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Tricopper trichloride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to Cl3Cu3+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.5EIWilliams, 1982LBLHLM
9.6EIBloom and Williams, 1981LLK
10.0 ± 0.3EIBernauer, Busse, et al., 1979LLK
9.6 ± 0.5EIWagner, Robert, et al., 1974LLK
9.9 ± 0.5EIGuido, Balducci, et al., 1971LLK
10.0PEMacNaughton, Bloor, et al., 1981Vertical value; LLK
9.52PEBerkowitz, Batson, et al., 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ClCu+20.0 ± 0.5CuCl+Cu+ClEIWagner, Robert, et al., 1974LLK
ClCu+23.3 ± 0.52Cu+2ClEIWagner, Robert, et al., 1974LLK
ClCu+16.0 ± 0.052CuClEIWagner, Robert, et al., 1974LLK
ClCu2+12.0 ± 0.5CuCl2EIGuido, Balducci, et al., 1971LLK
Cl2Cu2+16.7 ± 0.5Cu+ClEIWagner, Robert, et al., 1974LLK
Cl2Cu2+13.5 ± 0.5CuClEIWagner, Robert, et al., 1974LLK
Cl2Cu3+12.6ClEIBloom and Williams, 1981LLK
Cl2Cu3+12.8 ± 0.3ClEIBernauer, Busse, et al., 1979LLK
Cu+17.9 ± 0.5?EIWagner, Robert, et al., 1974LLK
Cu2+18.1 ± 0.5?EIWagner, Robert, et al., 1974LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Williams, 1982
Williams, D.J., Mass spectrometric study of the vaporization of the alkali chloride-cuprous chloride systems, Aust. J. Chem., 1982, 35, 1531. [all data]

Bloom and Williams, 1981
Bloom, H.; Williams, D.J., A mass spectrometric study of the vapors above the molten salt systems LiCl-CuCl, LiBr-CuBr, and NaI-CuI, J. Chem. Phys., 1981, 75, 4636. [all data]

Bernauer, Busse, et al., 1979
Bernauer, O.; Busse, B.; Weil, K.G., Massenspektrometrische Untersuchungen an Kupfer- und Silber- Halogeniden IV: Die Systeme AgxCu(1-x) (0=<X=<1) und AgClxBr(1-x) (0=<X=<1), Ber. Bunsen-Ges. Phys. Chem., 1979, 83, 603. [all data]

Wagner, Robert, et al., 1974
Wagner, L.C.; Robert, P.; Grindstaff, Q.; Grimley, R.T., A mass spectrometric study of the fragmentation of the cuprous chloride vapor system, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 255. [all data]

Guido, Balducci, et al., 1971
Guido, M.; Balducci, G.; Gigli, G.; Spoliti, M., Mass spectrometric study of the vaporization of cuprous chloride and the dissociation energy of Cu3Cl3, Cu4Cl4, and Cu5Cl5, J. Chem. Phys., 1971, 55, 4566. [all data]

MacNaughton, Bloor, et al., 1981
MacNaughton, R.M.; Bloor, J.E.; Sherrod, R.E.; Schweitzer, G.K., The He(I) photoelectron psectra of some gaseous 3d-transition metal dihalides, J. Electron Spectrosc. Relat. Phenom., 1981, 22, 1. [all data]

Berkowitz, Batson, et al., 1980
Berkowitz, J.; Batson, C.H.; Goodman, G.L., Photoelectron spectroscopy of AgCl, AgBr, and AgI vapors, J. Chem. Phys., 1980, 72, 5829. [all data]


Notes

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