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1-Dodecanol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil534.2KN/AAldrich Chemical Company Inc., 1990BS
Quantity Value Units Method Reference Comment
Tfus297.0 ± 0.8KAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple296.95KN/ASpizzichino, 1956Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Ptriple9.599×10-7barN/ASpizzichino, 1956Uncertainty assigned by TRC = 2.7×10-7 bar; TRC
Quantity Value Units Method Reference Comment
Tc719.4 ± 1.5KN/AGude and Teja, 1995 
Tc719.4KN/ARosenthal and Teja, 1990Uncertainty assigned by TRC = 0.8 K; TRC
Tc719.4KN/ARosenthal and Teja, 1989Uncertainty assigned by TRC = 0.8 K; TRC
Tc719.4KN/ATeja, Lee, et al., 1989TRC
Quantity Value Units Method Reference Comment
Pc19.9 ± 0.5barN/AGude and Teja, 1995 
Pc19.94barN/ARosenthal and Teja, 1990Uncertainty assigned by TRC = 0.50 bar; TRC
Pc19.94barN/ARosenthal and Teja, 1989Uncertainty assigned by TRC = 0.50 bar; TRC
Quantity Value Units Method Reference Comment
Deltavap92. ± 1.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Deltasub129.3kJ/molN/ADavies and Kybett, 1965AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
84.760343.15N/ASvensson, 1979No pressure measurement.; DH
85.8327.GSKulikov, Verevkin, et al., 2001Based on data from 303. - 348. K.; AC
80.5358.N/AN'Guimbi, Kasehgari, et al., 1992Based on data from 303. - 413. K.; AC
73.8398.AStephenson and Malanowski, 1987Based on data from 383. - 438. K.; AC
57.1520.AStephenson and Malanowski, 1987Based on data from 505. - 550. K.; AC
66.7440.A,EBStephenson and Malanowski, 1987Based on data from 425. - 550. K.; AC
83.3333.A,MEStephenson and Malanowski, 1987Based on data from 303. - 363. K. See also Geiseler, Quitzsch, et al., 1962.; AC
84.7 ± 0.5343.CSvensson, 1979AC
92.5312.N/AWilhoit and Zwolinski, 1973Based on data from 297. - 363. K.; AC
67.6426.N/AWilhoit and Zwolinski, 1973Based on data from 411. - 487. K.; AC
71.5415.DTAKemme and Kreps, 1969Based on data from 400. - 538. K.; AC
95. ± 2.297.VDavies and Kybett, 1965ALS
95.4305.MEDavies and Kybett, 1965Based on data from 297. - 313. K.; AC
67.6426.N/ARose, Papahronis, et al., 1958Based on data from 411. - 487. K.; AC

Entropy of vaporization

DeltavapS (J/mol*K) Temperature (K) Reference Comment
246.74343.15Svensson, 1979No; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
376.54 - 437.614.846912057.697-105.421Ambrose, Ellender, et al., 1974Coefficents calculated by NIST from author's data.
425.72 - 549.673.884991499.764-151.106Ambrose and Sprake, 1970Coefficents calculated by NIST from author's data.
399.7 - 538.63.811521454.635-155.915Kemme and Kreps, 1969 

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
130.1 ± 1.2290.MEDavies and Kybett, 1965Based on data from 285. - 294. K. See also Stephenson and Malanowski, 1987.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
40.31297.3van Miltenburg, van den Berg, et al., 2003AC
40.17300.2Acree, 1993AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Spizzichino, 1956
Spizzichino, C., Contribution a l'etude des tensions de vapeur et des chaleurs de vaporisation des acides gras, esters methyliques et alcools gras a des pressions inferieures a 1 mm de mercure, J. des Recherches du C.N.R.S., 1956, 34, 1-24. [all data]

Gude and Teja, 1995
Gude, M.; Teja, A.S., Vapor-Liquid Critical Properties of Elements and Compounds. 4. Aliphatic Alkanols, J. Chem. Eng. Data, 1995, 40, 1025-1036. [all data]

Rosenthal and Teja, 1990
Rosenthal, D.J.; Teja, A.S., The Critical Pressures and temperatures of Isomeric Alkanols, Ind. Eng. Chem. to be published 1990 1990, 1990. [all data]

Rosenthal and Teja, 1989
Rosenthal, D.J.; Teja, A.S., Critical pressures and temperatures of isomeric alkanols, Ind. Eng. Chem. Res., 1989, 28, 1693. [all data]

Teja, Lee, et al., 1989
Teja, A.S.; Lee, R.J.; Rosenthal, D.J.; Anselme, M.J., Correlation of the Critical Properties of Alkanes and Alkanols in 5th IUPAC Conference on Alkanes and AlkanolsGradisca, 1989. [all data]

Davies and Kybett, 1965
Davies, M.; Kybett, B., Sublimation and vaporization heats of long-chain alcohols, Trans. Faraday Soc., 1965, 61, 1608. [all data]

Svensson, 1979
Svensson, Ch., Enthalpies of vaporization of 1-decanol and 1-dodecanol and their influence on the CH2-increment for the enthalpies of formation, J. Chem. Thermodynam., 1979, 11, 593-596. [all data]

Kulikov, Verevkin, et al., 2001
Kulikov, Dmitry; Verevkin, Sergey P.; Heintz, Andreas, Enthalpies of vaporization of a series of aliphatic alcohols, Fluid Phase Equilibria, 2001, 192, 1-2, 187-207, https://doi.org/10.1016/S0378-3812(01)00633-1 . [all data]

N'Guimbi, Kasehgari, et al., 1992
N'Guimbi, J.; Kasehgari, H.; Mokbel, I.; Jose, J., Tensions de vapeur d'alcools primaires dans le domaine 0,3 Pa à 1,5 kPa, Thermochimica Acta, 1992, 196, 2, 367-377, https://doi.org/10.1016/0040-6031(92)80100-B . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Geiseler, Quitzsch, et al., 1962
Geiseler, G.; Quitzsch, K.; Hesselbach, J.; Huettig, R., Z. Phys. Chem. (Leipzig), 1962, 200, 79. [all data]

Wilhoit and Zwolinski, 1973
Wilhoit, R.C.; Zwolinski, B.J., Physical and thermodynamic properties of aliphatic alcohols, J. Phys. Chem. Ref. Data Suppl., 1973, 1, 2, 1. [all data]

Kemme and Kreps, 1969
Kemme, Herbert R.; Kreps, Saul I., Vapor pressure of primary n-alkyl chlorides and alcohols, J. Chem. Eng. Data, 1969, 14, 1, 98-102, https://doi.org/10.1021/je60040a011 . [all data]

Rose, Papahronis, et al., 1958
Rose, Arthur; Papahronis, B.; Williams, E., Experimental Measurement of Vapor-Liquid Equilibria for Octanol-Decanol and Decanol-Dodecanol Binaries., Ind. Eng. Chem. Chem. Eng. Data Series, 1958, 3, 2, 216-219, https://doi.org/10.1021/i460004a008 . [all data]

Ambrose, Ellender, et al., 1974
Ambrose, D.; Ellender, J.H.; Sprake, C.H.S., Thermodynamic properties of organic oxygen compounds XXXV. Vapour pressures of aliphatic alcohols, The Journal of Chemical Thermodynamics, 1974, 6, 9, 909-914, https://doi.org/10.1016/0021-9614(74)90235-3 . [all data]

Ambrose and Sprake, 1970
Ambrose, D.; Sprake, C.H.S., Thermodynamic properties of organic oxygen compounds XXV. Vapour pressures and normal boiling temperatures of aliphatic alcohols, The Journal of Chemical Thermodynamics, 1970, 2, 5, 631-645, https://doi.org/10.1016/0021-9614(70)90038-8 . [all data]

van Miltenburg, van den Berg, et al., 2003
van Miltenburg, J. Cees; van den Berg, Gerrit.J.K.; Ramirez, Marius, Heat Capacities and Derived Thermodynamic Functions of 1-Dodecanol and 1-Tridecanol between 10 K and 370 K and Heat Capacities of 1-Pentadecanol and 1-Heptadecanol between 300 K and 380 K and Correlations for the Heat Capacity and the Entropy of Liquid n -Alcohols, J. Chem. Eng. Data, 2003, 48, 1, 36-43, https://doi.org/10.1021/je025524o . [all data]

Acree, 1993
Acree, William E., Thermodynamic properties of organic compounds, Thermochimica Acta, 1993, 219, 97-104, https://doi.org/10.1016/0040-6031(93)80486-T . [all data]


Notes

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