Ethanol, 2-(2-methoxyethoxy)-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-670.3kJ/molCcbSimonetta, 1947Author value for hf298-condensed=-173 kcal/mol
Quantity Value Units Method Reference Comment
Δcliquid-3010.kJ/molCcbSimonetta, 1947Author value for hf298-condensed=-173 kcal/mol; Corresponding Δfliquid = -669. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil466.2KN/AWeast and Grasselli, 1989BS
Tboil466.1KN/ALecat, 1947Uncertainty assigned by TRC = 0.7 K; TRC
Tboil502.4KN/AWhitmore and Lieber, 1935Uncertainty assigned by TRC = 2.5 K; TRC
Tboil471.KN/ADavidson, 1926Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tc672.KN/AWilson, Wilson, et al., 1996Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Pc36.70barN/AWilson, Wilson, et al., 1996Uncertainty assigned by TRC = 1.50 bar; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
51.9400.AStephenson and Malanowski, 1987Based on data from 385. - 466. K. See also Dykyj, Seprakova, et al., 1957 and Dykyj, 1972.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
385.5 - 466.4.818691946.184-62.374Dykyj, Seprakova, et al., 1957, 2Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 2007
NIST MS number 352037

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References

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Simonetta, 1947
Simonetta, M., II problema termico nella catena di reazioni tra ossido di etilene ed alcool metilico, Chimi. Ind. (Milan), 1947, 29, 37-39. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Lecat, 1947
Lecat, M., Some azeotropes of which one constituant is heterocyclic nitrogen, Ann. Soc. Sci. Bruxelles, Ser. 1, 1947, 61, 73. [all data]

Whitmore and Lieber, 1935
Whitmore, W.F.; Lieber, E., Identification of Certain SOlvens by the Xanthate Reaction, Ind. Eng. Chem., Anal. Ed., 1935, 7, 127-9. [all data]

Davidson, 1926
Davidson, J.G., The glycol ethers and their use in the lacquer industry, Ind. Eng. Chem., 1926, 18, 669. [all data]

Wilson, Wilson, et al., 1996
Wilson, L.C.; Wilson, H.L.; Wilding, W.V.; Wilson, G.M., Critical Point Measurements for Fourteen Compounds by a Static Method and a Flow Method, J. Chem. Eng. Data, 1996, 41, 1252-4. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, Seprakova, et al., 1957
Dykyj, J.; Seprakova, M.; Paulech, J., Chem. Zvesti, 1957, 11, 461. [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Dykyj, Seprakova, et al., 1957, 2
Dykyj, J.; Seprakova, M.; Maulech, J., Physikalische Eigenschaften des Athylenglykols und Seiner Derivate (II) Dampftensionen von Alkoxyathanolen und Aneren Drivaten des Athylenglykols, Chem. Zvesti, 1957, 11, 461-466. [all data]


Notes

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