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1-Octene

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Kovats' RI, non-polar column, isothermal

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedCapillaryCapillaryPackedCapillary
Active phase PMS-1000Petrocol DHSqualaneC78, Branched paraffinSqualane
Column length (m) 2.150.93.3.3 
Carrier gas N2H2HeHe 
Substrate Chromaton N-AW-DMCS    
Column diameter (mm)  0.250.25  
Phase thickness (mum)  1.   
Temperature (C) 90.30.30.130.100.
I 786.788.3780.4784.9783.
ReferenceArutyunov, Kudryashov, et al., 2004Soják, Addová, et al., 2004Soják, Addová, et al., 2004Dallos, Sisak, et al., 2000Heinzen, Soares, et al., 1999
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPackedPacked
Active phase DB-1DB-1SqualaneC78, Branched paraffinApolane
Column length (m) 10.10. 3.33.7
Carrier gas HeHe   
Substrate    Chromosorb G HP 
Column diameter (mm) 0.250.25   
Phase thickness (mum) 0.250.25   
Temperature (C) 140.60.25.130.130.
I 789.788.780.785.3786.
ReferenceBeens, Tijssen, et al., 1998Beens, Tijssen, et al., 1998Hilal, Carreira, et al., 1994Reddy, Dutoit, et al., 1992Dutoit, 1991
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Methyl SiliconeMethyl SiliconeOV-101OV-101OV-101
Column length (m) 50.50.   
Carrier gas      
Substrate      
Column diameter (mm) 0.200.20   
Phase thickness (mum)      
Temperature (C) 40.80.40.60.80.
I 788.789.788.789.789.
ReferenceTakeda, 1991Takeda, 1991Laub and Purnell, 1988Laub and Purnell, 1988Laub and Purnell, 1988
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101SqualaneSqualane
Column length (m) 50.100.100.100.100.
Carrier gas HeN2N2N2N2
Substrate      
Column diameter (mm) 0.250.270.270.250.25
Phase thickness (mum)  0.90.9  
Temperature (C) 110.50.70.50.70.
I 789.788.3789.781.781.8
ReferenceRang, Kuningas, et al., 1987Boneva and Dimov, 1986Boneva and Dimov, 1986Boneva and Dimov, 1986Boneva and Dimov, 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedCapillaryCapillaryPacked
Active phase OV-1SE-30DB-1HP-PONASE-30
Column length (m) 55.3.60.50.3.
Carrier gas N2 H2H2Ar
Substrate     Gas Chrom Q (80-100 mesh)
Column diameter (mm) 0.21 0.2640.21 
Phase thickness (mum) 0.35 0.250.5 
Temperature (C) 100.42.40.40.150.
I 789.0788.788.788.790.
ReferenceAnders, Anders, et al., 1985Rudenko, Mal'tsev, et al., 1985Lubeck and Sutton, 1984Lubeck and Sutton, 1984Tiess, 1984
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-3OV-3OV-3OV-3OV-3
Column length (m)      
Carrier gas      
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Temperature (C) 30.40.50.60.70.
I 792.5792.6792.7792.8792.9
ReferenceChien, Furio, et al., 1983Chien, Furio, et al., 1983Chien, Furio, et al., 1983Chien, Furio, et al., 1983Chien, Furio, et al., 1983
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedCapillaryCapillaryCapillary
Active phase OV-3SE-30SE-30SE-30OV-1
Column length (m)  2.100.100. 
Carrier gas     H2
Substrate  Gaschrom Q   
Column diameter (mm)   0.50.5 
Phase thickness (mum)      
Temperature (C) 80.100.130.80.30.
I 793.0790.789.789.788.4
ReferenceChien, Furio, et al., 1983Winskowski, 1983Bredael, 1982Bredael, 1982Chien, Kopecni, et al., 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1OV-1OV-1OV-1OV-1
Column length (m)      
Carrier gas H2H2H2H2H2
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Temperature (C) 40.50.60.70.80.
I 788.6788.8789.786.7789.4
ReferenceChien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-30SE-30SE-30SE-30SE-30
Column length (m)      
Carrier gas H2H2H2H2H2
Substrate      
Column diameter (mm)      
Phase thickness (mum)      
Temperature (C) 30.40.50.60.70.
I 788.1787.7787.6787.3787.
ReferenceChien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981Chien, Kopecni, et al., 1981
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPackedCapillary
Active phase SE-30OV-1SqualaneSqualaneSqualane
Column length (m)  150.80.  
Carrier gas H2He   
Substrate      
Column diameter (mm)  0.500.23  
Phase thickness (mum)      
Temperature (C) 80.60.50.80.50.
I 786.6790.781.6782.781.
ReferenceChien, Kopecni, et al., 1981Nijs and Jacobs, 1981Welsch, Engewald, et al., 1978Chrétien and Dubois, 1977Chretien and Dubois, 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPackedCapillaryCapillary
Active phase SqualaneSqualaneApolaneSqualaneSqualane
Column length (m) 120.120.2.450.50.
Carrier gas HeHeHe  
Substrate   Chromosorb  
Column diameter (mm) 0.250.25 0.250.25
Phase thickness (mum)      
Temperature (C) 100.100.70.60.60.
I 782.6784.783.7782.782.
ReferenceLulova, Leont'eva, et al., 1976Lulova, Leont'eva, et al., 1976Riedo, Fritz, et al., 1976Ryba, 1976Ryba, 1976
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedCapillaryCapillaryCapillary
Active phase SqualaneSqualaneSqualaneSqualaneOV-101
Column length (m) 120.1.100.100.25.
Carrier gas HeN2N2N2N2
Substrate  DCMS-treated Celite   
Column diameter (mm) 0.25 0.250.250.25
Phase thickness (mum)     1.39
Temperature (C) 55.100.50.70.50.
I 784.784.781.782.788.
ReferenceLulova, Leont'eva, et al., 1975Vernon and Edwards, 1975Rijks and Cramers, 1974Rijks and Cramers, 1974Pacáková, Hoch, et al., 1973
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101SqualaneSqualaneSqualaneSqualane
Column length (m) 25.100.100.100. 
Carrier gas N2    
Substrate      
Column diameter (mm) 0.250.250.250.25 
Phase thickness (mum) 1.39    
Temperature (C) 60.80.80.80.100.
I 788.782.67782.67782.7783.
ReferencePacáková, Hoch, et al., 1973Schomburg and Dielmann, 1973Schomburg and Dielmann, 1973, 2Schomburg and Dielmann, 1973, 2Sojak, Hrivnak, et al., 1973
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SqualaneSqualaneApiezon LSqualaneSqualane
Column length (m)   45.80.80.
Carrier gas      
Substrate      
Column diameter (mm)   0.250.250.25
Phase thickness (mum)      
Temperature (C) 115.86.100.80.80.
I 783.782.789.2781.4781.
ReferenceSojak, Hrivnak, et al., 1973Sojak, Hrivnak, et al., 1973Eisen, Orav, et al., 1972Eisen, Orav, et al., 1972Orav and Eisen, 1972
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryPackedPacked
Active phase SqualaneSqualaneSqualaneApiezon LApiezon L
Column length (m) 200.200.91.42.32.3
Carrier gas N2N2N2N2N2
Substrate    DCMS-treated Chromosorb WDCMS-treated Chromosorb W
Column diameter (mm) 0.20.20.25  
Phase thickness (mum)      
Temperature (C) 115.86.40.100.150.
I 782.9782.3783.786.790.
ReferenceSoják and Bucinská, 1970Soják and Bucinská, 1970Matukuma, 1969Brown, Chapman, et al., 1968Brown, Chapman, et al., 1968
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedPacked
Active phase SqualaneApiezon LApiezon L
Column length (m) 100.2.252.25
Carrier gas Ar  
Substrate  CeliteCelite
Column diameter (mm)    
Phase thickness (mum)    
Temperature (C) 70.130.190.
I 782.783.779.
ReferenceSchomburg, 1967Wehrli and Kováts, 1959Wehrli and Kováts, 1959
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arutyunov, Kudryashov, et al., 2004
Arutyunov, Y.I.; Kudryashov, S.Y.; Onuchak, L.A., Analysis of Mixtures Containing Unknown Components by Gas Chromatography: Determination of Molecular Mass, J. Anal. Chem. USSR (Engl. Transl.), 2004, 59, 4, 358-365. [all data]

Soják, Addová, et al., 2004
Soják, L.; Addová, G.; Kubinec, R.; Kraus, A.; Bohác, A., Capillary gas chromatography-mass spectrometry of all 93 acyclic octenes and their identification in fluid catalytic cracked gasoline, J. Chromatogr. A, 2004, 1025, 2, 237-253, https://doi.org/10.1016/j.chroma.2003.10.112 . [all data]

Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E., Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups, J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0 . [all data]

Heinzen, Soares, et al., 1999
Heinzen, V.E.F.; Soares, M.F.; Yunes, R.A., Semi-empirical topological method for the prediction of the chromatographic retention of cis- and trans-alkene isomers and alkanes, J. Chromatogr. A, 1999, 849, 2, 495-506, https://doi.org/10.1016/S0021-9673(99)00530-0 . [all data]

Beens, Tijssen, et al., 1998
Beens, J.; Tijssen, R.; Blomberg, J., Prediction of comprehensive two-dimensional gas chromatographic separations. A theoretical and practical exercise, J. Chromatogr. A, 1998, 822, 2, 233-251, https://doi.org/10.1016/S0021-9673(98)00649-9 . [all data]

Hilal, Carreira, et al., 1994
Hilal, S.H.; Carreira, L.A.; Karickhoff, S.W.; Melton, C.M., Estimation of Gas-Liquid Chromatographic Retention Times from Molecular Structure, J. Chromatogr. A, 1994, 662, 2, 269-280, https://doi.org/10.1016/0021-9673(94)80515-6 . [all data]

Reddy, Dutoit, et al., 1992
Reddy, K.S.; Dutoit, J.-Cl.; Kovats, E. sz., Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr., 1992, 609, 1-2, 229-259, https://doi.org/10.1016/0021-9673(92)80167-S . [all data]

Dutoit, 1991
Dutoit, J., Gas chromatographic retention behaviour of some solutes on structurally similar polar and non-polar stationary phases, J. Chromatogr., 1991, 555, 1-2, 191-204, https://doi.org/10.1016/S0021-9673(01)87179-X . [all data]

Takeda, 1991
Takeda, I., Use of literature values of temperature programmed retention indexes in qualitative analysis by isothermal gas chromatography, J. Hi. Res. Chromatogr., 1991, 14, 12, 824-828, https://doi.org/10.1002/jhrc.1240141209 . [all data]

Laub and Purnell, 1988
Laub, R.J.; Purnell, J.H., Specific retention volumes, retention indices, and family-plot regressions of aliphatic, alicyclic, and aromatic hydrocarbon solutes with OV-101 poly (dimethylsiloxane) stationary phase, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1988, 11, 9, 649-660, https://doi.org/10.1002/jhrc.1240110908 . [all data]

Rang, Kuningas, et al., 1987
Rang, S.; Kuningas, K.; Strenze, T.; Orav, A.; Eisen, O., Retention and Thermodynamics of Solution of n-Alkenes in OV-101, J. Chromatogr., 1987, 406, 75-80, https://doi.org/10.1016/S0021-9673(00)94018-4 . [all data]

Boneva and Dimov, 1986
Boneva, S.; Dimov, N., Gas Chromatographic Retention Indices for Alkenes on OV-101 and Squalane Capillary Columns, Chromatographia, 1986, 21, 3, 149-151, https://doi.org/10.1007/BF02311743 . [all data]

Anders, Anders, et al., 1985
Anders, G.; Anders, K.; Engewald, W., Identification of non-branched alkenylcycloalkanes with a terminal double bond from retention index increments, Chromatographia, 1985, 20, 2, 83-86, https://doi.org/10.1007/BF02280602 . [all data]

Rudenko, Mal'tsev, et al., 1985
Rudenko, G.I.; Mal'tsev, V.V.; Studenichnik, V.N.; Ustinov, E.P., Gas chromatographic analysis of volatile substances evolved into atmosphere from polymer materials, Zh. Anal. Khim., 1985, 40, 6, 1119-1127. [all data]

Lubeck and Sutton, 1984
Lubeck, A.J.; Sutton, D.L., Kovats Retention Indices of Selected Olefins on Bonded Phase Fused Silica Capillaries, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1984, 7, 9, 542-544, https://doi.org/10.1002/jhrc.1240070913 . [all data]

Tiess, 1984
Tiess, D., Gaschromatographische Retentionsindices von 125 leicht- bis mittelflüchtigen organischen Substanzen toxikologisch-analytischer Relevanz auf SE-30, Wiss. Z. Wilhelm-Pieck-Univ. Rostock Math. Naturwiss. Reihe, 1984, 33, 6-9. [all data]

Chien, Furio, et al., 1983
Chien, C.-F.; Furio, D.L.; Kopecni, M.M.; Laub, R.J., Specific retention volumes and retention indices of selected hydrocarbon solutes with OV-3, OV-7, OV-11, OV-17, OV-22, and OV-25 polymethylphenylsiloxane solvents, J. Hi. Res. Chromatogr., 1983, 6, 12, 669-679, https://doi.org/10.1002/jhrc.1240061207 . [all data]

Winskowski, 1983
Winskowski, J., Gaschromatographische Identifizierung von Stoffen anhand von Indexziffem und unterschiedlichen Detektoren, Chromatographia, 1983, 17, 3, 160-165, https://doi.org/10.1007/BF02271041 . [all data]

Bredael, 1982
Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1982, 5, 6, 325-328, https://doi.org/10.1002/jhrc.1240050610 . [all data]

Chien, Kopecni, et al., 1981
Chien, C.-F.; Kopecni, M.M.; Laub, R.J., Specific Retention Volumes and Retention Indices of Selected Hydrocarbon Solutes with OV-1 and SE-30 Polydimethylsiloxane Solvents, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1981, 4, 10, 539-543, https://doi.org/10.1002/jhrc.1240041017 . [all data]

Nijs and Jacobs, 1981
Nijs, H.H.; Jacobs, P.A., On-Line Single Run Analysis of Effluents from a Fischer-Tropsch Reactor, J. Chromatogr. Sci., 1981, 19, 1, 40-45, https://doi.org/10.1093/chromsci/19.1.40 . [all data]

Welsch, Engewald, et al., 1978
Welsch, Th.; Engewald, W.; Berger, P., IX. Das gas-chromatographische Retentionsverhalten isomerer Octine and Octadiine, Chromatographia, 1978, 11, 1, 5-9, https://doi.org/10.1007/BF02262945 . [all data]

Chrétien and Dubois, 1977
Chrétien, J.R.; Dubois, J.E., Topological analysis of gas-liquid chromatographic behavior of alkenes, Anal. Chem., 1977, 49, 6, 747-756, https://doi.org/10.1021/ac50014a021 . [all data]

Chretien and Dubois, 1976
Chretien, J.R.; Dubois, J.-E., New Perspectives in the Prediction of Kovats Indices, J. Chromatogr., 1976, 126, 171-189, https://doi.org/10.1016/S0021-9673(01)84071-1 . [all data]

Lulova, Leont'eva, et al., 1976
Lulova, N.I.; Leont'eva, S.A.; Timofeeva, A.N., Gas-chromatographic method of determination of individual hydrocarbons in catalytic cracking gasolines in Proceedings of All-Union Research Institute on Oil Processes. Vol.18, All-Union Research Institute on Oil Processes, Moscow, 1976, 30-53. [all data]

Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Chromatogr., 1976, 126, 63-83, https://doi.org/10.1016/S0021-9673(01)84063-2 . [all data]

Ryba, 1976
Ryba, M., Unlösliche Restfilme er stationären Flüssigkeit in gas-chromatographischen Glaskapillaren, Chromatographia, 1976, 9, 3, 105-112, https://doi.org/10.1007/BF02330376 . [all data]

Lulova, Leont'eva, et al., 1975
Lulova, N.I.; Leont'eva, S.A.; Fedosova, A.K.; Kvasova, V.A., Individual composition of hydrocarbons in naphthas from secondary processes, Chem. Technol. Fuels Oils (Engl. Transl.), 1975, 11, 1/2, 59-64, https://doi.org/10.1007/BF00717315 . [all data]

Vernon and Edwards, 1975
Vernon, F.; Edwards, G.T., Gas-liquid chromatography on fluorinated stationary phases. I. Hydrocarbons and fluorocarbons, J. Chromatogr., 1975, 110, 1, 73-80, https://doi.org/10.1016/S0021-9673(00)91212-3 . [all data]

Rijks and Cramers, 1974
Rijks, J.A.; Cramers, C.A., High precision capillary gas chromatography of hydrocarbons, Chromatographia, 1974, 7, 3, 99-106, https://doi.org/10.1007/BF02269819 . [all data]

Pacáková, Hoch, et al., 1973
Pacáková, V.; Hoch, K.; Smolková, E., The Effect of Instrumentation on the Precision of Retention Indexes, Chromatographia, 1973, 6, 7, 320-324, https://doi.org/10.1007/BF02269334 . [all data]

Schomburg and Dielmann, 1973
Schomburg, G.; Dielmann, G., Identification by means of retention parameters, J. Chromatogr. Sci., 1973, 11, 3, 151-159, https://doi.org/10.1093/chromsci/11.3.151 . [all data]

Schomburg and Dielmann, 1973, 2
Schomburg, G.; Dielmann, G., Use of retention increments for identification and correlation of saturated and unsaturated cyclopropane hydrocarbons by means of Kovats indices, Anal. Chem., 1973, 45, 9, 1647-1658, https://doi.org/10.1021/ac60331a021 . [all data]

Sojak, Hrivnak, et al., 1973
Sojak, L.; Hrivnak, J.; Majer, P.; Janak, J., Capillary Gas Chromatography of Linear Alkenes on Squalane, Anal. Chem., 1973, 45, 2, 293-302, https://doi.org/10.1021/ac60324a039 . [all data]

Eisen, Orav, et al., 1972
Eisen, O.; Orav, A.; Rang, S., Identifizierung von Normal-Alkenen, Cyclopentenen und -Hexenen mittels Kapillar-Gas-Chromatographie. Identification des alcènes, cyclopentènes et -hexènes à l'aide de la chromatogrpahie en phase gazeuse sur colonne capillaire, Chromatographia, 1972, 5, 11, 229-239, https://doi.org/10.1007/BF02270600 . [all data]

Orav and Eisen, 1972
Orav, A.; Eisen, O., The retention indexes for alkenes, alkynes and cyclenes on capillary columns, Izv. Akad. Nauk Est. SSR, Khim. Geol., 1972, 21, 1, 39-47. [all data]

Soják and Bucinská, 1970
Soják, L.; Bucinská, A., Open tubular column gas chromatography of dehydrogenation products of C6-C10 n-alkanes. Separation and identification of mixtures of C6-C10 straight-chain alkanes, alkenes and aromatics, J. Chromatogr., 1970, 51, 75-82, https://doi.org/10.1016/S0021-9673(01)96841-4 . [all data]

Matukuma, 1969
Matukuma, A., Retention indices of alkanes through C10 and alkenes through C8 and relation between boiling points and retention data, Gas Chromatogr., Int. Symp. Anal. Instrum. Div Instrum Soc. Amer., 1969, 7, 55-75. [all data]

Brown, Chapman, et al., 1968
Brown, I.; Chapman, I.L.; Nicholson, G.J., Gas chromatography of polar solutes in electron acceptor stationary phases, Aust. J. Chem., 1968, 21, 5, 1125-1141, https://doi.org/10.1071/CH9681125 . [all data]

Schomburg, 1967
Schomburg, G., Struktur und Retentionsverhalten von Offenkettigen und Cyclischen Kohlenwasserstoffen und Deren Einfacher Substitutionsprodukte, Anal. Chim. Acta., 1967, 38, 45-64, https://doi.org/10.1016/S0003-2670(01)80560-2 . [all data]

Wehrli and Kováts, 1959
Wehrli, A.; Kováts, E., Gas-chromatographische Charakterisierung ogranischer Verbindungen. Teil 3: Berechnung der Retentionsindices aliphatischer, alicyclischer und aromatischer Verbindungen, Helv. Chim. Acta, 1959, 7, 7, 2709-2736, https://doi.org/10.1002/hlca.19590420745 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References