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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase 5 % Phenyl methyl siloxaneDB-5Equity-5MSBP-1SPB-5
Column length (m) 30.30.30.50.60.
Carrier gas  HeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.220.32
Phase thickness (μm) 0.250.250.250.251.
Tstart (C) 60.60.50.60.40.
Tend (C) 270.240.250.220.230.
Heat rate (K/min) 15.3.3.2.3.
Initial hold (min)     2.
Final hold (min) 15. 10.20.10.
I 1199.1205.1208.1183.1206.
ReferenceZaikin, 2010Baccouri, Ben Temime, et al., 2007Belsito E.L., Carbone C., et al., 2007Duquesnoy, Castola, et al., 2007Engel and Ratel, 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5MSDB-5DB-5RTX-1
Column length (m) 30.30.30.60.60.
Carrier gas N2HeHe He
Substrate      
Column diameter (mm) 0.250.250.250.320.22
Phase thickness (μm) 0.250.250.251.0.25
Tstart (C) 50.35.60.40.60.
Tend (C) 220.225.240.260.230.
Heat rate (K/min) 5.10.3.4.2.
Initial hold (min) 10.5. 2. 
Final hold (min)  25. 10.35.
I 1202.1214.1206.1207.1184.
ReferenceFlamini, Tebano, et al., 2007Lozano P.R., Miracle E.R., et al., 2007Maccioni, Baldini, et al., 2007Methven L., Tsoukka M., et al., 2007Paolini, Muselli, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase ZB-5HP-5MSHP-5MSDB-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHe  
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.50.250.250.251.
Tstart (C) 40.60.80.60.50.
Tend (C) 265.280.300.220.290.
Heat rate (K/min) 7.4.4.3.10.
Initial hold (min)  5.  1.
Final hold (min) 5.   10.
I 1206.1203.1206.81204.1212.
ReferenceRuiz Perez-Cacho, Mahattanatawee, et al., 2007Saroglou, Marin, et al., 2007Zeng, Zhao, et al., 2007Bastos, Ishimoto, et al., 2006Bylaite and Meyer, 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5MSHP-5MSHP-5MSSPB-1
Column length (m) 30.20.30.30.30.
Carrier gas N2 HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.50.
Tend (C) 220.240.280.280.250.
Heat rate (K/min) 5.5.3.3.5.
Initial hold (min) 10.4.  3.
Final hold (min)  15.  15.
I 1207.1206.1204.1185.1191.
ReferenceFlamini, Tebano, et al., 2006Kallio, Jussila, et al., 2006Kukic J., Petrovic S., et al., 2006Pavlovic, Kovacevic, et al., 2006Radulovic, Mananjarasoa, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5DB-5HP-5MSHP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeH2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.50.50.50.40.
Tend (C) 280.250.250.285.300.
Heat rate (K/min) 4.5.5.4.34.
Initial hold (min) 5.2.2. 5.
Final hold (min)      
I 1206.1202.1202.1198.1202.
ReferenceSaroglou, Dorizas, et al., 2006Su, Ho, et al., 2006Su, Ho, et al., 2006, 2Vujisic L., Vuckovic I., et al., 2006Vundac, Pfeifhofer, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5MSHP-5CP Sil 5 CBCP Sil 5 CB
Column length (m) 30.30.30.25.25.
Carrier gas HeHeHeH2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.25 0.4
Tstart (C) 50.80.60.80.80.
Tend (C) 220.300.250.270.270.
Heat rate (K/min) 3.4.10.10.10.
Initial hold (min)   2.  
Final hold (min) 20. 10.  
I 1214.1203.21210.1180.1180.
ReferenceXian Q., Chen H., et al., 2006Zhao C.X., Li, et al., 2006Zhao J.Y., Liu J.M., et al., 2006Ziegenbein, Hanssen, et al., 2006Ziegenbein, Hanssen, et al., 2006, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 8 CBDB-5MSDB-5MSHP-5MDN-5
Column length (m) 5.30.30.30.30.
Carrier gas  He N2He
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 60.40.40.60.50.
Tend (C) 220.200.200.220.250.
Heat rate (K/min) 4.5.10.5.3.
Initial hold (min) 5.5.3.10. 
Final hold (min) 30.45.20.  
I 1217.1223.1223.1205.1204.
ReferenceAliani and Farmer, 2005Carunchia Whetstine, Croissant, et al., 2005Carunchia Whetstine, Croissant, et al., 2005Celik, Gokturk, et al., 2005Dugo, Mondello, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase 5 % Phenyl methyl siloxaneDB-1HP-5HP-5DB-1
Column length (m) 30.30.30.30.30.
Carrier gas HeHeN2N2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 1.0.250.250.250.25
Tstart (C) 40.40.60.60.40.
Tend (C) 250.250.220.220.250.
Heat rate (K/min) 7.3.5.5.3.
Initial hold (min) 10. 10.10. 
Final hold (min) 5.20.  20.
I 1219.1184.1206.1204.1184.
ReferenceEstevez, Ventanas, et al., 2005Fanciullino, Gancel, et al., 2005Flamini, Luigi Cioni, et al., 2005Flamini, Luigi Cioni, et al., 2005, 2Gancel, Ollitrault, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5ZB-5RTX-1HP-5MS
Column length (m) 25.30.30.60.30.
Carrier gas N2HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.320.220.25
Phase thickness (μm) 0.25 0.50.250.25
Tstart (C) 75.60.40.60.60.
Tend (C) 210.260.265.230.250.
Heat rate (K/min) 3.3.7.2.4.
Initial hold (min) 10.   2.
Final hold (min) 1. 5.35.20.
I 1202.1204.1198.1182.1205.
Referencebin Jantan, Yalvema, et al., 2005Javidnia, Miri, et al., 2005Mahattanatawee, Rouseff, et al., 2005Paolini, Costa, et al., 2005Pino, Mesa, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5Mega 5MSDB-5HP-5MS
Column length (m) 60.25.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.20.20.250.260.25
Phase thickness (μm) 0.251.0.250.250.25
Tstart (C) 60.40.40.60.60.
Tend (C) 200.280.240.246.280.
Heat rate (K/min) 2.5.3.3.3.
Initial hold (min)   2.  
Final hold (min) 10.5.   
I 1203.1204.1199.1201.1204.
ReferenceSmadja, Rondeau, et al., 2005Solina, Baumgartner, et al., 2005Verzera, Trozzi, et al., 2005Adams, Habte, et al., 2004Aligiannis, Kalpoutzakis, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase ZB-5HP-5BPX-5RTX-5DB-5
Column length (m) 30.30.25.30.30.
Carrier gas Helium HeHeN2
Substrate      
Column diameter (mm) 0.320.250.220.250.25
Phase thickness (μm) 0.500.250.250.250.25
Tstart (C) 40.60.50.45.60.
Tend (C) 265.220.300.300.240.
Heat rate (K/min) 7.5.5.3.3.
Initial hold (min)  10.5.6. 
Final hold (min) 5.  10. 
I 1206.1205.1216.1205.1205.
ReferenceBell, 2004Ceccarini, Macchia, et al., 2004Dickschat, Wenzel, et al., 2004Dugo, Mondello, et al., 2004Flamini, Cioni, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5HP-5MSCP-Sil 8CB-MSHP-5
Column length (m) 30.30.30.60.30.
Carrier gas HeN2He He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 50.60.60.40.60.
Tend (C) 290.220.280.280.260.
Heat rate (K/min) 4.5.4.4.3.
Initial hold (min)  10.5.2. 
Final hold (min)    5. 
I 1206.1205.1203.1217.1206.
ReferenceFlach A., Dondon R.C., et al., 2004Flamini, Luigi Cioni, et al., 2004Grujic-Jovanovic, Skaltsa, et al., 2004Hierro, de la Hoz, et al., 2004Javidnia, Miri, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5MSSPB-5HP-5HP-5MS
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)  0.250.250.250.25
Tstart (C) 60.40.60.50.50.
Tend (C) 260.280.250.310.200.
Heat rate (K/min) 3.4.4.4.6.
Initial hold (min)  2.2. 1.5
Final hold (min)   20. 5.
I 1205.1209.1205.1205.1207.
ReferenceJavidnia, Miri, et al., 2004, 2Mardarowicz, Wianowska, et al., 2004Pino, Marbot, et al., 2004Singer, Flach, et al., 2004Weissbecker, Holighaus, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1HP-5HP-5SPB-1
Column length (m) 30.30.30.30.30.
Carrier gas HeHeN2N2He
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.60.60.35.
Tend (C) 240.250.220.220.225.
Heat rate (K/min) 3.3.5.5.4.
Initial hold (min)   10.10.5.
Final hold (min) 30.20.  20.
I 1205.1172.1205.1205.1184.
ReferenceBader, Caponi, et al., 2003Brat, Rega, et al., 2003Campeol, Flamini, et al., 2003Campeol, Flamini, et al., 2003Chisholm, Jell, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1SPB-1SPB-1SPB-1HP-5
Column length (m) 30.25.25.25.30.
Carrier gas He   N2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 35.35.35.35.60.
Tend (C) 225.225.225.225.220.
Heat rate (K/min) 4.4.4.4.5.
Initial hold (min) 5.10.10.10.10.
Final hold (min) 20.    
I 1191.1189.1188.1189.1205.
ReferenceChisholm, Jell, et al., 2003Chisholm, Wilson, et al., 2003Chisholm, Wilson, et al., 2003Chisholm, Wilson, et al., 2003Dural, Bagci, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5DB-5HP-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas N2HeHeN2N2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 220.240.240.220.220.
Heat rate (K/min) 5.3.3.5.5.
Initial hold (min) 10.  10.10.
Final hold (min)      
I 1206.1205.1205.1206.1205.
ReferenceErtugrul, Dural, et al., 2003Flamini, Cioni, et al., 2003Flamini, Luigi Cioni, et al., 2003Flamini, Luigi Cioni, et al., 2003, 2Flamini, Luigi Cioni, et al., 2003, 3
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5DB-1DB-5DB-5
Column length (m) 30.30.30.30.30.
Carrier gas N2HeHe  
Substrate      
Column diameter (mm) 0.250.250.250.320.32
Phase thickness (μm) 0.250.250.250.50.5
Tstart (C) 60.60.40.40.40.
Tend (C) 220.280.250.265.265.
Heat rate (K/min) 5.3.3.7.7.
Initial hold (min) 10.    
Final hold (min)   20.5.5.
I 1206.1204.1184.1211.1210.
ReferenceFlamini, Luigi Cioni, et al., 2003, 4Fokialakis, Melliou, et al., 2003Gancel, Ollitrault, et al., 2003Högnadóttir and Rouseff, 2003Högnadóttir and Rouseff, 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-1HP-5Mega 5MSDB-5
Column length (m) 30.30.30.30.30.
Carrier gas N2HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.330.250.251.
Tstart (C) 75.40.60.40.50.
Tend (C) 230.260.280.240.200.
Heat rate (K/min) 3.2.4.3.2.5
Initial hold (min) 10.5.5.2. 
Final hold (min)  20.   
I 1205.1209.1203.1199.1206.6
Referencebin Jantan, Yassin, et al., 2003Senatore, Rigano, et al., 2003Skaltsa, Demetzos, et al., 2003Verzera, Trozzi, et al., 2003Xu, van Stee, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BPX-5HP-5MSHP-5MSCP Sil 8 CBDB-5
Column length (m) 50.30.30.60.30.
Carrier gas  He HeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.50.250.250.250.25
Tstart (C) 60.60.50.40.60.
Tend (C) 250.300.280.250.240.
Heat rate (K/min) 4.3.3.4.3.
Initial hold (min) 5. 5.8. 
Final hold (min) 20.  10. 
I 1219.1205.1195.1216.1205.
ReferenceBredie, Mottram, et al., 2002Couladis, Chinou, et al., 2002Demetzos, Angelopoulou, et al., 2002Duckham, Dodson, et al., 2002Flamini, Cioni, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5CP Sil 5 CBBP-1HP-1
Column length (m) 30.30.50.50.24.
Carrier gas N2 H2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.220.32
Phase thickness (μm) 0.250.250.150.250.17
Tstart (C) 60.60.40.60.60.
Tend (C) 220.280.300.220.250.
Heat rate (K/min) 5.3.4.2.4.
Initial hold (min) 10.5.3. 2.
Final hold (min)    20.20.
I 1205.1197.1205.1183.1184.
ReferenceFlamini, Cioni, et al., 2002, 2Fokialakis, Magiatis, et al., 2002Heinrich, Pfeifhofer, et al., 2002Lota, de Rocca Serra, et al., 2002Nath, Sarma, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 8 CBSPB-5HP-5Petrocol DHCP-Sil 8CB-MS
Column length (m) 60.30.30.100.60.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.50.25
Tstart (C) 40.60.60.60.40.
Tend (C) 250.250.280.180.280.
Heat rate (K/min) 4.4.3.4.4.
Initial hold (min) 8.2.5.8.2.
Final hold (min) 10.20. 2. 
I 1205.1204.1204.1204.1209.
ReferenceOruna-Concha, Ames, et al., 2002Pino, Marbot, et al., 2002Aligiannis, Kalpoutzakis, et al., 2001Alonzo, Saiano, et al., 2001Bruna, Hierro, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1SPB-1HP-5SPB-SulfurSPB-1
Column length (m) 15.15.30.30.30.
Carrier gas   He He
Substrate      
Column diameter (mm) 0.250.250.250.320.32
Phase thickness (μm) 0.250.250.254.4.
Tstart (C) 35.35.60.40.45.
Tend (C) 225.225.380.200.240.
Heat rate (K/min) 6.6.3.4.5.
Initial hold (min) 3.3. 12.513.
Final hold (min) 10.10.  5.
I 1189.1188.1197.1187.51193.
ReferenceChisholm, Wilson, et al., 2001Chisholm, Wilson, et al., 2001Couladis, Tsortanidou, et al., 2001de Lacy Costello, Evans, et al., 2001Larráyoz, Addis, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1BP-1BP-1BPX-5BPX-5
Column length (m) 30.50.50.50.50.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.320.220.220.320.32
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 40.60.60.35.35.
Tend (C) 240.220.220.250.250.
Heat rate (K/min) 7.2.2.4.4.
Initial hold (min)    3.3.
Final hold (min) 5.  10.10.
I 1200.1183.1183.1218.1214.
ReferenceLin and Rouseff, 2001Lota, Serra, et al., 2001Lota, Serra, et al., 2001Oruna-Concha, Duckham, et al., 2001Oruna-Concha, Duckham, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BPX-5CP Sil 5 CBHP-5HP-5MSHP-5
Column length (m) 50.50.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.320.250.250.20
Phase thickness (μm) 0.250.4 0.250.25
Tstart (C) 35.60.50.60.60.
Tend (C) 250.280.200.280.180.
Heat rate (K/min) 4.3.4.4.4.
Initial hold (min) 3.10.1.5.8.
Final hold (min) 10.60.  2.
I 1217.1186.1219.1203.1206.
ReferenceOruna-Concha, Duckham, et al., 2001Pino and Marbot, 2001Shalit, Katzir, et al., 2001Skaltsa, Mavrommati, et al., 2001Alonzo, Bosco, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5CP Sil 8 CBHP-5HP-5
Column length (m) 60.50.60.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.320.250.250.25
Phase thickness (μm) 0.251.050.250.250.25
Tstart (C) 40.50.40.50.50.
Tend (C) 290.290.280.280.280.
Heat rate (K/min) 4.2.4.4.4.
Initial hold (min) 2. 2.5.5.
Final hold (min) 5.    
I 1205.1207.1209.1204.1204.
ReferenceBartley and Jacobs, 2000David, Scanlan, et al., 2000Elmore, Mottram, et al., 2000Lazari, Skaltsa, et al., 2000Lazari, Skaltsa, et al., 2000, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-1RTX-5SE-30DB-5Mega 5MS
Column length (m) 50.10.50.30.30.
Carrier gas HeHe N2He
Substrate      
Column diameter (mm) 0.220.10.20.250.25
Phase thickness (μm) 0.250.1 0.250.25
Tstart (C) 60.50.50.70.40.
Tend (C) 230.350.250.230.240.
Heat rate (K/min) 2.12.36.2.3.
Initial hold (min)     2.
Final hold (min) 35.    
I 1183.1209.1190.1230.1199.
ReferenceLota, de Rocca Serra, et al., 2000Mondello, Zappia, et al., 2000Paramonov, Khalilova, et al., 2000Song, Sawamura, et al., 2000Verzera, la Rosa, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Mega 5MSDB-1HP-5BP-1BPX-5
Column length (m) 30.60.30.50.50.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.250.320.250.220.32
Phase thickness (μm) 0.251.0.250.250.25
Tstart (C) 40.-50.50.60.50.
Tend (C) 240.175.280.230.250.
Heat rate (K/min) 3.6.4.2.4.
Initial hold (min) 2.2.5. 5.
Final hold (min)    35.5.
I 1199.1192.11204.1183.1204.
ReferenceVerzera, Trozzi, et al., 2000Helmig, Klinger, et al., 1999Lazari, Skaltsa, et al., 1999Lota, Serra, et al., 1999Mandin, Duckham, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BPX-5OV-1OV-1BPX-5SPB-5
Column length (m) 50.20.20.50.60.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.320.320.320.32
Phase thickness (μm) 0.250.30.30.501.
Tstart (C) 50.45.45.40.40.
Tend (C) 250.220.220.280.200.
Heat rate (K/min) 4.10.10.4.3.
Initial hold (min) 5.5.5. 5.
Final hold (min) 5.10.10. 2.
I 1214.1195.1191.1219.1206.
ReferenceMandin, Duckham, et al., 1999Valero, Sanz, et al., 1999Valero, Sanz, et al., 1999Aaslyng, Elmore, et al., 1998Verdier-Metz., Coulon, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-1DB-1DB-1
Column length (m) 30.30.25.25.30.
Carrier gas H2H2HeHe 
Substrate      
Column diameter (mm) 0.320.320.20.20.25
Phase thickness (μm) 1.1.0.110.111.
Tstart (C) 40.40.50.50.-50.
Tend (C) 210.210.250.250.180.
Heat rate (K/min) 3.3.5.5.6.
Initial hold (min)      
Final hold (min)      
I 1208.1209.1187.1187.1184.7
ReferenceMoio and Addeo, 1998Moio and Addeo, 1998Warthen, Lee, et al., 1997Warthen, Lee, et al., 1997Helmig, Pollock, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5SE-30DB-5DB-5DB-1
Column length (m) 60.50.30.30.60.
Carrier gas   H2H2 
Substrate      
Column diameter (mm) 0.330.320.320.320.32
Phase thickness (μm) 0.250.251.1.0.5
Tstart (C) -50.50.40.40.40.
Tend (C) 180.250.220.220.290.
Heat rate (K/min) 6.4.3.3.4.
Initial hold (min)     2.
Final hold (min)     5.
I 1206.1180.1209.1209.1184.
ReferenceHelmig, Pollock, et al., 1996Misharina and Golovnya, 1996Moio L., Rillo L., et al., 1996Moio L., Rillo L., et al., 1996Bartley and Foley, 1994
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1OV-101OV-101OV-101DB-1
Column length (m) 60.50.50.50.60.
Carrier gas  HeN2N2 
Substrate      
Column diameter (mm) 0.250.310.250.250.32
Phase thickness (μm) 0.250.5   
Tstart (C) 35.50.80.80.50.
Tend (C) 280.250.200.200.250.
Heat rate (K/min) 2.4.2.2.4.
Initial hold (min) 10.   0.1
Final hold (min) 10.    
I 1186.1180.1184.1185.1184.
ReferenceSpecht and Baltes, 1994Misharina, Golovnya, et al., 1992Yang, Sugisawa, et al., 1992Yang, Sugisawa, et al., 1992Flath, Light, et al., 1990
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPackedPackedPacked
Active phase DB-5OV-1Apiezon MApiezon MApiezon M
Column length (m) 0.3260.1.51.51.5
Carrier gas H2HeN2N2N2
Substrate   Celite 545Celite 545Celite 545
Column diameter (mm) 1.0.25   
Phase thickness (μm)      
Tstart (C) 30.50.75.75.75.
Tend (C) 180.225.200.200.200.
Heat rate (K/min) 1.51.56.6.6.
Initial hold (min) 5.    
Final hold (min)  50.   
I 1188.1185.1175.1177.1180.
ReferenceGuichard and Souty, 1988Chen and Ho, 1987Golovnya and Uraletz, 1971Golovnya and Uraletz, 1971Golovnya and Uraletz, 1971
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Packed
Active phase SE-30
Column length (m)  
Carrier gas  
Substrate Celite
Column diameter (mm)  
Phase thickness (μm)  
Tstart (C) 75.
Tend (C) 228.
Heat rate (K/min)  
Initial hold (min)  
Final hold (min)  
I 1193.
Referencevan den Dool and Kratz, 1963
Comment MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zaikin, 2010
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Radulovic, Mananjarasoa, et al., 2006
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Xian Q.; Chen H.; Zou H.; Yin D., Chemical composition of essential oils of two submerged macrophytes, Ceratophyllum demersum L. and Vallisneria spiralis L., Flavour Fragr. J., 2006, 21, 3, 524-526, https://doi.org/10.1002/ffj.1588 . [all data]

Zhao C.X., Li, et al., 2006
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Zhao J.Y., Liu J.M., et al., 2006
Zhao J.Y.; Liu J.M.; Zhang X.Y.; Liu Z.J.; Tsering T.; Zhong Y.; Nan P., Chemical composition of the volatiles of three wild Bergenia species from western China, Flavour Fragr. J., 2006, 21, 3, 431-434, https://doi.org/10.1002/ffj.1689 . [all data]

Ziegenbein, Hanssen, et al., 2006
Ziegenbein, F.C.; Hanssen, H.-P.; König, W.A., Secondary metabolites from Ganoderma lucidum and Spongiporus leucomallellus, Phytochemistry, 2006, 67, 2, 202-211, https://doi.org/10.1016/j.phytochem.2005.10.025 . [all data]

Ziegenbein, Hanssen, et al., 2006, 2
Ziegenbein, F.C.; Hanssen, H.-P.; König, W.A., Chemical constituents of the essential oils of three wood-rotting fungi, Flavour Fragr. J., 2006, 21, 5, 813-816, https://doi.org/10.1002/ffj.1732 . [all data]

Aliani and Farmer, 2005
Aliani, M.; Farmer, L.J., Precursors of chicken flavor. II. Identification of key flavor precursors using sensory methods, J. Agric. Food Chem., 2005, 53, 16, 6455-6462, https://doi.org/10.1021/jf050087d . [all data]

Carunchia Whetstine, Croissant, et al., 2005
Carunchia Whetstine, M.E.; Croissant, A.E.; Drake, M.A., Characterization of Dried Whey Protein Concentrate and Isolate Flavor, J. Dairy Sci., 2005, 88, 11, 3826-3839, https://doi.org/10.3168/jds.S0022-0302(05)73068-X . [all data]

Celik, Gokturk, et al., 2005
Celik, S.; Gokturk, R.S.; Flamini, G.; Cioni, P.L.; Morelli, I., Essential oils of Phlomis leucophracta, Phlomis chimerae and Phlomis grandiflora var. grandiflora from Turkey, Biochem. Syst. Ecol., 2005, 33, 6, 617-623, https://doi.org/10.1016/j.bse.2004.11.010 . [all data]

Dugo, Mondello, et al., 2005
Dugo, P.; Mondello, L.; Favoino, O.; Cicero, L.; Rodriguez Zenteno, N.A.; Dugo, G., Characterization of cold-pressed Mexican dancy tangerine oils, Flavour Fragr. J., 2005, 20, 1, 60-66, https://doi.org/10.1002/ffj.1367 . [all data]

Estevez, Ventanas, et al., 2005
Estevez, M.; Ventanas, S.; Ramirez, R.; Cava, R., Influence of the Addition of Rosemary Essential Oil on the Volatiles Pattern of Porcine Frankfurters, J. Agric. Food Chem., 2005, 53, 21, 8317-8324, https://doi.org/10.1021/jf051025q . [all data]

Fanciullino, Gancel, et al., 2005
Fanciullino, A.-L.; Gancel, A.-L.; Froelicher, Y.; Luro, F.; Ollitrault, P.; Brillouet, J.-M., Effects of Nucleo-cytoplasmic Interactions on Leaf Volatile Compounds from Citrus Somatic Diploid Hybrids, J. Agric. Food Chem., 2005, 53, 11, 4517-4523, https://doi.org/10.1021/jf0502855 . [all data]

Flamini, Luigi Cioni, et al., 2005
Flamini, G.; Luigi Cioni, P.; Morelli, I.; Celik, S.; Gokturk, R.S.; Unal, O., Essential oil of Stachys aleurites from Turkey, Biochem. Syst. Ecol., 2005, 33, 1, 61-66, https://doi.org/10.1016/j.bse.2004.05.013 . [all data]

Flamini, Luigi Cioni, et al., 2005, 2
Flamini, G.; Luigi Cioni, P.; Morelli, I., Composition of the essential oils and in vivo emission of volatiles of four Lamium species from Italy: L. purpureum, L. hybridum, L. bifidum and L. amplexicaule, Food Chem., 2005, 91, 1, 63-68, https://doi.org/10.1016/j.foodchem.2004.05.047 . [all data]

Gancel, Ollitrault, et al., 2005
Gancel, A.-L.; Ollitrault, P.; Froelicher, Y.; Tomi, F.; Jacquemond, C.; Luro, F.; Brillouet, J.-M., Leaf volatile compounds of six citrus somatic allotetraploid hybrids originating from various combinations of lime, lemon, citron, sweet orange, and grapefruit, J. Agric. Food Chem., 2005, 53, 6, 2224-2230, https://doi.org/10.1021/jf048315b . [all data]

bin Jantan, Yalvema, et al., 2005
bin Jantan, I.; Yalvema, M.F.; Ayop, N.; Ahmad, A.S., Constituents of the essential oils of Cinnamomum sintoc Blume from a mountain forest of Peninsular Malaysia, Flavour Fragr. J., 2005, 20, 6, 601-604, https://doi.org/10.1002/ffj.1495 . [all data]

Javidnia, Miri, et al., 2005
Javidnia, K.; Miri, R.; Jamalian, A., Composition of the essential oil of Salvia macrosiphon Boiss. from Iran, Flavour Fragr. J., 2005, 20, 5, 542-543, https://doi.org/10.1002/ffj.1468 . [all data]

Mahattanatawee, Rouseff, et al., 2005
Mahattanatawee, K.; Rouseff, R.; Filomena Valim, M.; Naim, M., Identification and aroma impact of norisoprenoids in orange juice, J. Agric. Food Chem., 2005, 53, 2, 393-397, https://doi.org/10.1021/jf049012k . [all data]

Paolini, Costa, et al., 2005
Paolini, J.; Costa, J.; Bernardini, A., Analysis of the essential oil from aerial parts of Eupatorium cannabinum subsp. corsicum (L.) by gas chromatography with electron impact and chemical ionization mass spectrometry, J. Chromatogr. A, 2005, 1076, 1-2, 170-178, https://doi.org/10.1016/j.chroma.2005.03.131 . [all data]

Pino, Mesa, et al., 2005
Pino, J.A.; Mesa, J.; Muñoz, Y.; Martí, M.P.; Marbot, R., Volatile components from mango (Mangifera indica L.) cultivars, J. Agric. Food Chem., 2005, 53, 6, 2213-2223, https://doi.org/10.1021/jf0402633 . [all data]

Smadja, Rondeau, et al., 2005
Smadja, J.; Rondeau, P.; Sing, A.S.C., Volatile constituents of five Citrus Petitgrain essential oils from Reunion, Flavour Fragr. J., 2005, 20, 4, 399-402, https://doi.org/10.1002/ffj.1438 . [all data]

Solina, Baumgartner, et al., 2005
Solina, M.; Baumgartner, P.; Johnson, R.L.; Whitfield, F.B., Volatile aroma components of soy protein isolate and acid-hydrolysed vegetable protein, Food Chem., 2005, 90, 4, 861-873, https://doi.org/10.1016/j.foodchem.2004.06.005 . [all data]

Verzera, Trozzi, et al., 2005
Verzera, A.; Trozzi, A.; Zappala, M.; Condurso, C.; Cotroneo, A., Essential Oil Composition of Citrus meyerii Y. Tan. and Citrus medica L. cv. Diamante and Their Lemon Hybrids, J. Agric. Food Chem., 2005, 53, 12, 4890-4894, https://doi.org/10.1021/jf047879c . [all data]

Adams, Habte, et al., 2004
Adams, R.P.; Habte, M.; Park, S.; Dafforn, M.R., Preliminary comparison of vetiver root essential oils from cleansed (bacteria- and fungus-free) versus non-cleansed (normal) vetiver plants, Biochem. Syst. Ecol., 2004, 32, 12, 1137-1144, https://doi.org/10.1016/j.bse.2004.03.013 . [all data]

Aligiannis, Kalpoutzakis, et al., 2004
Aligiannis, N.; Kalpoutzakis, E.; Kyriakopoulou, I.; Mitaku, S.; Chinou, I.B., Essential oils of Phlomis species growing in Greece: chemical composition and antimicrobial activity, Flavour Fragr. J., 2004, 19, 4, 320-324, https://doi.org/10.1002/ffj.1305 . [all data]

Bell, 2004
Bell, W.A.-M., Examination of Aroma Volatiles Formed from Thermal Processing of Florida Reconstituted Grapefruit Juice. A Thesis presented to the graduate school of the university of Florida in partial fulfillment of the requirements for the degree of master of science, 2004. [all data]

Ceccarini, Macchia, et al., 2004
Ceccarini, L.; Macchia, M.; Flamini, G.; Cioni, P.L.; Caponi, C.; Morelli, I., Essential oil composition of Helianthus annuus L. leaves and heads of two cultivated hybride Carlos and Florom 350, Ind. Crops Prod., 2004, 19, 1, 13-17, https://doi.org/10.1016/S0926-6690(03)00076-1 . [all data]

Dickschat, Wenzel, et al., 2004
Dickschat, J.S.; Wenzel, S.C.; Bode, H.B.; Muller, R.; Schulz, S., Biosynthesis of Volatiles by the Myxobacterium Myxococcus xanthus, ChemBioChem, 2004, 5, 6, 778-787, https://doi.org/10.1002/cbic.200300813 . [all data]

Dugo, Mondello, et al., 2004
Dugo, P.; Mondello, L.; Zappia, G.; Bonaccorsi, I.; Cotroneo, A.; Russo, M.T., The composition of the volatile fraction and the enantiomeric distribution of five volatile components of faustrime oil (Monocitrus australatica x Fortunella sp. x Citrus aurantifolia), J. Essent. Oil Res., 2004, 16, 4, 328-333, https://doi.org/10.1080/10412905.2004.9698734 . [all data]

Flamini, Cioni, et al., 2004
Flamini, G.; Cioni, P.L.; Morelli, I.; Maccioni, S.; Baldini, R., Phytochemical typologies in some populations of Myrtus communis L. on Caprione Promontory (East Liguria, Italy), Food Chem., 2004, 85, 4, 599-604, https://doi.org/10.1016/j.foodchem.2003.08.005 . [all data]

Flach A., Dondon R.C., et al., 2004
Flach A.; Dondon R.C.; Singer R.B.; Koehler S.; Amaral M.D.E.; Marsaioli A.J., The chemistry of pollination in selected Brazilian maxillariinae orchids: Floral rewards and fragrance, J. Chem. Ecol., 2004, 30, 5, 1045-1056, https://doi.org/10.1023/B:JOEC.0000028466.50392.ed . [all data]

Flamini, Luigi Cioni, et al., 2004
Flamini, G.; Luigi Cioni, P.; Morelli, I., Essential oils of Galeopsis pubescens and G. tetrahit from Tuscany (Italy), Flavour Fragr. J., 2004, 19, 4, 327-329, https://doi.org/10.1002/ffj.1307 . [all data]

Grujic-Jovanovic, Skaltsa, et al., 2004
Grujic-Jovanovic, S.; Skaltsa, H.D.; Marin, P.; Sokovic, M., Composition and antibacterial activity of the essential oil of six Stachys species from Serbia, Flavour Fragr. J., 2004, 19, 2, 139-144, https://doi.org/10.1002/ffj.1275 . [all data]

Hierro, de la Hoz, et al., 2004
Hierro, E.; de la Hoz, L.; Ordóñez, J.A., Headspace volatile compounds from salted and occasionally smoked dried meats (cecinas) as affected by animal species, Food Chem., 2004, 85, 4, 649-657, https://doi.org/10.1016/j.foodchem.2003.07.001 . [all data]

Javidnia, Miri, et al., 2004
Javidnia, K.; Miri, R.; Jafari, A.; Rezai, H., Analysis of the volatile constituents of Nepeta macrosiphon Boiss. grown in Iran, Flavour Fragr. J., 2004, 19, 2, 156-158, https://doi.org/10.1002/ffj.1287 . [all data]

Javidnia, Miri, et al., 2004, 2
Javidnia, K.; Miri, R.; Kamalinejad, M.; Sarkarzadeh, H.; Jamalian, A., Chemical composition of the essential oils of Anthemis altissima L. grown in Iran, Flavour Fragr. J., 2004, 19, 3, 213-216, https://doi.org/10.1002/ffj.1277 . [all data]

Mardarowicz, Wianowska, et al., 2004
Mardarowicz, M.; Wianowska, D.; Dawidowicz, A.L.; Sawicki, R., The influence of sample treatment on SPME extracts from conifers. I. Comparison of terpene composition in Engelmann Spruce (Picea engelmanii) using hydrodistillation, SPME and PLE, Annales Universitatis Mariae Curie-Sklodowska Lublin - Polonia, 2004, 59, 3, 25-42. [all data]

Pino, Marbot, et al., 2004
Pino, J.A.; Marbot, R.; Rosado, A.; Vázquez, C., Volatile constituents of Malay rose apple [Syzygium malaccense (L.) Merr. Perry], Flavour Fragr. J., 2004, 19, 1, 32-35, https://doi.org/10.1002/ffj.1269 . [all data]

Singer, Flach, et al., 2004
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Weissbecker, Holighaus, et al., 2004
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Chen and Ho, 1987
Chen, C.-C.; Ho, C.-T., Gas chromatographic analysis of thermal degradation products of gingerol compounds in steam-distilled oil from ginger (Zingiber officinale Roscoe), J. Chromatogr., 1987, 387, 499-504, https://doi.org/10.1016/S0021-9673(01)94559-5 . [all data]

Golovnya and Uraletz, 1971
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van den Dool and Kratz, 1963
van den Dool, H.; Kratz, P. Dec., A generalization of the retention index system including linear temperature programmed gas-liquid partition chromatography, J. Chromatogr., 1963, 11, 463-471, https://doi.org/10.1016/S0021-9673(01)80947-X . [all data]


Notes

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