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Nonane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-54.57kcal/molN/AGood, 1969Value computed using «DELTA»fHliquid° value of -274.7±1 kj/mol from Good, 1969 and «DELTA»vapH° value of 46.43 kj/mol from missing citation.; DRB
Quantity Value Units Method Reference Comment
gas121.06 ± 0.24cal/mol*KN/AScott D.W., 1974This reference does not contain the original experimental data. Experimental entropy value is based on the results [ Messerly J.F., 1967] for S(liquid).; GT

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
38.700200.Scott D.W., 1974, 2Recommended values were obtained from the consistent correlation scheme for alkanes [ Scott D.W., 1974, Scott D.W., 1974, 2]. This approach gives a good agreement with experimental data available for alkanes. However, large uncertainties could be expected at high temperatures.; GT
47.029273.15
50.3 ± 0.1298.15
50.531300.
64.250400.
76.850500.
87.500600.
96.401700.
103.70800.
109.90900.
115.101000.
119.501100.
123.401200.
127.001300.
130.001400.
133.001500.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-65.65 ± 0.24kcal/molCcrGood, 1969ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1463.96 ± 0.13kcal/molCcrGood, 1969Corresponding «DELTA»fliquid = -65.65 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-1463.89 ± 0.27kcal/molCcbProsen and Rossini, 1944Corresponding «DELTA»fliquid = -65.72 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-1462.7kcal/molCcbJessup, 1937Corresponding «DELTA»fliquid = -66.95 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid94.089cal/mol*KN/AFinke, Gross, et al., 1954DH
liquid93.91cal/mol*KN/AHuffman, Parks, et al., 1931Extrapolation below 90 K, 83.09 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
69.833318.15Banipal, Garg, et al., 1991T = 318 to 373 K. p = 0.1 MPa.; DH
67.959298.15Trejo, Costas, et al., 1991DH
68.059298.15Andreoli-Ball, Patterson, et al., 1988DH
67.83298.15Wilhelm, Inglese, et al., 1982DH
70.08323.Zaripov, 1982T = 298, 323, 363 K.; DH
67.88298.15Grolier, Hamedi, et al., 1979DH
77.01350.Swietoslawski and Zielenkiewicz, 1958Mean value over the temperature range 22 to 129°C.; DH
67.971298.15Finke, Gross, et al., 1954T = 12 to 320 K.; DH
67.880298.15Osborne and Ginnings, 1947T = 278 to 318 K.; DH
67.09297.9Huffman, Parks, et al., 1931T = 93 to 298 K. Value is unsmoothed experimental datum.; DH
67.21299.1Parks, Huffman, et al., 1930T = 224 to 299 K. Value is unsmoothed experimental datum.; DH

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2Hydrogen + 2-Nonyne = Nonane

By formula: 2H2 + C9H16 = C9H20

Quantity Value Units Method Reference Comment
Deltar-65.08 ± 0.51kcal/molChydRogers, Dagdagan, et al., 1979liquid phase; solvent: Hexane

2Hydrogen + 3-Nonyne = Nonane

By formula: 2H2 + C9H16 = C9H20

Quantity Value Units Method Reference Comment
Deltar-64.69 ± 0.34kcal/molChydRogers, Dagdagan, et al., 1979liquid phase; solvent: Hexane

2Hydrogen + 4-Nonyne = Nonane

By formula: 2H2 + C9H16 = C9H20

Quantity Value Units Method Reference Comment
Deltar-64.96 ± 0.43kcal/molChydRogers, Dagdagan, et al., 1979liquid phase; solvent: Hexane

1-Nonene + Hydrogen = Nonane

By formula: C9H18 + H2 = C9H20

Quantity Value Units Method Reference Comment
Deltar-29.71 ± 0.24kcal/molChydRogers and Skanupong, 1974liquid phase; solvent: Hexane

2Hydrogen + 1-Nonyne = Nonane

By formula: 2H2 + C9H16 = C9H20

Quantity Value Units Method Reference Comment
Deltar-69.54 ± 0.46kcal/molChydRogers, Dagdagan, et al., 1979liquid phase; solvent: Hexane

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Good, 1969
Good, W.D., Enthalpies of combustion and formation of 11 isomeric nonanes, J. Chem. Eng. Data, 1969, 14, 231-235. [all data]

Scott D.W., 1974
Scott D.W., Correlation of the chemical thermodynamic properties of alkane hydrocarbons, J. Chem. Phys., 1974, 60, 3144-3165. [all data]

Messerly J.F., 1967
Messerly J.F., Low-temperature thermal data for n-pentane, n-heptadecane, and n-octadecane. Revised thermodynamic functions for the n-alkanes, C5-C18, J. Chem. Eng. Data, 1967, 12, 338-346. [all data]

Scott D.W., 1974, 2
Scott D.W., Chemical Thermodynamic Properties of Hydrocarbons and Related Substances. Properties of the Alkane Hydrocarbons, C1 through C10 in the Ideal Gas State from 0 to 1500 K. U.S. Bureau of Mines, Bulletin 666, 1974. [all data]

Prosen and Rossini, 1944
Prosen, E.J.; Rossini, F.D., Heats of combustion of eight normal paraffin hydrocarbons in the liquid state, J. Res. NBS, 1944, 33, 255-272. [all data]

Jessup, 1937
Jessup, R.S., Heats of combustion of the liquid normal paraffin hydrocarbons from hexane to dodecane, J. Res. NBS, 1937, 18, 114-128. [all data]

Finke, Gross, et al., 1954
Finke, H.L.; Gross, M.E.; Waddington, G.; Huffman, H.M., Low-temperature thermal data for the nine normal paraffin hydrocarbons from octane to hexadecane, J. Am. Chem. Soc., 1954, 76, 333-341. [all data]

Huffman, Parks, et al., 1931
Huffman, H.M.; Parks, G.S.; Barmore, M., Thermal data on organic compounds. X. Further studies on the heat capacities, entropies and free energies of hydrocarbons, J. Am. Chem. Soc., 1931, 53, 3876-3888. [all data]

Banipal, Garg, et al., 1991
Banipal, T.S.; Garg, S.K.; Ahluwalia, J.C., Heat capacities and densities of liquid n-octane, n-nonane, n-decane, and n-hexadecane at temperatures from 318.15 to 373.15 K and at pressures up to 10 MPa, J. Chem. Thermodynam., 1991, 23, 923-931. [all data]

Trejo, Costas, et al., 1991
Trejo, L.M.; Costas, M.; Patterson, D., Excess heat capacity of organic mixtures, Internat. DATA Series, Selected Data Mixt., 1991, Ser. [all data]

Andreoli-Ball, Patterson, et al., 1988
Andreoli-Ball, L.; Patterson, D.; Costas, M.; Caceres-Alonso, M., Heat capacity and corresponding states in alkan-1-ol-n-alkane systems, J. Chem. Soc., Faraday Trans. 1, 1988, 84(11), 3991-4012. [all data]

Wilhelm, Inglese, et al., 1982
Wilhelm, E.; Inglese, A.; Quint, J.R.; Grolier, J.-P.E., Molar excess volumes and excess heat capacities of (1,2,4-trichlorobenzene + an alkane), J. Chem. Thermodynam., 1982, 14, 303-308. [all data]

Zaripov, 1982
Zaripov, Z.I., Experimental study of the isobaric heat capacity of liquid organic compounds with molecular weights of up to 4000 a.e.m., 1982, Teplomassoobmen Teplofiz. [all data]

Grolier, Hamedi, et al., 1979
Grolier, J-P.E.; Hamedi, M.H.; Wilhelm, E.; Kehiaian, H.V., Excess heat capacities of binary mixtures of carbon tetrachloride with n-alkanes at 298.15 K, Thermochim. Acta, 1979, 31, 79-84. [all data]

Swietoslawski and Zielenkiewicz, 1958
Swietoslawski, W.; Zielenkiewicz, A., Mean specific heat of some ternary azeotropes, Bull. Acad. Pol. Sci. Ser. Sci. Chim., 1958, 6, 365-366. [all data]

Osborne and Ginnings, 1947
Osborne, N.S.; Ginnings, D.C., Measurements of heat of vaporization and heat capacity of a number of hydrocarbons, J. Res. NBS, 1947, 39, 453-477. [all data]

Parks, Huffman, et al., 1930
Parks, G.S.; Huffman, H.M.; Thomas, S.B., Thermal data on organic compounds. VI. The heat capacities, entropies and free energies of some saturated, non-benzenoid hydrocarbons, J. Am. Chem. Soc., 1930, 52, 1032-1041. [all data]

Rogers, Dagdagan, et al., 1979
Rogers, D.W.; Dagdagan, O.A.; Allinger, N.L., Heats of hydrogenation and formation of linear alkynes and a molecular mechanics interpretation, J. Am. Chem. Soc., 1979, 101, 671-676. [all data]

Rogers and Skanupong, 1974
Rogers, D.W.; Skanupong, S., Heats of hydrogenation of sixteen terminal monoolefins. The alternating effect, J. Phys. Chem., 1974, 78, 2569-2572. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References