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1-Dodecene

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-165.4 ± 2.1kJ/molCcrStridh, 1976 
Deltafgas-165.2kJ/molChydBretschneider and Rogers, 1970 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-226.2 ± 2.1kJ/molCcrStridh, 1976ALS
Quantity Value Units Method Reference Comment
Deltacliquid-7925.9 ± 1.3kJ/molCcrStridh, 1976Corresponding «DELTA»fliquid = -226.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid484.80J/mol*KN/AMcCullough, Finke, et al., 1957Does not include S0.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
360.66298.15McCullough, Finke, et al., 1957T = 11 to 360 K.; DH

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

1-Dodecene + Hydrogen = Dodecane

By formula: C12H24 + H2 = C12H26

Quantity Value Units Method Reference Comment
Deltar-125.4 ± 1.5kJ/molChydRogers and Skanupong, 1974liquid phase; solvent: Hexane
Deltar125.7 ± 2.1kJ/molChydBretschneider and Rogers, 1970liquid phase; solvent: glacial acetic acid

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Stridh, 1976
Stridh, G., Enthalpies of formation of 1-dodecene and 1-hexadecene and the CH2-increment in the 1-alkene series, J. Chem. Thermodyn., 1976, 8, 895-899. [all data]

Bretschneider and Rogers, 1970
Bretschneider, E.; Rogers, D.W., A new microcalorimeter: heats of hydrogenation of four monoolefins, Mikrochim. Acta, 1970, 482-490. [all data]

McCullough, Finke, et al., 1957
McCullough, J.P.; Finke, H.L.; Gross, M.E.; Messerly, J.F.; Waddington, G., Low temperature calorimetric studies of seven 1-olefins: effect of orientational disorder in the solid state, J. Phys. Chem., 1957, 61, 289-301. [all data]

Rogers and Skanupong, 1974
Rogers, D.W.; Skanupong, S., Heats of hydrogenation of sixteen terminal monoolefins. The alternating effect, J. Phys. Chem., 1974, 78, 2569-2572. [all data]


Notes

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