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n-Tridecan-1-ol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus303.05KN/AGaikwad and Subrahmanyam, 1985Uncertainty assigned by TRC = 0.5 K; TRC
Tfus301.7KN/ABelousov, Bubnov, et al., 1977Uncertainty assigned by TRC = 1. K; TRC
Tfus304.89KN/AMosselman, Mourik, et al., 1974Crystal phase 3 phase; Uncertainty assigned by TRC = 0.05 K; TRC
Tfus304.63KN/AMosselman, Mourik, et al., 1974Crystal phase 2 phase; Uncertainty assigned by TRC = 0.04 K; TRC
Tfus303.50KN/AMosselman, Mourik, et al., 1974Crystal phase 1 phase; Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Deltavap94.7 ± 0.4kJ/molCGCNichols, Kweskin, et al., 2006AC
Deltavap95.8kJ/molGSKulikov, Verevkin, et al., 2001Based on data from 307. - 348. K.; AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
428.70.020Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
91.1327.GSKulikov, Verevkin, et al., 2001Based on data from 307. - 348. K.; AC
87.4343.N/AN'Guimbi, Kasehgari, et al., 1992Based on data from 313. - 373. K.; AC
69.2446.AStephenson and Malanowski, 1987Based on data from 431. - 568. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
44.78304.7van Miltenburg, van den Berg, et al., 2003AC
18.74306.6Mosselman, Mourik, et al., 1974, 2AC

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
3.600301.6crystaline, «beta»crystaline, Mosselman, Mourik, et al., 1974, 2DH
22.100305.8crystaline, «beta»crystaline, «alpha»Mosselman, Mourik, et al., 1974, 2DH
45.120304.6crystaline, «beta»liquidMosselman, Mourik, et al., 1974, 2DH
23.000303.5crystaline, «alpha»liquidMosselman, Mourik, et al., 1974, 2DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
11.9301.6crystaline, «beta»crystaline, Mosselman, Mourik, et al., 1974, 2DH
72.3305.8crystaline, «beta»crystaline, «alpha»Mosselman, Mourik, et al., 1974, 2DH
148.1304.6crystaline, «beta»liquidMosselman, Mourik, et al., 1974, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gaikwad and Subrahmanyam, 1985
Gaikwad, B.R.; Subrahmanyam, V.V., Melting behavior of fatty alcohols and their binary blends., J. Indian Chem. Soc., 1985, 62, 513. [all data]

Belousov, Bubnov, et al., 1977
Belousov, V.P.; Bubnov, V.I.; Pfestorf, R.; Schumichen, A., Calorimetric characteristics of selected nonelectrotype systems. Additional experimental measurement of enthalpy of mixing in systems of n- alkylanine-aromatic & n-alchohol-aromatic, Z. Chem., 1977, 17, 382. [all data]

Mosselman, Mourik, et al., 1974
Mosselman, C.; Mourik, J.; Dekker, H., Enthalpies of phase change and heat capacities of some long-chain alcohols. Adiabatic semi-microcalorimeter for studies of polymorphism, J. Chem. Thermodyn., 1974, 6, 477-87. [all data]

Nichols, Kweskin, et al., 2006
Nichols, Gary; Kweskin, Sasha; Frericks, Margaret; Reiter, Sarah; Wang, Gin; Orf, Jennifer; Carvallo, Brett; Hillesheim, Dorothea; Chickos, James, Evaluation of the Vaporization, Fusion, and Sublimation Enthalpies of the 1-Alkanols: The Vaporization Enthalpy of 1-, 6-, 7-, and 9-Heptadecanol, 1-Octadecanol, 1-Eicosanol, 1-Docosanol, 1-Hexacosanol, and Cholesterol at T = 298.15 K by Correlation Gas Chromatography, J. Chem. Eng. Data, 2006, 51, 2, 475-482, https://doi.org/10.1021/je0503857 . [all data]

Kulikov, Verevkin, et al., 2001
Kulikov, Dmitry; Verevkin, Sergey P.; Heintz, Andreas, Enthalpies of vaporization of a series of aliphatic alcohols, Fluid Phase Equilibria, 2001, 192, 1-2, 187-207, https://doi.org/10.1016/S0378-3812(01)00633-1 . [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

N'Guimbi, Kasehgari, et al., 1992
N'Guimbi, J.; Kasehgari, H.; Mokbel, I.; Jose, J., Tensions de vapeur d'alcools primaires dans le domaine 0,3 Pa à 1,5 kPa, Thermochimica Acta, 1992, 196, 2, 367-377, https://doi.org/10.1016/0040-6031(92)80100-B . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

van Miltenburg, van den Berg, et al., 2003
van Miltenburg, J. Cees; van den Berg, Gerrit.J.K.; Ramirez, Marius, Heat Capacities and Derived Thermodynamic Functions of 1-Dodecanol and 1-Tridecanol between 10 K and 370 K and Heat Capacities of 1-Pentadecanol and 1-Heptadecanol between 300 K and 380 K and Correlations for the Heat Capacity and the Entropy of Liquid n -Alcohols, J. Chem. Eng. Data, 2003, 48, 1, 36-43, https://doi.org/10.1021/je025524o . [all data]

Mosselman, Mourik, et al., 1974, 2
Mosselman, C.; Mourik, J.; Dekker, H., Enthalpies of phase change and heat capacities of some long-chain alcohols. Adiabatic semi-microcalorimeter for studies of polymorphism, J. Chem. Thermodynam., 1974, 6, 477-487. [all data]


Notes

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