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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-102.0 ± 0.1kcal/molCcbMosselman and Dekker, 1975ALS
Deltafliquid-102.30 ± 0.26kcal/molCcbGundry, Harrop, et al., 1969Heat of formation derived by Cox and Pilcher, 1970; ALS
Deltafliquid-101.62 ± 0.27kcal/molCcbChao and Rossini, 1965see Rossini, 1934; ALS
Deltafliquid-103.96 ± 0.64kcal/molCcbGreen, 1960ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1265.3 ± 0.1kcal/molCcbMosselman and Dekker, 1975Corresponding «DELTA»fliquid = -102.0 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-1265.65 ± 0.24kcal/molCcbChao and Rossini, 1965see Rossini, 1934; Corresponding «DELTA»fliquid = -101.59 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-1263.31 ± 0.64kcal/molCcbGreen, 1960Corresponding «DELTA»fliquid = -103.93 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-1263.3kcal/molCcbVerkade and Coops, 1927Corrected for 298 and 1 atm.; Corresponding «DELTA»fliquid = -103.9 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
72.66298.15Vesely, Barcal, et al., 1989T = 298.15 to 318.15 K.; DH
78.75303.2Naziev, Bashirov, et al., 1986T = 303.2 to 448 K. p = 0.1 MPa. Unsmoothed experimental datum given as 2.53 kJ/kg*K.; DH
73.028298.15Zegers and Somsen, 1984DH
76.08310.67Griigo'ev, Yanin, et al., 1979T = 310 to 452 K. p = 0.98 bar.; DH
74.59298.Hutchinson and Bailey, 1959DH
68.00286.0Cline and Andrews, 1931T = 102 to 286 K. Value is unsmoothed experimental datum.; DH
77.51298.von Reis, 1881T = 291 to 470 K.; DH


Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H., Enthalpies of formation of n-alkan-1-ols, J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]

Gundry, Harrop, et al., 1969
Gundry, H.A.; Harrop, D.; Head, A.J.; Lewis, G.B., Thermodynamic properties of organic oxygen compounds. 21. Enthalpies of combustion of benzoic acid, pentan-1-ol, octan-1-ol, and hexadecan-1-ol, J. Chem. Thermodyn., 1969, 1, 321-332. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Chao and Rossini, 1965
Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

Rossini, 1934
Rossini, F.D., Heats of combustion and of formation of the normal aliphatic alcohols in the gaseous and liquid states, and the energies of their atomic linkages, J. Res. NBS, 1934, 13, 189-197. [all data]

Green, 1960
Green, J.H.S., Revision of the values of the heats of formation of normal alcohols, Chem. Ind. (London), 1960, 1215-1216. [all data]

Verkade and Coops, 1927
Verkade, P.E.; Coops, J., Jr., Calorimetric researches XIV. Heats of combustion of successive members of homologous series: the normal primary aliphatic alcohols, Recl. Trav. Chim. Pays-Bas, 1927, 46, 903-917. [all data]

Vesely, Barcal, et al., 1989
Vesely, F.; Barcal, P.; Zabransky, M.; Svoboda, V., Heat capacities of 4-methyl-2-pentanone, 2,6-dimethyl-4-heptanone, 1-hexanol, 1-heptanol, and 1-octanol in the temperature range 298-318 K, Collect. Czech. Chem. Commun., 1989, 54, 602-607. [all data]

Naziev, Bashirov, et al., 1986
Naziev, Ya.M.; Bashirov, M.M.; Badalov, Yu.A., Experimental study of isobaric specific heat of higher alcohols at high pressures, Inzh.-Fiz. Zhur., 1986, 51, 998-1004. [all data]

Zegers and Somsen, 1984
Zegers, H.C.; Somsen, G., Partial molar volumes and heat capacities in (dimethylformamide + an n-alkanol), J. Chem. Thermodynam., 1984, 16, 225-235. [all data]

Griigo'ev, Yanin, et al., 1979
Griigo'ev, B.A.; Yanin, G.S.; Rastorguev, Yu.L.; Thermophysical parameters of alcohols, Tr. GIAP, 54, 1979, 57-64. [all data]

Hutchinson and Bailey, 1959
Hutchinson, E.; Bailey, L.G., A thermodynamic study of colloidal electrolyte solutions. II. Heat capacities of solubilized systems, experimental, Z. Physik. Chem. [N.G.], 1959, 21, 30-37. [all data]

Cline and Andrews, 1931
Cline, J.K.; Andrews, D.H., Thermal energy studies. III. The octanols, J. Am. Chem. Soc., 1931, 53, 3668-3673. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]


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