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Propyl sulfide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltafgas-125.2kJ/molN/AMcCullough, Finke, et al., 1961Value computed using «DELTA»fHliquid° value of -169.8±0.88 kj/mol from McCullough, Finke, et al., 1961 and «DELTA»vapH° value of 44.6 kj/mol from missing citation.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-169.8 ± 0.88kJ/molCcrMcCullough, Finke, et al., 1961ALS
Quantity Value Units Method Reference Comment
Deltacliquid-4794.28 ± 0.75kJ/molCcrMcCullough, Finke, et al., 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -4793.78 ± 0.75 kJ/mol; ALS
Quantity Value Units Method Reference Comment
liquid338.28J/mol*KN/AMcCullough, Finke, et al., 1961DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
237.90300.Tutubalina, Gabdrakhmanov, et al., 1982T = 273 to 373 K. Cp = 221.21 + 3.060x10-2T + 8.343x10-5T2.; DH
225.48298.15McCullough, Finke, et al., 1961T = 11 to 370 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C6H14S+ + Propyl sulfide = (C6H14S+ bullet Propyl sulfide)

By formula: C6H14S+ + C6H14S = (C6H14S+ bullet C6H14S)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar119.kJ/molDTJames and Illies, 1996gas phase; «DELTA»rH(0K) = 123. kJ/mol
Quantity Value Units Method Reference Comment
Deltar168.J/mol*KDTJames and Illies, 1996gas phase; «DELTA»rH(0K) = 123. kJ/mol

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McCullough, Finke, et al., 1961
McCullough, J.P.; Finke, H.L.; Hubbard, W.N.; Todd, S.S.; Messerly, J.F.; Douslin, D.R.; Waddington, G., Thermodynamic properties of four linear thiaalkanes, J. Phys. Chem., 1961, 65, 784-791. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Tutubalina, Gabdrakhmanov, et al., 1982
Tutubalina, V.P.; Gabdrakhmanov, F.G.; Konyukhova, T.M., Study of the heat capacity of n-sulfides, 1982, Teplo-Massoobmen Khim. [all data]

James and Illies, 1996
James, M.A.; Illies, A.J., Studies of two-center three-electron S...S bonds in [n-Pr2S...Sn-Pr2]+ and [i-Pr2S...Si-Pr2]+: Thermochemistry of adduct formation and MS/MS metastable and collision-induced dissociation spectra of the adducts, J. Phys. Chem., 1996, 100, 39, 15794, https://doi.org/10.1021/jp9612487 . [all data]


Notes

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