Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Cyclohexane

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Normal melting point

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director

Tfus (K) Reference Comment
280.15Anonymous, 1988Uncertainty assigned by TRC = 1. K; nominal value, from the catalog; TRC; Data excluded from overall average
279.74Snow, Ott, et al., 1986Uncertainty assigned by TRC = 0.02 K; TRC
279.66Guieu, Carbonnel, et al., 1985Crystal phase 1 phase; Uncertainty assigned by TRC = 0.1 K; TRC
279.74Ott and Goates, 1983Uncertainty assigned by TRC = 0.08 K; TRC
279.730Stokes and Tomlins, 1974Uncertainty assigned by TRC = 0.01 K; in equilibrium with air; TRC
279.870Stokes and Tomlins, 1974Uncertainty assigned by TRC = 0.01 K; air-free at 1 atm pressure; TRC
279.70Findenegg, 1970Uncertainty assigned by TRC = 0.05 K; TRC
280.69Stokes, Levien, et al., 1970Uncertainty assigned by TRC = 0.05 K; TRC; Data excluded from overall average
279.73Brunet and Gubbins, 1969Uncertainty assigned by TRC = 0.15 K; TRC
279.72Stokes, Marsh, et al., 1969Uncertainty assigned by TRC = 0.04 K; TRC
279.7Cruickshank and Cutler, 1967Uncertainty assigned by TRC = 0.03 K; TRC
279.58Battino and Allison, 1966Uncertainty assigned by TRC = 0.1 K; TRC
279.75Sabinin, Belousov, et al., 1966Uncertainty assigned by TRC = 0.3 K; TRC
279.69Rastogi and Nigam, 1959Uncertainty assigned by TRC = 0.1 K; TRC
279.22Staveley and Taylor, 1956Uncertainty assigned by TRC = 0.1 K; TRC
279.70Rock and Sieg, 1955Uncertainty assigned by TRC = 0.2 K; TRC
279.7Roeck and Sieg, 1955Uncertainty assigned by TRC = 0.3 K; TRC
279.65Russell and Brown, 1955Uncertainty assigned by TRC = 0.1 K; TRC
279.65Crowe and Smyth, 1951Crystal phase 1 phase; Uncertainty assigned by TRC = 0.3 K; TRC
279.62Denyer, Fidler, et al., 1949Uncertainty assigned by TRC = 0.2 K; TRC
279.55Kennard and McCusker, 1948Uncertainty assigned by TRC = 0.2 K; TRC
279.57Spitzer and Huffman, 1947Uncertainty assigned by TRC = 0.06 K; measured by Kistiakowsky; TRC
279.5Spitzer and Huffman, 1947Uncertainty assigned by TRC = 0.07 K; measured by G. S. Parks; TRC
279.69Forziati, Glasgow, et al., 1946Uncertainty assigned by TRC = 0.01 K; TRC
279.3Greensfelder and Voge, 1945Uncertainty assigned by TRC = 0.8 K; TRC
279.51Tooke and Aston, 1945Uncertainty assigned by TRC = 0.06 K; TRC
279.65Anonymous, 1940Uncertainty assigned by TRC = 0.1 K; TRC
279.55Wibaut, Hoog, et al., 1939Uncertainty assigned by TRC = 0.2 K; TRC
279.55Seyer, 1938Uncertainty assigned by TRC = 0.5 K; TRC
279.55Smittenberg, Hoog, et al., 1938Uncertainty assigned by TRC = 0.2 K; TRC
266.75Leslie and Heuer, 1937Uncertainty assigned by TRC = 1.5 K; TRC; Data excluded from overall average
277.15Ipatieff and Komarewsky, 1936Uncertainty assigned by TRC = 1. K; TRC; Data excluded from overall average
279.550Kistiakowsky, Ruhoff, et al., 1936Uncertainty assigned by TRC = 0.1 K; TRC
279.Timmermans, 1935Uncertainty assigned by TRC = 1.5 K; TRC; Data excluded from overall average
279.4Parks and Huffman, 1931Crystal phase 1 phase; Uncertainty assigned by TRC = 1. K; TRC
279.15Smyth and Stoops, 1929Uncertainty assigned by TRC = 0.5 K; TRC
279.35Smyth and Stoops, 1929Uncertainty assigned by TRC = 0.5 K; TRC
279.4Dessart, 1926Uncertainty assigned by TRC = 0.6 K; TRC
279.55Timmermans and Martin, 1926Uncertainty assigned by TRC = 0.2 K; TRC
277.7Faragher and Garner, 1921Uncertainty assigned by TRC = 1. K; TRC; Data excluded from overall average
279.55Richards and Shipley, 1919Uncertainty assigned by TRC = 0.4 K; TRC
279.55Richards and Shipley, 1916Uncertainty assigned by TRC = 0.2 K; TRC
278.65Drapier, 1911Uncertainty assigned by TRC = 0.2 K; TRC; Data excluded from overall average
279.65Chavanne and Van Roelen, 1908Uncertainty assigned by TRC = 0.5 K; may not have been measured by author; TRC
279.6Zelinskii, 1901Uncertainty assigned by TRC = 2. K; TRC
277.9Young and Fortey, 1900Uncertainty assigned by TRC = 0.6 K; TRC; Data excluded from overall average
278.7Faraday, 1825Uncertainty assigned by TRC = 2.77 K; called "bicarburet of hydrogen", probably cyclohexane; TRC; Data excluded from overall average

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Normal melting point, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Anonymous, 1988
Anonymous, X., , NBS Spec. Publ. (U. S.) 260, 1988. [all data]

Snow, Ott, et al., 1986
Snow, R.L.; Ott, J.B.; Goates, J.R.; Marsh, K.N.; O'Shea, S.; Stokes, R.H., (Solid + liquid) and (vapor + liquid) phase equilibria and excess enthalpies for (benzene + n-tetradecane), (benzene + n-hexadecane), (cyclohexane + n-tetradecane), and (cyclohexane + n-hexadecane), J. Chem. Thermodyn., 1986, 18, 107. [all data]

Guieu, Carbonnel, et al., 1985
Guieu, R.; Carbonnel, L.; Kehiaian, H.V., Solutions solides organiques I. Etude des diagrammes de phases des systemes oxanne ou 1,4-dioxanne + cyclohexane, Bull. Soc. Chim. Fr., 1985, 1985, 709. [all data]

Ott and Goates, 1983
Ott, J.B.; Goates, J.R., (Solid + liquid) Phase Equilibria in Binary Mixtures Containing Benzene, a Cycloalkane, an n-Alkane, or Tetrachloromethane. An Equation for Representing (Solid + liquid) Phase Equilibria, J. Chem. Thermodyn., 1983, 15, 267-78. [all data]

Stokes and Tomlins, 1974
Stokes, R.H.; Tomlins, R.P., Thermodynamic functions of melting for cyclohexane, J. Chem. Thermodyn., 1974, 6, 379-86. [all data]

Findenegg, 1970
Findenegg, G.H., Density and expansion coefficient of some liquid alkanes, Monatsh. Chem., 1970, 101, 1081. [all data]

Stokes, Levien, et al., 1970
Stokes, R.H.; Levien, B.J.; Marsh, K.N., A contunuous dilution dilatometer. The excess volume for the system cyclohexane + benzene, J. Chem. Thermodyn., 1970, 2, 43-52. [all data]

Brunet and Gubbins, 1969
Brunet, J.; Gubbins, K.E., Viscosity of Binary Liquid Mixtures near the Critical Mixing Point., Trans. Faraday Soc., 1969, 65, 1255. [all data]

Stokes, Marsh, et al., 1969
Stokes, R.H.; Marsh, K.N.; Tomlins, R.P., An isothermal displacement calorimeter for endothermic enthalpies of mixing, J. Chem. Thermodyn., 1969, 1, 211-21. [all data]

Cruickshank and Cutler, 1967
Cruickshank, A.J.B.; Cutler, A.J.B., Vapor Pressure of Cyclohexane, 25 to 75 deg C, J. Chem. Eng. Data, 1967, 12, 326. [all data]

Battino and Allison, 1966
Battino, R.; Allison, G.W., Thermodynamics of Binary Solutions of Nonelectrolytes with 2,2,4-Trimethyl- pentane II. Phase Equilibrium Study with Cyclohexane and a New Cooling Curve Apparatus, J. Phys. Chem., 1966, 70, 3417. [all data]

Sabinin, Belousov, et al., 1966
Sabinin, V.E.; Belousov, V.P.; Morachevskii, A.G., Heat of Mixing and Heat of Vaporization in the Benzene-Cyclohexane System, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1966, 9, 382. [all data]

Rastogi and Nigam, 1959
Rastogi, R.P.; Nigam, R.K., Thermodynamic Properties of Binary Mixtures of Benzene, Cyclohexane and Carbon Tetrachloride, Trans. Faraday Soc., 1959, 55, 2005. [all data]

Staveley and Taylor, 1956
Staveley, L.A.K.; Taylor, P.F., Solutions of Alcohols in Nonpolar Solvents III. The Viscosities of Dilute Solutions of Primary Alcohols in Benzene, J. Chem. Soc., 1956, 1956, 200. [all data]

Rock and Sieg, 1955
Rock, H. (see roeck h); Sieg, L., Measurement of Evaporation Equilibrium with A Modern Circulation Apparatus, Z. Phys. Chem. (Munich), 1955, 3, 355. [all data]

Roeck and Sieg, 1955
Roeck, H.; Sieg, L., Meassurement of Vaporization Equilibria witn a Modernized Circulation Apparatus, Z. Phys. Chem. (Munich), 1955, 3, 355. [all data]

Russell and Brown, 1955
Russell, G.A.; Brown, H.C., The Competitive Halogenation of Cyclohexane and Aralkyl Hydrocarbons Evidence as to the Nature of the Transition States in Halogenation React., J. Am. Chem. Soc., 1955, 77, 4578. [all data]

Crowe and Smyth, 1951
Crowe, R.W.; Smyth, C.P., J. Am. Chem. Soc., 1951, 73, 5406. [all data]

Denyer, Fidler, et al., 1949
Denyer, R.L.; Fidler, F.A.; Lowry, R.A., Azeotrope Formation Between Thiols and Hydrocarbons, Ind. Eng. Chem., 1949, 41, 2727-37. [all data]

Kennard and McCusker, 1948
Kennard, S.M.S.; McCusker, P.A., Some systems of carbon halides with dixane, pyridine and cyclohexane, J. Am. Chem. Soc., 1948, 70, 3375. [all data]

Spitzer and Huffman, 1947
Spitzer, R.; Huffman, H.M., The Heat of Combustion of Cyclopentane, Cyclohexane, Cycloheptane, and Cyclooctane, J. Am. Chem. Soc., 1947, 69, 211. [all data]

Forziati, Glasgow, et al., 1946
Forziati, A.F.; Glasgow, A.R.; Willingham, C.B.; Rossini, F.D., Specification adn Properties of 29 Paraffin, 4 Alkylcyclopentanes, 10 Alkylcyclohexanes and 8 Alkylbenzene Hydrocarbons, J. Res. Natl. Bur. Stand. (U. S.), 1946, 36, 129. [all data]

Greensfelder and Voge, 1945
Greensfelder, B.S.; Voge, H.H., Catalytic Cracking of Pure Hydrodarbons. Cracking of Naphthenes, Ind. Eng. Chem., 1945, 37, 1038-43. [all data]

Tooke and Aston, 1945
Tooke, J.W.; Aston, J.G., Solid Solutions in Hydrocarbon Systems, J. Am. Chem. Soc., 1945, 67, 2275. [all data]

Anonymous, 1940
Anonymous, R., , Am. Pet. Inst. Hydrocarbon Res. Proj., Second Annu. Rep., Ohio State Univ., Aug. 31, 1940. [all data]

Wibaut, Hoog, et al., 1939
Wibaut, J.P.; Hoog, H.; Lagedijk, S.L.; Overhoff, J.; Smittenberg, J.; Benninga, N.; Bouman, G.P.; van Dijk, H.; Gaade, W.; Geldof, H.; Hackmann, J.Th.; Jonker, E.W.; Paap, T.; Zuiderweg, F.J., Study on the preparation and the physical constants of a number of alkanes and cycloalkanes, Recl. Trav. Chim. Pays-Bas, 1939, 58, 329. [all data]

Seyer, 1938
Seyer, W.F., Mutual Solubilities of Hydrocarbons II. The Freezing Point Curves of Dotricontane (Dicetyl) in Dodecane, Decane, Octane, Hexane, Cyclohexane and Benzene, J. Am. Chem. Soc., 1938, 60, 827-30. [all data]

Smittenberg, Hoog, et al., 1938
Smittenberg, J.; Hoog, H.; Henkes, R.A., Freezing Points of A Number of Pure Hydrocarbons of the Gasoline Boiling Range and of Some of their Binary Mixtures, J. Am. Chem. Soc., 1938, 60, 17. [all data]

Leslie and Heuer, 1937
Leslie, R.T.; Heuer, W.W., Study of the Crystal Behavior of Hydrocarbons, J. Res. Natl. Bur. Stand. (U. S.), 1937, 18, 639. [all data]

Ipatieff and Komarewsky, 1936
Ipatieff, V.N.; Komarewsky, V.I., Desctructive Alkylation with a Hydrogenating Agent, J. Am. Chem. Soc., 1936, 58, 922. [all data]

Kistiakowsky, Ruhoff, et al., 1936
Kistiakowsky, G.B.; Ruhoff, J.R.; Smith, H.A.; Vaughan, W.E., Heats of Organic Reactions III. Hydrogenation of SOme Higher Olefins, J. Am. Chem. Soc., 1936, 58, 137. [all data]

Timmermans, 1935
Timmermans, J., Researches in Stoichiometry. I. The Heat of Fusion of Organic Compounds., Bull. Soc. Chim. Belg., 1935, 44, 17-40. [all data]

Parks and Huffman, 1931
Parks, G.S.; Huffman, H.M., Some fusion and transition data for hydrocarbons, Ind. Eng. Chem., 1931, 23, 1138-9. [all data]

Smyth and Stoops, 1929
Smyth, C.P.; Stoops, W.N., The Dielectric Polarization of Liquids VI. Ethyl Iodide, Ethanol, Normal-Butanol and Normal-Octanol, J. Am. Chem. Soc., 1929, 51, 3312. [all data]

Dessart, 1926
Dessart, A., Theory of Concentrated Solutions: III. Physical Constants of Mixtures of m-Nitrotoluene and m-Toluidine with Some Hydrocarbons, Bull. Soc. Chim. Belg., 1926, 35, 9. [all data]

Timmermans and Martin, 1926
Timmermans, J.; Martin, F., J. Chim. Phys. Phys.-Chim. Biol., 1926, 23, 747. [all data]

Faragher and Garner, 1921
Faragher, W.F.; Garner, F.H., The Elimination of Hydrogen CHloride from Chlorohydrocarbons, J. Am. Chem. Soc., 1921, 43, 1715-24. [all data]

Richards and Shipley, 1919
Richards, T.W.; Shipley, J.W., The Dielectric Constants of Typical Aliphatic and Aromatic Hydrocarbons, Cyclohexane, Cyclohexanone, and Cyclohexanol, J. Am. Chem. Soc., 1919, 41, 2002. [all data]

Richards and Shipley, 1916
Richards, T.W.; Shipley, J.W., The Compressibility of Certain Typical Hydrocarbons, Alcohols and Ketones, J. Am. Chem. Soc., 1916, 38, 989-99. [all data]

Drapier, 1911
Drapier, P., Research on the viscosity of Binary Liquid Mixtures in the vicinity of the critical temperature, Bull. Cl. Sci., Acad. R. Belg., 1911, 1, 621-640. [all data]

Chavanne and Van Roelen, 1908
Chavanne, G.; Van Roelen, B., Cyclohexanol., Bull. Soc. Chim. Belg., 1908, 22, 410. [all data]

Zelinskii, 1901
Zelinskii, N.D., Ber. Dtsch. Chem. Ges., 1901, 34, 1799-2803. [all data]

Young and Fortey, 1900
Young, S.; Fortey, E.C., Note on the Refraction and Magnetic Rotation of Hexamethylene, Chlorohexamethylene, and Dichlorolhexamethylene, J. Chem. Soc., 1900, 77, 372. [all data]

Faraday, 1825
Faraday, M., On New Compounds of Carbon and Hydrogen, and on Certain Other Products Obtained During Decomposition of Oil By Heat, Philos. Trans. R. Soc. London, 1825, 115, 440. [all data]


Notes

Go To: Top, Normal melting point, References