Di-n-propyl ether

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-78.59 ± 0.21kcal/molCcbColomina, Pell, et al., 1965ALS
Δfliquid-79.61 ± 0.49kcal/molCcbMurrin and Goldhagen, 1957ALS
Quantity Value Units Method Reference Comment
Δcliquid-963.93 ± 0.19kcal/molCcbColomina, Pell, et al., 1965Corresponding Δfliquid = -78.58 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-962.92 ± 0.49kcal/molCcbMurrin and Goldhagen, 1957Corresponding Δfliquid = -79.59 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid77.41cal/mol*KN/AAndon, Counsell, et al., 1975DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
52.928298.15Kimura, Treszczanowicz, et al., 1983DH
52.96298.15Andon, Counsell, et al., 1975T = 10 to 330 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Colomina, Pell, et al., 1965
Colomina, M.; Pell, A.S.; Skinner, H.A.; Coleman, D.J., Heats of combustion of four dialkylethers, Trans. Faraday Soc., 1965, 61, 2641. [all data]

Murrin and Goldhagen, 1957
Murrin, J.W.; Goldhagen, S., Determination of the C-O bond energy from the heats of combustion of four aliphatic ethers, NAVORD Report No. 5491, U.S. Naval Powder Factory Res. & Dev. Dept., 1957, 1-14. [all data]

Andon, Counsell, et al., 1975
Andon, R.J.L.; Counsell, J.F.; Lee, D.A.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. 39. Heat capacity of n-propyl ether, J. Chem. Thermodynam., 1975, 7, 587-592. [all data]

Kimura, Treszczanowicz, et al., 1983
Kimura, F.; Treszczanowicz, A.J.; Halpin, C.J.; Benson, G.C., Excess volumes and ultrasonic speeds for (di-n-propylether + n-heptane), J. Chem. Thermodynam., 1983, 15, 503-510. [all data]


Notes

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