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triethylgallium

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-70.5 ± 4.5kJ/molReviewMartinho Simões 
Deltafgas-54.2 ± 4.5kJ/molReviewMartinho Simões 
Deltafgas-62. ± 10.kJ/molReviewMartinho SimõesSelected data. The enthalpy of formation is the average of the values from Kol'yakova, Rabinovich, et al., 1973and Shaulov, Genchel, et al., 1972.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-109.0 ± 4.5kJ/molReviewMartinho SimõesMS
Deltafliquid-92.7 ± 4.5kJ/molReviewMartinho SimõesMS
Deltafliquid-101. ± 10.kJ/molReviewMartinho SimõesSelected data. The enthalpy of formation is the average of the values from Kol'yakova, Rabinovich, et al., 1973and Shaulov, Genchel, et al., 1972.; MS
Quantity Value Units Method Reference Comment
Deltacliquid-4941.3 ± 4.2kJ/molCC-SBKol'yakova, Rabinovich, et al., 1973Please also see Pedley and Rylance, 1977.; MS
Deltacliquid-4957.6 ± 4.2kJ/molCC-SBShaulov, Genchel, et al., 1972Please also see Pedley and Rylance, 1977.; MS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
278.03298.15Maslova and Faminskaya, 1972T = 60 to 300 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil414.4KN/ADibrivnyi, Dolbneva, et al., 1986Uncertainty assigned by TRC = 1. K; TRC
Quantity Value Units Method Reference Comment
Ttriple193.5KN/AMaslova and Faminskaya, 1972, 2Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap38.5 ± 0.4kJ/molCC-SBShaulov, Genchel, et al., 1972MS

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
43.1 ± 1.6343.Baev, 2001Based on data from 299. - 387. K. See also Baev and Chernyak, 2001.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
11.644193.5Maslova and Faminskaya, 1972DH
11.64193.5Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
60.18193.5Maslova and Faminskaya, 1972DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Kol'yakova, Rabinovich, et al., 1973
Kol'yakova, G.M.; Rabinovich, I.B.; Zorina, E.N., Dokl. Akad. Nauk SSSR, 1973, 209, 616. [all data]

Shaulov, Genchel, et al., 1972
Shaulov, Yu.Kh.; Genchel, V.G.; Aizatullova, R.M.; Pesotskii, G.S., Russ. J. Phys. Chem., 1972, 46, 1358. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Maslova and Faminskaya, 1972
Maslova, V.A.; Faminskaya, L.A., Specific heat phase transitions of triethylarsine and triethylgallium, Tr. Khim. Khim. Tekhnol., 1972, (2), 51-53. [all data]

Dibrivnyi, Dolbneva, et al., 1986
Dibrivnyi, V.N.; Dolbneva, T.N.; Dikii, M.A., Saturated vapor pressure and vaporization enthalpies of aromatic peroxides in Vses. Konf. po Kalorimetrii i Khim. Termodinamike, 11th, Novosibirsk, Nr 2, p 115, 1986. [all data]

Maslova and Faminskaya, 1972, 2
Maslova, V.A.; Faminskaya, L.A., Specific heat and phase changes of triethylarsine and triethylgallium, Tr. Khim. Khim. Tekhnol., 1972, 1972, 51. [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Baev and Chernyak, 2001
Baev, A.K.; Chernyak, I.N., Zh. Neorg. Khim., 2001, 46, 2, 361. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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