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Ethanol, 2-ethoxy-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
50.148298.15Svoboda, Zabransky, et al., 1991T = 298 to 330 K. Cp(liq) = 84.928 + 0.4189(T/K) J/mol*K. Cp value calculated from equation.
50.31298.15Roux, Perron, et al., 1978T = 283.15, 298.15, 313.15 K. Data at three temperatures.
50.38298.15Kusano, Suurkuusk, et al., 1973 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil408.3 ± 0.5KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Deltavap11.53kcal/molN/AMajer and Svoboda, 1985 
Deltavap11.8kcal/molEBAntosik, Fras, et al., 1999Based on data from 313. - 353. K.; AC
Deltavap12.0kcal/molEBAntosik, Fras, et al., 1999Based on data from 313. - 363. K.; AC
Deltavap11.5 ± 0.02kcal/molCKusano, Wadsö, et al., 1971AC
Deltavap11.8kcal/molISunwoo and Eisen, 1971AC

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
9.374408.1N/AMajer and Svoboda, 1985 
11.0338.TGAAl-Najjar and Al-Sammerrai, 2007Based on data from 323. - 353. K.; AC
11.3325.EBChylinski, Fras, et al., 2001Based on data from 310. - 385. K.; AC
10.7351.AStephenson and Malanowski, 1987Based on data from 336. - 408. K. See also Pick, Fried, et al., 1956.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
336. - 407.4.863061756.857-46.92Pick, Fried, et al., 1956, 2Coefficents calculated by NIST from author's data.

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IR Spectrum

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Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1998.
NIST MS number 290907

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References

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Svoboda, Zabransky, et al., 1991
Svoboda, V.; Zabransky, M.; Barta, M., Molar heat capacities of 2-methoxyethanol, 2-ethoxyethanol, and 2-propoxyethanol in the temperature range from 298K to 330K, J. Chem. Thermodynam., 1991, 23, 711-712. [all data]

Roux, Perron, et al., 1978
Roux, G.; Perron, G.; Desnoyers, J.E., Model systems for hydrophobic interactions: volumes and heat capacities of n-alkoxyethanols in water, J. Solution Chem., 1978, 7, 639-654. [all data]

Kusano, Suurkuusk, et al., 1973
Kusano, K.; Suurkuusk, J.; Wads, I., Thermochemistry of solutions of biochemical model compounds. 2. Alkoxyethanols and 1,2-dialkoxyethanes in water, J. Chem. Thermodynam. 5,757-767 (1973).73LEB/TSV Lebedev, B.V., Tsvetkova, L.Ya., and Rabinovich, I.B., Specific heat and thermodynamic functions of poly(vinyltrimethylsilane), Tr. Khim. Khim. Tekhnol., 1973, (1), 17-18. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Antosik, Fras, et al., 1999
Antosik, Maria; Fras, Zbigniew; Malanowski, Stanislaw K., Vapor-Liquid Equilibrium in 2-Ethoxyethanol + Methanol at 313.15 to 333.15 K, J. Chem. Eng. Data, 1999, 44, 3, 368-372, https://doi.org/10.1021/je9801011 . [all data]

Kusano, Wadsö, et al., 1971
Kusano, Kazuhito; Wadsö, Ingemar; Rømming, Chr.; Lindberg, Alf A.; Lagerlund, Inger; Ehrenberg, L., Enthalpies of Vaporization of Organic Compounds. VIII. Alkoxyethanols., Acta Chem. Scand., 1971, 25, 219-224, https://doi.org/10.3891/acta.chem.scand.25-0219 . [all data]

Sunwoo and Eisen, 1971
Sunwoo, Chimin; Eisen, Henry, Solubility parameter of selected sulfonamides, J. Pharm. Sci., 1971, 60, 2, 238-244, https://doi.org/10.1002/jps.2600600217 . [all data]

Al-Najjar and Al-Sammerrai, 2007
Al-Najjar, Hazim; Al-Sammerrai, Dhoaib, Thermogravimetric determination of the heat of vaporization of some highly polar solvents, J. Chem. Technol. Biotechnol., 2007, 37, 3, 145-152, https://doi.org/10.1002/jctb.280370302 . [all data]

Chylinski, Fras, et al., 2001
Chylinski, K.; Fras, Z.; Malanowski, S.K., Vapor-Liquid Equilibrium in Phenol + 2-Ethoxyethanol at 363.15 to 383.15 K, J. Chem. Eng. Data, 2001, 46, 1, 29-33, https://doi.org/10.1021/je0001072 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Pick, Fried, et al., 1956
Pick, J.; Fried, V.; Hala, E.; Vilim, O., Collect. Czech. Chem. Commun., 1956, 21, 260. [all data]

Pick, Fried, et al., 1956, 2
Pick, J.; Fried, V.; Hala, E.; Vilim, O., Der Dampfdruck des Athylenglykolmonomethylathers und des Athylenglykolmonoathylathers, Collect. Czech. Chem. Commun., 1956, 21, 1, 260-261, https://doi.org/10.1135/cccc19560260 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References