Cyclopentene, 3-methyl-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1HP-PONASE-30SqualaneSqualane
Column length (m) 60.50.100.100.100.
Carrier gas H2H2   
Substrate      
Column diameter (mm) 0.2640.210.50.250.25
Phase thickness (μm) 0.250.5   
Temperature (C) 40.40.80.50.70.
I 610.610.615.605.5606.5
ReferenceLubeck and Sutton, 1984Lubeck and Sutton, 1984Bredael, 1982Bajus, Veselý, et al., 1979Bajus, Veselý, et al., 1979
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 100.27.30.50.67.
I 611.600.600.603.608.
ReferenceBogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m)    100.120.
Carrier gas    Nitrogen or heliumHe
Substrate      
Column diameter (mm)    0.250.25
Phase thickness (μm)      
Temperature (C) 70.80.86.100.100.
I 607.607.610.610.604.
ReferenceBogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978Rang, Orav, et al., 1977Lulova, Leont'eva, et al., 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m) 100.100.100.100.100.
Carrier gas   N2N2 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)      
Temperature (C) 100.80.50.70.27.
I 611.607.603.606.600.00
ReferenceDielmann, Schwengers, et al., 1974Dielmann, Schwengers, et al., 1974Rijks and Cramers, 1974Rijks and Cramers, 1974Schomburg and Dielmann, 1973
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Apiezon LApiezon LSqualaneSqualaneSqualane
Column length (m) 45.45.80.80.80.
Carrier gas      
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm)      
Temperature (C) 100.120.30.60.80.
I 627.633.601.5605.8607.7
ReferenceEisen, Orav, et al., 1972Eisen, Orav, et al., 1972Eisen, Orav, et al., 1972Eisen, Orav, et al., 1972Eisen, Orav, et al., 1972
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPackedPacked
Active phase SqualaneSqualaneSqualaneSE-30Squalane
Column length (m) 80.80.80.6.13.0
Carrier gas    N2N2
Substrate    Chromosorb WEmbacel
Column diameter (mm) 0.250.250.25  
Phase thickness (μm)      
Temperature (C) 30.60.80.75.100.
I 602.606.608.615.609.
ReferenceOrav and Eisen, 1972Orav and Eisen, 1972Orav and Eisen, 1972Robinson and Odell, 1971Robinson and Odell, 1971
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedCapillary
Active phase SqualaneSqualaneSqualaneSqualaneSqualane
Column length (m) 15.15.15.15. 
Carrier gas HeHeHeHe 
Substrate Chromosorb PChromosorb PChromosorb PChromosorb P 
Column diameter (mm) 0.250.250.250.25 
Phase thickness (μm)      
Temperature (C) 27.49.67.86.50.
I 601.604.608.610.607.
ReferenceHively and Hinton, 1968Hively and Hinton, 1968Hively and Hinton, 1968Hively and Hinton, 1968Schomburg, 1966
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lubeck and Sutton, 1984
Lubeck, A.J.; Sutton, D.L., Kovats Retention Indices of Selected Olefins on Bonded Phase Fused Silica Capillaries, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1984, 7, 9, 542-544, https://doi.org/10.1002/jhrc.1240070913 . [all data]

Bredael, 1982
Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1982, 5, 6, 325-328, https://doi.org/10.1002/jhrc.1240050610 . [all data]

Bajus, Veselý, et al., 1979
Bajus, M.; Veselý, V.; Leclercq, P.A.; Rijks, J.A., Steam cracking of hydrocarbons. 2. Pyrolysis of methylcyclohexane, Ind. Eng. Chem. Prod. Res. Dev., 1979, 18, 2, 135-142, https://doi.org/10.1021/i360070a012 . [all data]

Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]

Rang, Orav, et al., 1977
Rang, S.; Orav, A.; Kuningas, K.; Eisen, O., Capillary Gas Chromatography of Monosubstituted Cyclopentenes and Cyclohexenes, Chromatographia, 1977, 10, 3, 115-122, https://doi.org/10.1007/BF02297862 . [all data]

Lulova, Leont'eva, et al., 1976
Lulova, N.I.; Leont'eva, S.A.; Timofeeva, A.N., Gas-chromatographic method of determination of individual hydrocarbons in catalytic cracking gasolines in Proceedings of All-Union Research Institute on Oil Processes. Vol.18, All-Union Research Institute on Oil Processes, Moscow, 1976, 30-53. [all data]

Dielmann, Schwengers, et al., 1974
Dielmann, G.; Schwengers, D.; Schomburg, G., Gas-chromatographische Retentionsdaten und Strukture chemischer Verbindungen Gesättigte und ungesättigte alkylsubstituierte Cyclopentane und Methylcyclopentane, Chromatographia, 1974, 7, 5, 215-224, https://doi.org/10.1007/BF02321771 . [all data]

Rijks and Cramers, 1974
Rijks, J.A.; Cramers, C.A., High precision capillary gas chromatography of hydrocarbons, Chromatographia, 1974, 7, 3, 99-106, https://doi.org/10.1007/BF02269819 . [all data]

Schomburg and Dielmann, 1973
Schomburg, G.; Dielmann, G., Identification by means of retention parameters, J. Chromatogr. Sci., 1973, 11, 3, 151-159, https://doi.org/10.1093/chromsci/11.3.151 . [all data]

Eisen, Orav, et al., 1972
Eisen, O.; Orav, A.; Rang, S., Identifizierung von Normal-Alkenen, Cyclopentenen und -Hexenen mittels Kapillar-Gas-Chromatographie. Identification des alcènes, cyclopentènes et -hexènes à l'aide de la chromatogrpahie en phase gazeuse sur colonne capillaire, Chromatographia, 1972, 5, 11, 229-239, https://doi.org/10.1007/BF02270600 . [all data]

Orav and Eisen, 1972
Orav, A.; Eisen, O., The retention indexes for alkenes, alkynes and cyclenes on capillary columns, Izv. Akad. Nauk Est. SSR, Khim. Geol., 1972, 21, 1, 39-47. [all data]

Robinson and Odell, 1971
Robinson, P.G.; Odell, A.L., A system of standard retention indices and its uses. The characterisation of stationary phases and the prediction of retention indices, J. Chromatogr., 1971, 57, 1-10, https://doi.org/10.1016/0021-9673(71)80001-8 . [all data]

Hively and Hinton, 1968
Hively, R.A.; Hinton, R.E., Variation of the retention index with temperature on squalane substrates, J. Gas Chromatogr., 1968, 6, 4, 203-217, https://doi.org/10.1093/chromsci/6.4.203 . [all data]

Schomburg, 1966
Schomburg, G., Gaschromatographische Retentionsdaten und struktur chemischer verbindungen. III. Alkylverzweigte und ungesättigte cyclische Kohlenwasserstoffe, J. Chromatogr., 1966, 23, 18-41, https://doi.org/10.1016/S0021-9673(01)98653-4 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References