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Silane, dimethyl-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H7Si- + Hydrogen cation = Silane, dimethyl-

By formula: C2H7Si- + H+ = C2H8Si

Quantity Value Units Method Reference Comment
Deltar380.9 ± 2.1kcal/molD-EABrinkman, Berger, et al., 1994gas phase
Deltar384.7 ± 4.1kcal/molG+TSDamrauer, Kass, et al., 1988gas phase; Between furan and methanol.
Quantity Value Units Method Reference Comment
Deltar373.1 ± 2.2kcal/molH-TSBrinkman, Berger, et al., 1994gas phase
Deltar377.0 ± 4.0kcal/molIMRBDamrauer, Kass, et al., 1988gas phase; Between furan and methanol.

C2H7Si- + Hydrogen cation = Silane, dimethyl-

By formula: C2H7Si- + H+ = C2H8Si

Quantity Value Units Method Reference Comment
Deltar392.8 ± 6.1kcal/molG+TSDamrauer, Kass, et al., 1988gas phase; Between Me2NH and fluorobenzene
Quantity Value Units Method Reference Comment
Deltar384.0 ± 6.0kcal/molIMRBDamrauer, Kass, et al., 1988gas phase; Between Me2NH and fluorobenzene

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brinkman, Berger, et al., 1994
Brinkman, E.A.; Berger, S.; Brauman, J.I., alpha-Silyl-substituent stabilization of carbanions and silyl anions, J. Am. Chem. Soc., 1994, 116, 18, 8304, https://doi.org/10.1021/ja00097a042 . [all data]

Damrauer, Kass, et al., 1988
Damrauer, R.; Kass, S.R.; DePuy, C.H., Gas-Phase Acidities of Methylsilanes: C-H versus Si-H, Organomet., 1988, 7, 3, 637, https://doi.org/10.1021/om00093a011 . [all data]


Notes

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