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Decanal

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil481.7KN/AWeast and Grasselli, 1989BS
Tboil479.15KN/AFoote and Gelpi, 1943Uncertainty assigned by TRC = 3. K; TRC
Tboil481.65KN/AEscourrou, 1939Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tfus269.25KN/AVasil'ev and Petrov, 1984Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Tc674.0KN/AGude and Teja, 1994Uncertainty assigned by TRC = 2.5 K; by the sealed ampule method; TRC
Tc674.2KN/ATeja and Rosenthal, 1990Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Pc26.00barN/ATeja and Rosenthal, 1990Uncertainty assigned by TRC = 0.80 bar; TRC
Quantity Value Units Method Reference Comment
rhoc1.67mol/lN/AGude and Teja, 1994Uncertainty assigned by TRC = 0.04 mol/l; by the sealed ampule method; TRC
Quantity Value Units Method Reference Comment
Deltavap59.5 ± 0.4kJ/molGSVerevkin, Krasnykh, et al., 2003Based on data from 280. - 316. K.; AC
Deltavap60.5kJ/molCGCKoutek, Hoskovec, et al., 1996Based on data from 308. - 353. K. See also Ova, Koultek, et al., 2000.; AC
Deltavap60.4 ± 0.3kJ/molN/AD'yakova, Korichev, et al., 1981AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
57.3303.AStephenson and Malanowski, 1987Based on data from 288. - 333. K.; AC
57.3308.AStephenson and Malanowski, 1987Based on data from 293. - 358. K.; AC
56.3339.N/AStephenson and Malanowski, 1987Based on data from 324. - 482. K. See also Stull, 1947.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
325.1 - 481.75.332842378.316-35.245Stull, 1947Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
30.600269.47D'yakova and Vasil'ev, 198097.10 mol% purity.; DH
30.6268.2D'yakova and Vasil'ev, 1980AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
113.6269.47D'yakova and Vasil'ev, 198097.10; DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Foote and Gelpi, 1943
Foote; Gelpi, J. Am. Pharm. Assoc., Sci. Ed., 1943, 32, 145. [all data]

Escourrou, 1939
Escourrou, R., Bull. Soc. Chim. Fr., 1939, 6, 1173. [all data]

Vasil'ev and Petrov, 1984
Vasil'ev, I.A.; Petrov, V.M., Thermodynamic Properties of Oxygen-containing Organic Compounds, Handbook, Soedinenii: Khimya, Leningrad, p 240, 1984. [all data]

Gude and Teja, 1994
Gude, M.T.; Teja, A.S., The Critical Properties of Several n-Alkanals, Tetralin and NMP, Experimental Results for DIPPR 1990-91 Projects on Phase Equilibria and Pure Component Properties, 1994, 1994, DIPPR Data Series No. 2, p.174-83. [all data]

Teja and Rosenthal, 1990
Teja, A.S.; Rosenthal, D.J., The Critical Pressures and Temperatures of Twelve Substances Using A Low Residence Time Flow Apparatus, AIChE Symp. Ser., 1990, 86, 279, 133-7. [all data]

Verevkin, Krasnykh, et al., 2003
Verevkin, Sergey P.; Krasnykh, Eugen L.; Vasiltsova, Tatiana V.; Koutek, Bohumir; Doubsky, Jan; Heintz, Andreas, Vapor pressures and enthalpies of vaporization of a series of the linear aliphatic aldehydes, Fluid Phase Equilibria, 2003, 206, 1-2, 331-339, https://doi.org/10.1016/S0378-3812(03)00035-9 . [all data]

Koutek, Hoskovec, et al., 1996
Koutek, Bohumir; Hoskovec, Michal; Vrkocov, Pavlína; Konecný, Karel; Feltl, Ladislav; Vrkoc, Jan, Gas chromatographic determination of vapour pressures of pheromone-like compounds III. Aldehydes, Journal of Chromatography A, 1996, 719, 2, 391-400, https://doi.org/10.1016/0021-9673(95)00740-7 . [all data]

Ova, Koultek, et al., 2000
Ova, P.V.; Koultek, B.; Hoskovec, M., Practice Oriented Results on Use and Production of Neem Ingredients and Pheromones VI, H. Kleeberg and C.P.W. Zebitz, ed(s)., Druck and Graphic, Giessen, 2000, 211-218. [all data]

D'yakova, Korichev, et al., 1981
D'yakova, G.N.; Korichev, G.L.; Korkhova, A.D.; Vasil'eva, T.F.; Vasil'ev, I.A., Zh. Prikl. Khim. (Leningrad), 1981, 54, 1644. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

D'yakova and Vasil'ev, 1980
D'yakova, G.N.; Vasil'ev, I.A., Study of the thermodynamic properties of octanal and decanal, B.S.R. Inst. Neftekhim. Protsessov (Leningrad), 1980, (1), 51. [all data]


Notes

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