)

By formula: (C2H7O+ bullet 2H2O) + C2H6O = (C2H7O+ bullet C2H6O bullet 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar16.4kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar22.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 3Water) + Dimethyl ether = (C2H7O+ bullet Dimethyl ether bullet 3Water)

By formula: (C2H7O+ bullet 3H2O) + C2H6O = (C2H7O+ bullet C2H6O bullet 3H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar16.9kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar32.9cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C3H7O2+ + Dimethyl ether = (C3H7O2+ bullet Dimethyl ether)

By formula: C3H7O2+ + C2H6O = (C3H7O2+ bullet C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar30.2kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar28.8cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar21.6kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C4H9O2+ + Dimethyl ether = (C4H9O2+ bullet Dimethyl ether)

By formula: C4H9O2+ + C2H6O = (C4H9O2+ bullet C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
Deltar29.9kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar29.1cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar21.2kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C10H10Fe+ + Dimethyl ether = (C10H10Fe+ bullet Dimethyl ether)

By formula: C10H10Fe+ + C2H6O = (C10H10Fe+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar9.kcal/molPHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<; M
Quantity Value Units Method Reference Comment
Deltar20.cal/mol*KN/AMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.7250.PHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, «DELTA»rH<, DG<; M

Chlorine anion + Dimethyl ether = C2H6ClO-

By formula: Cl- + C2H6O = C2H6ClO-

Quantity Value Units Method Reference Comment
Deltar7.50 ± 0.40kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Deltar2.9 ± 1.0kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Cesium ion (1+) + Dimethyl ether = (Cesium ion (1+) bullet Dimethyl ether)

By formula: Cs+ + C2H6O = (Cs+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar13.6 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) bullet 2Dimethyl ether)

By formula: (Cs+ bullet C2H6O) + C2H6O = (Cs+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar11.2 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) bullet 3Dimethyl ether)

By formula: (Cs+ bullet 2C2H6O) + C2H6O = (Cs+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar9.6 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Copper ion (1+) + Dimethyl ether = (Copper ion (1+) bullet Dimethyl ether)

By formula: Cu+ + C2H6O = (Cu+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar44.2 ± 2.9kcal/molCIDTKoizumi, 2001RCD

(Copper ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Copper ion (1+) bullet 2Dimethyl ether)

By formula: (Cu+ bullet C2H6O) + C2H6O = (Cu+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar46.1 ± 1.9kcal/molCIDTKoizumi, 2001RCD

(Copper ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Copper ion (1+) bullet 3Dimethyl ether)

By formula: (Cu+ bullet 2C2H6O) + C2H6O = (Cu+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar13.1 ± 1.0kcal/molCIDTKoizumi, 2001RCD

(Copper ion (1+) bullet 3Dimethyl ether) + Dimethyl ether = (Copper ion (1+) bullet 4Dimethyl ether)

By formula: (Cu+ bullet 3C2H6O) + C2H6O = (Cu+ bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar10.8 ± 2.4kcal/molCIDTKoizumi, 2001RCD

Potassium ion (1+) + Dimethyl ether = (Potassium ion (1+) bullet Dimethyl ether)

By formula: K+ + C2H6O = (K+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar17.4 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar22.2kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Deltar20.8kcal/molHPMSDavidson and Kebarle, 1976, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.8cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M
Deltar24.8cal/mol*KHPMSDavidson and Kebarle, 1976, 2gas phase; M

(Potassium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) bullet 2Dimethyl ether)

By formula: (K+ bullet C2H6O) + C2H6O = (K+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar16.5 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) bullet 3Dimethyl ether)

By formula: (K+ bullet 2C2H6O) + C2H6O = (K+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar13.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) bullet 3Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) bullet 4Dimethyl ether)

By formula: (K+ bullet 3C2H6O) + C2H6O = (K+ bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar12.0 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) bullet Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar39.4 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar39.5kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Deltar39.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar27.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
Deltar31.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
39.4 (+2.5,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 2Dimethyl ether)

By formula: (Li+ bullet C2H6O) + C2H6O = (Li+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar28.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
31.1 (+0.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 3Dimethyl ether)

By formula: (Li+ bullet 2C2H6O) + C2H6O = (Li+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar21.3 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
26.3 (+1.4,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 4Dimethyl ether)

By formula: (Li+ bullet 3C2H6O) + C2H6O = (Li+ bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar16.3 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kcal/mol) T (K) Method Reference Comment
22.8 (+1.6,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Sodium ion (1+) + Dimethyl ether = (Sodium ion (1+) bullet Dimethyl ether)

By formula: Na+ + C2H6O = (Na+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar24.0 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
Deltar21.9 ± 1.1kcal/molCIDTArmentrout and Rodgers, 2000RCD
Deltar22.0 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar22.2 ± 1.2kcal/molCIDTMore, Ray, et al., 1997RCD

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
17.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
17.6298.CIDCMcMahon and Ohanessian, 2000RCD

(Sodium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) bullet 2Dimethyl ether)

By formula: (Na+ bullet C2H6O) + C2H6O = (Na+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar20. ± 2.kcal/molAVGN/AAverage of 7 values; Individual data points

(Sodium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) bullet 3Dimethyl ether)

By formula: (Na+ bullet 2C2H6O) + C2H6O = (Na+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar16.0 ± 1.2kcal/molCIDTMore, Ray, et al., 1997RCD

(Sodium ion (1+) bullet 3Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) bullet 4Dimethyl ether)

By formula: (Na+ bullet 3C2H6O) + C2H6O = (Na+ bullet 4C2H6O)

Quantity Value Units Method Reference Comment
Deltar14.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar13.9 ± 1.0kcal/molCIDTMore, Ray, et al., 1997RCD

Rubidium ion (1+) + Dimethyl ether = (Rubidium ion (1+) bullet Dimethyl ether)

By formula: Rb+ + C2H6O = (Rb+ bullet C2H6O)

Quantity Value Units Method Reference Comment
Deltar14.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) bullet 2Dimethyl ether)

By formula: (Rb+ bullet C2H6O) + C2H6O = (Rb+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
Deltar13.1 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) bullet 3Dimethyl ether)

By formula: (Rb+ bullet 2C2H6O) + C2H6O = (Rb+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
Deltar8.8 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Grimsrud, et al., 1974
Hiraoka, K.; Grimsrud, E.P.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Hydrogen Ion in Water - Dimethyl Ether and Methanol - Dimethyl Ether Mixtures, J. Am. Chem. Soc., 1974, 96, 11, 3359, https://doi.org/10.1021/ja00818a004 . [all data]

Meot-Ner, 1984
Meot-Ner, (Mautner)M., The Ionic Hydrogen Bond and Ion Solvation. 1. -NH+ O-, -NH+ N- and -OH+ O- Bonds. Correlations with Proton Affinity. Deviations Due to Structural Effects, J. Am. Chem. Soc., 1984, 106, 5, 1257, https://doi.org/10.1021/ja00317a015 . [all data]

Meot-Ner (Mautner) and Sieck, 1991
Meot-Ner (Mautner), M.; Sieck, L.W., Proton affinity ladders from variable-temperature equilibrium measurements. 1. A reevaluation of the upper proton affinity range, J. Am. Chem. Soc., 1991, 113, 12, 4448, https://doi.org/10.1021/ja00012a012 . [all data]

Grimsrud and Kebarle, 1973
Grimsrud, E.P.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Solvation of the Hydrogen Ion by Methanol, Dimethyl Ether and Water. Effect of Hydrogen Bonding, J. Am. Chem. Soc., 1973, 95, 24, 7939, https://doi.org/10.1021/ja00805a002 . [all data]

Tholman, Tonner, et al., 1994
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Notes

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