1-Hexanol

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Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Δfgas (kcal/mol) Method Reference Comment
-73.69N/AMosselman and Dekker, 1975Value computed using ΔfHliquid° value of -377.5±0.4 kj/mol from Mosselman and Dekker, 1975 and ΔvapH° value of 69.2 kj/mol from Green, 1960.; DRB
-75.4 ± 0.1CcbMosselman and Dekker, 1975Value computed using ΔfHliquid° from Mosselman and Dekker, 1975 and ΔvapH° value of 14.8 kcal/mol from Mansson, Sellers, et al., 1977.; DRB
-74.14N/AChao and Rossini, 1965Value computed using ΔfHliquid° value of -379.4±1.0 kj/mol from Chao and Rossini, 1965 and ΔvapH° value of 69.2 kj/mol from Green, 1960.; DRB
-75.88 ± 0.24CcbChao and Rossini, 1965Value computed using ΔfHliquid° from Chao and Rossini, 1965 and ΔvapH° value of 14.8 kcal/mol from Mansson, Sellers, et al., 1977.; DRB
-75.22 ± 0.33CcbGreen, 1960Reanalyzed by Cox and Pilcher, 1970, Original value = -76.75 ± 0.56 kcal/mol; ALS
-76.12N/AKelley, 1929Value computed using ΔfHliquid° value of -387.7 kj/mol from Kelley, 1929 and ΔvapH° value of 69.2 kj/mol from Green, 1960.; DRB
-77.87 ± 0.96CmKelley, 1929Value computed using ΔfHliquid° from Kelley, 1929 and ΔvapH° value of 14.8 kcal/mol from Mansson, Sellers, et al., 1977. estimated uncertainty; DRB

References

Go To: Top, Enthalpy of formation of gas at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H., Enthalpies of formation of n-alkan-1-ols, J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]

Green, 1960
Green, J.H.S., Revision of the values of the heats of formation of normal alcohols, Chem. Ind. (London), 1960, 1215-1216. [all data]

Mansson, Sellers, et al., 1977
Mansson, M.; Sellers, P.; Stridh, G.; Sunner, S., Enthalpies of vaporization of some 1-substituted n-alkanes, J. Chem. Thermodyn., 1977, 9, 91. [all data]

Chao and Rossini, 1965
Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Kelley, 1929
Kelley, K.K., The heat capacities of ethyl and hexyl alcohols from 16°K. to 298°K. and the corresponding entropies and free energies and free energies, J. Am. Chem. Soc., 1929, 51, 779-781. [all data]


Notes

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