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Van Den Dool and Kratz RI, polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20FFAPRTX-WaxDB-WaxDB-Wax
Column length (m) 50.30.60.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.220.250.220.250.32
Phase thickness (μm) 0.250.250.250.50.5
Tstart (C) 60.35.60.40.40.
Tend (C) 220.225.230.250.240.
Heat rate (K/min) 2.10.2.4.7.
Initial hold (min)  5. 5. 
Final hold (min) 20.25.35.15.5.
I 1496.1495.1498.1500.1516.
ReferenceDuquesnoy, Castola, et al., 2007Lozano P.R., Miracle E.R., et al., 2007Paolini, Muselli, et al., 2007Pozo-Bayon M.A., Ruiz-Rodriguez A., et al., 2007Ruiz Perez-Cacho, Mahattanatawee, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10HP-WaxDB-WaxDB-WaxZB-Wax
Column length (m) 30.30.60.30.30.
Carrier gas HeN2HeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.320.25
Phase thickness (μm) 0.50.250.250.50.15
Tstart (C) 70.60.40.40.35.
Tend (C) 220.220.265.265.220.
Heat rate (K/min) 4.5.7.7.5.
Initial hold (min) 7.10.  5.
Final hold (min) 20. 5.5.10.
I 1501.1481.1515.1507.1501.
ReferenceArena, Guarrera, et al., 2006Flamini, Tebano, et al., 2006Gurbuz O., Rouseff J.M., et al., 2006Gurbuz O., Rouseff J.M., et al., 2006Ledauphin, Basset, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Wax 52CBDB-WaxDB-WaxDB-WaxStabilwax
Column length (m) 50.30.30.30.60.
Carrier gas  HeHe He
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm)  0.50.250.250.25
Tstart (C) 60.50.40.40.40.
Tend (C) 220.260.250.200.240.
Heat rate (K/min) 4.4.3.10.3.
Initial hold (min) 5.  3.5.
Final hold (min) 30.5.20.20.10.
I 1492.1515.1472.1483.1497.
ReferenceMahadevan and Farmer, 2006Selli, Rannou, et al., 2006Berlinet, Ducruet, et al., 2005Carunchia Whetstine, Croissant, et al., 2005Cros, Lignot, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10DB-WaxDB-WaxDB-WaxDB-Wax
Column length (m) 60.30.30.30.60.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.250.320.25
Phase thickness (μm) 0.250.250.250.50.25
Tstart (C) 40.40.40.40.70.
Tend (C) 280.250.250.240.230.
Heat rate (K/min) 4.3.3.7.2.
Initial hold (min) 2.   2.
Final hold (min)  20.20.5.20.
I 1505.1485.1485.1508.1511.
ReferenceElmore, Nisyrios, et al., 2005Fanciullino, Gancel, et al., 2005Gancel, Ollitrault, et al., 2005Mahattanatawee, Rouseff, et al., 2005Njoroge, Koaze, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxSupelcowax-10Carbowax 20MMegawaxDB-Wax
Column length (m) 60.60.60.30.30.
Carrier gas HeHeHeHeHelium
Substrate      
Column diameter (mm) 0.220.20.250.250.32
Phase thickness (μm) 0.250.20.250.250.50
Tstart (C) 60.60.45.40.40.
Tend (C) 230.200.250.220.240.
Heat rate (K/min) 2.2.2.2.7.
Initial hold (min)   0.176. 
Final hold (min) 35.10. 10.5.
I 1498.1458.1480.1476.1509.
ReferencePaolini, Costa, et al., 2005Smadja, Rondeau, et al., 2005Verzera, Campisi, et al., 2005Verzera, Trozzi, et al., 2005Bell, 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxHP-WaxHP-WaxDB-WaxDB-Wax
Column length (m) 30.30.30.30.30.
Carrier gas HeN2N2HeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 45.60.60.45.45.
Tend (C) 240.240.220.240.240.
Heat rate (K/min) 3.3.5.6.6.
Initial hold (min) 6. 10.10.10.
Final hold (min) 10.  30.30.
I 1482.1484.1480.1510.1510.
ReferenceDugo, Mondello, et al., 2004Flamini, Cioni, et al., 2004Flamini, Luigi Cioni, et al., 2004Nielsen, Larsen, et al., 2004Nielsen, Larsen, et al., 2004, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxDB-WaxHP-WaxDB-WaxHP-Wax
Column length (m) 30.30.30.30.30.
Carrier gas HeHeN2HeN2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 45.40.60.40.60.
Tend (C) 240.240.220.250.220.
Heat rate (K/min) 3.6.5.3.5.
Initial hold (min) 10.10.10. 10.
Final hold (min) 30.25. 20. 
I 1486.1476.1480.1471.1484.
ReferenceNielsen and Poll, 2004Varming, Petersen, et al., 2004Bader, Caponi, et al., 2003Brat, Rega, et al., 2003Campeol, Flamini, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-WaxInnowaxSupelcowaxSupelcowaxDB-Wax
Column length (m) 30.15.25.25.60.
Carrier gas N2He  N2
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.35.35.35.70.
Tend (C) 220.225.225.225.230.
Heat rate (K/min) 5.4.4.4.2.
Initial hold (min) 10.5.5.5.2.
Final hold (min)  20.10.10.20.
I 1484.1502.1517.1517.1538.
ReferenceCampeol, Flamini, et al., 2003Chisholm, Jell, et al., 2003Chisholm, Wilson, et al., 2003Chisholm, Wilson, et al., 2003Choi, 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase StabilwaxDB-WaxDB-WaxDB-WaxMegawax
Column length (m) 60.60.30.30.30.
Carrier gas HeH2  He
Substrate      
Column diameter (mm) 0.250.320.320.320.25
Phase thickness (μm) 0.250.250.50.50.25
Tstart (C) 40.40.40.35.40.
Tend (C) 240.245.240.240.220.
Heat rate (K/min) 3.1.57.5.2.
Initial hold (min) 5.  5.6.
Final hold (min) 10.20.5.5.10.
I 1497.1485.1510.1503.1476.
ReferenceCros, Vandanjon, et al., 2003Gancel, Ollitrault, et al., 2003Högnadóttir and Rouseff, 2003Rega, Fournier, et al., 2003Verzera, Trozzi, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase ZB-WaxSupelcowax-10BP-20Supelcowax-10DB-Wax
Column length (m) 60.60.50.60.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.250.220.250.32
Phase thickness (μm) 0.250.250.250.250.50
Tstart (C) 40.35.60.35.40.
Tend (C) 220.195.220.195.240.
Heat rate (K/min) 3.2.2.2.7.
Initial hold (min)  5. 5. 
Final hold (min)  90.20.90.5.
I 1490.1503.1492.1503.1499.
ReferenceBrunton, Cronin, et al., 2002Chung, Yung, et al., 2002Lota, de Rocca Serra, et al., 2002Chung, Yung, et al., 2001Lin and Rouseff, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20AT-WaxCP-Wax 52CBDB-WaxDB-Wax
Column length (m) 50.60.60.60.60.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.220.320.250.50.25
Phase thickness (μm) 0.250.250.250.320.25
Tstart (C) 60.65.45.40.70.
Tend (C) 220.250.250.290.230.
Heat rate (K/min) 2.2.2.4.2.
Initial hold (min)  10.0.172.2.
Final hold (min)  60. 5.20.
I 1492.1488.1480.1509.1509.
ReferenceLota, Serra, et al., 2001Pino and Marbot, 2001Verzera, Campisi, et al., 2001Bartley and Jacobs, 2000Choi and Sawamura, 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Wax 52CBBP-20DB-WaxHP-WaxMegawax
Column length (m) 50.50.15.15.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.220.530.530.25
Phase thickness (μm) 0.20.251.1.0.25
Tstart (C) 30.60.40.40.40.
Tend (C) 220.230.220.220.220.
Heat rate (K/min) 2.2.5.5.2.
Initial hold (min) 1.3 3.3.6.
Final hold (min)  35.30.30.10.
I 1475.1492.1523.1514.1476.
ReferenceJensen, Christensen, et al., 2000Lota, de Rocca Serra, et al., 2000Peng, 2000Peng, 2000Verzera, Trozzi, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BP-20Carbowax 20MDB-WaxCarbowax 20MSupelcowax-10
Column length (m) 50.60.30.60.60.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.220.320.320.320.25
Phase thickness (μm) 0.250.4250.25 0.25
Tstart (C) 60.45.40.50.40.
Tend (C) 230.300.220.225.175.
Heat rate (K/min) 2.3.5.1.52.
Initial hold (min)  3.3. 5.
Final hold (min) 35.20. 80.20.
I 1492.1490.1483.1485.1503.
ReferenceLota, Serra, et al., 1999Mondello, Dugo, et al., 1995Frohlich and Schreier, 1990Chen and Ho, 1988Vejaphan, Hsieh, et al., 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPacked
Active phase Supelcowax-10DB-WaxCarbowax 20M
Column length (m) 60.60. 
Carrier gas  He 
Substrate   Celite 545
Column diameter (mm) 0.250.32 
Phase thickness (μm) 0.25  
Tstart (C) 40.50.75.
Tend (C) 175.225.228.
Heat rate (K/min) 2.1.54.6
Initial hold (min) 5.  
Final hold (min) 20.50. 
I 1506.1483.1498.
ReferenceVejaphan, Hsieh, et al., 1988Chen and Ho, 1987van den Dool and Kratz, 1963
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Duquesnoy, Castola, et al., 2007
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Nielsen, Larsen, et al., 2004
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Nielsen, Larsen, et al., 2004, 2
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Nielsen and Poll, 2004
Nielsen, G.S.; Poll, L., Determination of odor active aroma compounds in freshly cut leek (Allium ampeloprasum Var. Bulga) and in long-term stored frozen unblanched and blanched leek slices by gas chromatography olfactometry analysis, J. Agric. Food Chem., 2004, 52, 6, 1642-1646, https://doi.org/10.1021/jf030682k . [all data]

Varming, Petersen, et al., 2004
Varming, C.; Petersen, M.A.; Poll, L., Comparison of isolation methods for the determination of important aroma compounds in black currant (Ribes nigrum L.) juice, using nasal impact frequency profiling, J. Agric. Food Chem., 2004, 52, 6, 1647-1652, https://doi.org/10.1021/jf035133t . [all data]

Bader, Caponi, et al., 2003
Bader, A.; Caponi, C.; Cioni, P.L.; Flamini, G.; Morelli, I., Composition of the essential oil of Ballota undulata, B. nigra ssp. foetida and B. saxatilis, Flavour Fragr. J., 2003, 18, 6, 502-504, https://doi.org/10.1002/ffj.1257 . [all data]

Brat, Rega, et al., 2003
Brat, P.; Rega, B.; Alter, P.; Reynes, M.; Brillouet, J.-M., Distribution of volatile compounds in the pulp, cloud, and serum of freshly squeezed orange juice, J. Agric. Food Chem., 2003, 51, 11, 3442-3447, https://doi.org/10.1021/jf026226y . [all data]

Campeol, Flamini, et al., 2003
Campeol, E.; Flamini, G.; Cioni, P.L.; Morelli, I.; Cremonini, R.; Ceccarini, L., Volatile fractions from three cultivars of Olea eruopaea L. collected in two different seasons, J. Agric. Food Chem., 2003, 51, 7, 1994-1999, https://doi.org/10.1021/jf026025u . [all data]

Chisholm, Jell, et al., 2003
Chisholm, M.G.; Jell, J.A.; Cass, D.M., Jr., Characterization of the major odorants found in the peel oil of Citrus reticulata Blanco cv. Clementine using gas chromatography-olfactometry, Flavour Fragr. J., 2003, 18, 4, 275-281, https://doi.org/10.1002/ffj.1188 . [all data]

Chisholm, Wilson, et al., 2003
Chisholm, M.G.; Wilson, M.A.; Gaskey, G.M., Characterization of aroma volatiles in key lime essential oils (Cirtrus aurantifolia Swingle), Flavour Fragr. J., 2003, 18, 2, 106-115, https://doi.org/10.1002/ffj.1172 . [all data]

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Notes

Go To: Top, Van Den Dool and Kratz RI, polar column, temperature ramp, References