2-Octanone

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-1OV-101OV-101SE-54SE-54
Column length (m)  20.20.15.15.
Carrier gas    ArAr
Substrate      
Column diameter (mm)  0.50.50.280.28
Phase thickness (μm)    2.52.5
Temperature (C) 333.150.180.110.130.
I 968.8971.0974.2993.4994.1
ReferenceHu, Lu, et al., 2006Cha and Lee, 1994Cha and Lee, 1994Grigor'eva, Vasil'ev, et al., 1989Grigor'eva, Vasil'ev, et al., 1989
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SE-54Apiezon LH + KFApiezon LH + KFApiezon LH + KFApiezon LH + KF
Column length (m) 15.30.30.30.30.
Carrier gas ArHeHeHeHe
Substrate      
Column diameter (mm) 0.280.250.250.250.25
Phase thickness (μm) 2.50.0630.0630.0630.063
Temperature (C) 150.100.100.100.100.
I 995.6952.953.953.954.
ReferenceGrigor'eva, Vasil'ev, et al., 1989Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Apiezon LH + KFApiezon LH + KFApiezon LH + KFApiezon L + KFApiezon L + KF
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.0630.0630.0630.0630.063
Temperature (C) 100.100.100.100.100.
I 954.955.955.953.953.
ReferenceSamusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Apiezon L + KFApiezon L + KFApiezon L + KFApiezon L + KFApiezon L + KF
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.0630.0630.0630.0630.063
Temperature (C) 100.100.100.100.100.
I 953.953.953.955.955.
ReferenceSamusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Apiezon L + KFApiezon L + KFApiezon L + KFApiezon L + KFApiezon L + KF
Column length (m) 30.30.30.30.30.
Carrier gas      
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.060.060.060.060.06
Temperature (C) 60.100.100.100.100.
I 968.953.953.953.954.
ReferenceSvetlova, Samusenko, et al., 1986Svetlova, Samusenko, et al., 1986Svetlova, Samusenko, et al., 1986Svetlova, Samusenko, et al., 1986Svetlova, Samusenko, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryPackedPackedPacked
Active phase Apiezon L + KFApiezon L + KFSE-30Apiezon LApiezon L
Column length (m) 30.30.3.7  
Carrier gas      
Substrate   Celatom AW silanizedCelite 545Celite 545
Column diameter (mm) 0.250.25   
Phase thickness (μm) 0.060.06   
Temperature (C) 100.100.150.120.160.
I 955.955.978.950.965.
ReferenceSvetlova, Samusenko, et al., 1986Svetlova, Samusenko, et al., 1986Haken, Nguyen, et al., 1979Bogoslovsky, Anvaer, et al., 1978Bogoslovsky, Anvaer, et al., 1978
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase ApolaneSE-30Apiezon LApiezon LApiezon L
Column length (m) 2.43.72.32.32.25
Carrier gas He N2N2 
Substrate Chromosorb DCMS-treated Chromosorb WDCMS-treated Chromosorb WCelite
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 190.150.100.150.130.
I 938.5977.946.957.947.
ReferenceRiedo, Fritz, et al., 1976Haken, Ho, et al., 1975Brown, Chapman, et al., 1968Brown, Chapman, et al., 1968Wehrli and Kováts, 1959
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Packed
Active phase Apiezon L
Column length (m) 2.25
Carrier gas  
Substrate Celite
Column diameter (mm)  
Phase thickness (μm)  
Temperature (C) 190.
I 953.
ReferenceWehrli and Kováts, 1959
Comment MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hu, Lu, et al., 2006
Hu, X.-F.; Lu, C.-H.; Yin, C.-S., Modeling Gas Chromatographic Retention Indices of Oxygen-containing Compounds by Novel Atom-type Topological Indices, Chinese Journal of Chemical Physics, 2006, 19, 3, 243-247, https://doi.org/10.1360/cjcp2006.19(3).243.5 . [all data]

Cha and Lee, 1994
Cha, K.-W.; Lee, D.-J., Prediction of retention indices of various compounds in gas-liquid chromatography, J. Korean Chem. Soc., 1994, 38, 2, 108-120, retrieved from http://journal.kcsnet.or.kr/publi/dh/dh94n2/108.pdf. [all data]

Grigor'eva, Vasil'ev, et al., 1989
Grigor'eva, D.N.; Vasil'ev, A.V.; Golovnya, R.V., Variation in retention indices and equivalent chain lengths of homologous series of n-alkyl acetates, n-alkyl methyl ketones, and methyl esters of aliphatic carboxylic acids as a function of homolog number and analysis temperature, Zh. Anal. Khim., 1989, 44, 1, 68-73. [all data]

Samusenko, Svetlova, et al., 1986
Samusenko, A.L.; Svetlova, N.I.; Golovnya, R.V., Reproducible and durable glass capillary columns with hydrogenated apiezon-l and OV-101 for the analysis of polar substances, Zh. Anal. Khim., 1986, 61, 1, 127-133. [all data]

Svetlova, Samusenko, et al., 1986
Svetlova, N.I.; Samusenko, A.L.; Golovnya, R.V., Advantage of the universal equation over the linear equation for the calculation of retention parameters of homologous series in capillary chromatography, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 12, 737-740, https://doi.org/10.1002/jhrc.1240091205 . [all data]

Haken, Nguyen, et al., 1979
Haken, J.K.; Nguyen, A.; Wainwright, M.S., Application of linear extrathermodynamic relationships to alcohols, aldehydes, ketones, amd ethoxy alcohols, J. Chromatogr., 1979, 179, 1, 75-85, https://doi.org/10.1016/S0021-9673(00)80658-5 . [all data]

Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]

Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Chromatogr., 1976, 126, 63-83, https://doi.org/10.1016/S0021-9673(01)84063-2 . [all data]

Haken, Ho, et al., 1975
Haken, J.K.; Ho, D.K.M.; Vaughan, C.E., Gas chromatography of homologous esters. VII. The retention behaviour of pyruvate esters and related carbonyl and carboxyl compounds, J. Chromatogr., 1975, 106, 2, 317-325, https://doi.org/10.1016/S0021-9673(00)93839-1 . [all data]

Brown, Chapman, et al., 1968
Brown, I.; Chapman, I.L.; Nicholson, G.J., Gas chromatography of polar solutes in electron acceptor stationary phases, Aust. J. Chem., 1968, 21, 5, 1125-1141, https://doi.org/10.1071/CH9681125 . [all data]

Wehrli and Kováts, 1959
Wehrli, A.; Kováts, E., Gas-chromatographische Charakterisierung ogranischer Verbindungen. Teil 3: Berechnung der Retentionsindices aliphatischer, alicyclischer und aromatischer Verbindungen, Helv. Chim. Acta, 1959, 7, 7, 2709-2736, https://doi.org/10.1002/hlca.19590420745 . [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References