GeCl4+

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 51070 ± 400 gas Green, Green, et al., 1970
Bassett and Lloyd, 1971
Smith, Tuckett, et al., 1994

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 21620 ± 240 gas Green, Green, et al., 1970
Bassett and Lloyd, 1971
Smith, Tuckett, et al., 1994

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 20200 gas C-X Lambert, Mason, et al., 1988
Lambert, Mason, et al., 1988, 2
Ibuki and Kamamoto, 1996

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txt = 16300 gas C-A Lambert, Mason, et al., 1988
Lambert, Mason, et al., 1988, 2
Ibuki and Kamamoto, 1996

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 8880 ± 1100 gas Green, Green, et al., 1970
Bassett and Lloyd, 1971
Smith, Tuckett, et al., 1994

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 5650 ± 1100 gas Green, Green, et al., 1970
Bassett and Lloyd, 1971
Smith, Tuckett, et al., 1994

Additional references: Jacox, 1994, page 297; Jacox, 1998, page 306; Jacox, 2003, page 306; Biehl, Boyle, et al., 1998

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.
tEnergy separation between the v = 0 levels of the two excited states involed in the transition.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Green, Green, et al., 1970
Green, J.C.; Green, M.L.; Joachim, P.J.; Orchard, A.F.; Turner, D.W., A Study of the Bonding in the Group IV Tetrahalides by Photoelectron Spectroscopy, Phil. Trans. Roy. Soc. (London) A268, 1970, 268, 1184, 111, https://doi.org/10.1098/rsta.1970.0065 . [all data]

Bassett and Lloyd, 1971
Bassett, P.J.; Lloyd, D.R., J. Chem. Soc. A, 1971, 641. [all data]

Smith, Tuckett, et al., 1994
Smith, D.M.; Tuckett, R.P.; Yoxall, K.R.; Codling, K.; Hatherly, P.A.; Aarts, J.F.M.; Stankiewicz, M., Use of threshold electron and fluorescence coincidence techniques to probe the decay dynamics of the valence states of CF+4, SiF+4, SiCl+4, and GeCl+4, J. Chem. Phys., 1994, 101, 12, 10559, https://doi.org/10.1063/1.467873 . [all data]

Lambert, Mason, et al., 1988
Lambert, I.R.; Mason, S.M.; Tuckett, R.P.; Hopkirk, A., Electronic emission spectroscopy of Group IV tetrachloro molecular ions, J. Chem. Phys., 1988, 89, 5, 2675, https://doi.org/10.1063/1.455018 . [all data]

Lambert, Mason, et al., 1988, 2
Lambert, I.R.; Mason, S.M.; Tuckett, R.P.; Hopkirk, A., Decay pathways of excited electronic states of Group IV tetrafluoro and tetrachloro molecular ions studied with synchrotron radiation, J. Chem. Phys., 1988, 89, 5, 2683, https://doi.org/10.1063/1.455019 . [all data]

Ibuki and Kamamoto, 1996
Ibuki, T.; Kamamoto, A., Photoabsorption cross section and radiative processes of GeCl4 in the valence region of 6--31 eV, Chem. Phys. Lett., 1996, 260, 1-2, 314, https://doi.org/10.1016/0009-2614(96)00909-8 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Biehl, Boyle, et al., 1998
Biehl, H.; Boyle, K.I.; Seccombe, D.P.; Smith, D.M.; Tuckett, R.P.; Baumgartel, H.; Jochims, H.W., Vacuum--UV fluorescence spectroscopy of CCl4, SiCl4 and GeCl4 in the range 9--25eV, J. Electron Spectrosc. Relat. Phenom., 1998, 97, 1-2, 89, https://doi.org/10.1016/S0368-2048(98)00261-8 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References