Ethanol, 2,2'-oxybis-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil519. ± 3.KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus265.4KN/AAnonymous, 1958Uncertainty assigned by TRC = 0.6 K; TRC
Tfus263.05KN/AGallaugher and Hibbert, 1936Uncertainty assigned by TRC = 0.5 K; TRC
Tfus262.80KN/ARinkenbach, 1927Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Tc753.KN/ANikitin, Pavlov, et al., 1995Uncertainty assigned by TRC = 4. K; TRC
Tc723.5KN/AAnselme and Teja, 1990Uncertainty assigned by TRC = 50. K; Tc > 723.5 K, which was observed with decomposition; TRC
Tc680.KN/AStephens and Tamplin, 1979Uncertainty assigned by TRC = 20. K; TC data from Union Carbide Corp.; TRC
Quantity Value Units Method Reference Comment
Pc47.08atmN/ANikitin, Pavlov, et al., 1995Uncertainty assigned by TRC = 0.49 atm; TRC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
406.20.018Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
15.9413.TGAAl-Najjar and Al-Sammerrai, 2007Based on data from 373. to 453. K.; AC
16.0 ± 0.07420.EBSteele, Chirico, et al., 2002Based on data from 410. to 539. K.; AC
15.1 ± 0.07460.EBSteele, Chirico, et al., 2002Based on data from 410. to 539. K.; AC
14.1 ± 0.07500.EBSteele, Chirico, et al., 2002Based on data from 410. to 539. K.; AC
13.2 ± 0.1540.EBSteele, Chirico, et al., 2002Based on data from 410. to 539. K.; AC
14.3379.AStephenson and Malanowski, 1987Based on data from 364. to 518. K.; AC
16.0427.N/AAmbrose and Hall, 1981Based on data from 412. to 513. K. See also Boublik, Fried, et al., 1984.; AC
13.7 ± 1.4273.VGallaugher and Hibbert, 1937Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 12.50 kcal/mol; ALS
15.91523.VRinkenbach, 1927, 2ALS
16.5418.N/ARinkenbach, 1927, 3Based on data from 403. to 513. K. See also Boublik, Fried, et al., 1984.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApiezon L160.927.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedApiezon L170.925.Singliar and Dykyj, 1969 

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedPEG-2000200.1989.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryUltra-2967.Poskrobko, Linkiewicz, et al., 199425. m/0.32 mm/0.52 μm, H2, 8. K/min; Tstart: 50. C; Tend: 310. C

Van Den Dool and Kratz RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillarySupelcowax-101975.Moreira, Trugo, et al., 200230. m/0.25 mm/0.25 μm, He, 3. K/min, 230. C @ 30. min; Tstart: 50. C
CapillaryCarbowax 20M1968.Chen, Kuo, et al., 1986He, 50. C @ 5. min, 2. K/min, 200. C @ 40. min; Column length: 50. m; Column diameter: 0.32 mm

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-101941.Zenkevich, 200525. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C

Normal alkane RI, polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-Wax1953.Peng, Yang, et al., 1991Program: not specified

References

Go To: Top, Phase change data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Anonymous, 1958
Anonymous, R., , Am. Pet. Inst. Res. Proj. 45, Ohio State Univ., 1958. [all data]

Gallaugher and Hibbert, 1936
Gallaugher, A.F.; Hibbert, H., Studies on reactions relating to carbohydrates and polysaccharides: xlix molecular weight, molar refraction, freezing point and other properties of the polyethylene glycols and their derivatives, J. Am. Chem. Soc., 1936, 58, 813. [all data]

Rinkenbach, 1927
Rinkenbach, W.H., Properties of Diethylene Glycol, Ind. Eng. Chem., 1927, 19, 475-6. [all data]

Nikitin, Pavlov, et al., 1995
Nikitin, E.D.; Pavlov, P.A.; Popov, A.P., (Gas + liquid) critical temperatures and pressures of polyethene glycols for HOCH2CH2OH to H(OCH2CH2)v.apprxeq.13.2OH, J. Chem. Thermodyn., 1995, 27, 43-51. [all data]

Anselme and Teja, 1990
Anselme, M.J.; Teja, A.S., The critical properties of rapidly reacting substances, AIChE Symp. Ser., 1990, 86, 279, 128-32. [all data]

Stephens and Tamplin, 1979
Stephens, M.A.; Tamplin, W.S., Saturated Liquid SPecific Heats of Ethylene GLycol Homologues, J. Chem. Eng. Data, 1979, 24, 81-2. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Al-Najjar and Al-Sammerrai, 2007
Al-Najjar, Hazim; Al-Sammerrai, Dhoaib, Thermogravimetric determination of the heat of vaporization of some highly polar solvents, J. Chem. Technol. Biotechnol., 2007, 37, 3, 145-152, https://doi.org/10.1002/jctb.280370302 . [all data]

Steele, Chirico, et al., 2002
Steele, W.V.; Chirico, R.D.; Cowell, A.B.; Knipmeyer, S.E.; Nguyen, A., Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for Methyl Benzoate, Ethyl Benzoate, ( R )-(+)-Limonene, tert -Amyl Methyl Ether, trans -Crotonaldehyde, and Diethylene Glycol, J. Chem. Eng. Data, 2002, 47, 4, 667-688, https://doi.org/10.1021/je0100847 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Ambrose and Hall, 1981
Ambrose, D.; Hall, D.J., Thermodynamic properties of organic oxygen compounds L. The vapour pressures of 1,2-ethanediol (ethylene glycol) and bis(2-hydroxyethyl) ether (diethylene glycol), The Journal of Chemical Thermodynamics, 1981, 13, 1, 61-66, https://doi.org/10.1016/S0021-9614(81)80009-2 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Gallaugher and Hibbert, 1937
Gallaugher, A.F.; Hibbert, H., Studies on reactions relating to carbohydrates and polysaccharides. LV. Vapor pressures of the polyethylene glycols and their derivatives, J. Am. Chem. Soc., 1937, 59, 2521-2525. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Rinkenbach, 1927, 2
Rinkenbach, Wm.H., Properties of Diethylene Glycol, Ind. Eng. Chem., 1927, 19, 474-475. [all data]

Rinkenbach, 1927, 3
Rinkenbach, Wm.H., Properties of Diethylene Glycol 1, Ind. Eng. Chem., 1927, 19, 4, 474-476, https://doi.org/10.1021/ie50208a017 . [all data]

Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]

Singliar and Dykyj, 1969
Singliar, M.; Dykyj, J., Gas chromatography of glycol ethers, Collect. Czech. Chem. Commun., 1969, 34, 3, 767-775, https://doi.org/10.1135/cccc19690767 . [all data]

Anderson, Jurel, et al., 1973
Anderson, A.; Jurel, S.; Shymanska, M.; Golender, L., Gas-liquid chromatography of some aliphatic and heterocyclic mono- and pollyfunctional amines. VII. Retention indices of amines in some polar and unpolar stationary phases, Latv. PSR Zinat. Akad. Vestis Kim. Ser., 1973, 1, 51-63. [all data]

Poskrobko, Linkiewicz, et al., 1994
Poskrobko, J.; Linkiewicz, M.; Jaworski, M., Analysis of high-boiling ethoxylates of methyl, ethyl and butyl alcohols, with the use of gas chromatography, Chem. Anal. (Warsaw), 1994, 39, 2, 153-159. [all data]

Moreira, Trugo, et al., 2002
Moreira, R.F.A.; Trugo, L.C.; Pietroluongo, M.; de Maria, C.A.B., Flavor composition of cashew (Anacardium occidentale) and marmeleiro (Croton species) honeys, J. Agric. Food Chem., 2002, 50, 26, 7616-7621, https://doi.org/10.1021/jf020464b . [all data]

Chen, Kuo, et al., 1986
Chen, C.-C.; Kuo, M.-C.; Liu, S.-E.; Wu, C.-M., Volatile components of salted and pickled prunes (Prunus mume Sieb. et Zucc.), J. Agric. Food Chem., 1986, 34, 1, 140-144, https://doi.org/10.1021/jf00067a038 . [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]

Peng, Yang, et al., 1991
Peng, C.T.; Yang, Z.C.; Ding, S.F., Prediction of rentention idexes. II. Structure-retention index relationship on polar columns, J. Chromatogr., 1991, 586, 1, 85-112, https://doi.org/10.1016/0021-9673(91)80028-F . [all data]


Notes

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