Mercury, chloromethyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
10.5PEBaidin, Chizhov, et al., 1981LLK
10.5PEBaidin, Chizhov, et al., 1981, 2LLK
11.3 ± 0.2EIGlockling, Irwin, et al., 1976LLK
11.5 ± 0.02EIGowenlock, Haynes, et al., 1962RDSH
10.84 ± 0.05PEBaidin, Timoshenko, et al., 1985Vertical value; LBLHLM
10.83 ± 0.05PEBaidin, Chizhov, et al., 1981Vertical value; LLK
10.83PEBaidin, Chizhov, et al., 1981, 2Vertical value; LLK
10.88PEEland, 1970Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH3+14.8 ± 0.2?EIGowenlock, Haynes, et al., 1962RDSH
CH3Hg+12.4 ± 0.2ClEIGowenlock, Haynes, et al., 1962RDSH
ClHg+13.3 ± 0.2CH3EIGlockling, Irwin, et al., 1976LLK


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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baidin, Chizhov, et al., 1981
Baidin, V.N.; Chizhov, Y.V.; Timoshenko, M.M.; Sokolikova, O.K.; Grishin, Y.K.; Ustynyuk, Y.A., The photoelectron spectra of alkylmercury chlorides, J. Struct. Chem., 1981, 22, 616, In original 164. [all data]

Baidin, Chizhov, et al., 1981, 2
Baidin, V.N.; Chizhov, Y.V.; Timoshenko, M.M.; Ustynyuk, Y.A.; Kritskaya, I.I., He(I) photoelectronic spectra of organic compounds with a mercury atom attached to an sp2 hybridized carbon, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1981, 2362. [all data]

Glockling, Irwin, et al., 1976
Glockling, F.; Irwin, J.G.; Morrison, R.J.; Sweeney, J.J., A mass spectroscopic study of organomercurials and mercuric halides, Inorg. Chim. Acta, 1976, 19, 267. [all data]

Gowenlock, Haynes, et al., 1962
Gowenlock, B.G.; Haynes, R.M.; Majer, J.R., Electron impact measurement on some organomercury compounds, J. Chem. Soc. Faraday Trans., 1962, 58, 1905. [all data]

Baidin, Timoshenko, et al., 1985
Baidin, V.N.; Timoshenko, M.M.; Chizhov, Y.V.; Ustynyuk, Y.A.; Kritskaya, I.I., Photoelectron spectra nad the structure of organomercury compounds, J. Organomet. Chem., 1985, 292, 55. [all data]

Eland, 1970
Eland, J.H.D., Photoelectron spectra and chemical bonding of mercury(II) compounds, Intern. J. Mass Spectrom. Ion Phys., 1970, 4, 37. [all data]


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