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Ethane, 1,2-dimethoxy-

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-81.9 ± 0.2kcal/molCcrSteele, Chirico, et al., 1996 
Deltafgas-93.1 ± 0.5kcal/molEqkWiberg, Morgan, et al., 1994 
Deltafgas-81.37 ± 0.15kcal/molCcrLoucks and Laidler, 1967 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-90.72 ± 0.15kcal/molCcrSteele, Chirico, et al., 1996ALS
Deltafliquid-100.4 ± 0.4kcal/molEqkWiberg, Morgan, et al., 1994ALS
Deltafliquid-90.02 ± 0.05kcal/molCcrLoucks and Laidler, 1967ALS
Quantity Value Units Method Reference Comment
Deltacliquid-627.06 ± 0.37kcal/molCcrSteele, Chirico, et al., 1996Corresponding «DELTA»fliquid = -90.717 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
45.684298.15Trejo, Costas, et al., 1991DH
46.20298.15Kusano, Suurkuusk, et al., 1973DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil358. ± 1.KAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus203.94KN/AGuanquan, Ott, et al., 1986Uncertainty assigned by TRC = 0.1 K; TRC
Tfus204.15KN/AAnonymous, 1982TRC
Quantity Value Units Method Reference Comment
Tc537.KN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 2. K; TRC
Tc539.2KN/AQuadri and Kudchadker, 1991Uncertainty assigned by TRC = 0.5 K; TRC
Tc536.KN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Pc39.08atmN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 2.47 atm; from extraploation of obs. vapor pressures to Tc; TRC
Pc38.10atmN/AQuadri and Kudchadker, 1991Uncertainty assigned by TRC = 0.20 atm; TRC
Pc38.19atmN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 0.2721 atm; TRC
Quantity Value Units Method Reference Comment
Vc0.271l/molN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 0.005 l/mol; TRC
Quantity Value Units Method Reference Comment
rhoc3.25mol/lN/ASteele, Chirico, et al., 1996Uncertainty assigned by TRC = 0.13 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap9. ± 1.kcal/molAVGN/AAverage of 8 values; Individual data points

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
7.749358.N/AMajer and Svoboda, 1985 
8.25304. - 358.EBLi, Fang, et al., 2009AC
9.42253.AStephenson and Malanowski, 1987Based on data from 238. - 298. K.; AC
9.35253.AStephenson and Malanowski, 1987Based on data from 238. - 363. K.; AC
8.10240.N/AStull, 1947Based on data from 225. - 366. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
225. - 366.3.832041260.52-37.322Stull, 1947Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(C4H11O2+ bullet 2Water bullet 2Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ bullet 3Water bullet 2Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ bullet 2H2O bullet 2C4H10O2) + H2O = (C4H11O2+ bullet 3H2O bullet 2C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.2kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/AMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.5225.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

(C4H11O2+ bullet 3Water bullet Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ bullet 4Water bullet Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ bullet 3H2O bullet C4H10O2) + H2O = (C4H11O2+ bullet 4H2O bullet C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.5kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/AMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
3.9225.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

(C4H11O2+ bullet 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (C4H11O2+ bullet 3Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ bullet 2C4H10O2) + C4H10O2 = (C4H11O2+ bullet 3C4H10O2)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar10.2kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar25.0cal/mol*KN/AMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
5.0208.PHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; Entropy change calculated or estimated; M

Sodium ion (1+) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Na+ + C4H10O2 = (Na+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar37.8 ± 1.0kcal/molCIDTArmentrout and Rodgers, 2000glyme; RCD
Deltar57.6 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar38.5 ± 1.0kcal/molCIDTMore, Ray, et al., 1997RCD
Deltar47.2kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar34.6cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Free energy of reaction

DeltarG° (kcal/mol) T (K) Method Reference Comment
31.8298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD

Potassium ion (1+) + Ethane, 1,2-dimethoxy- = (Potassium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: K+ + C4H10O2 = (K+ bullet C4H10O2)

Bond type: Polydentate bonding in non-hydrogen-bonded positive ions

Quantity Value Units Method Reference Comment
Deltar28.4 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar30.8kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.8cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M

(Sodium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Na+ bullet C4H10O2) + C4H10O2 = (Na+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar27.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD
Deltar27.2 ± 2.0kcal/molCIDTMore, Ray, et al., 1997RCD
Deltar35.1kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar40.5cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

(C4H11O2+ bullet Ethane, 1,2-dimethoxy- bullet 2Water) + Ethane, 1,2-dimethoxy- = (C4H11O2+ bullet 2Ethane, 1,2-dimethoxy- bullet 2Water)

By formula: (C4H11O2+ bullet C4H10O2 bullet 2H2O) + C4H10O2 = (C4H11O2+ bullet 2C4H10O2 bullet 2H2O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar19.8kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.5cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet 2Water bullet Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ bullet 3Water bullet Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ bullet 2H2O bullet C4H10O2) + H2O = (C4H11O2+ bullet 3H2O bullet C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.2kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.8cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet Water bullet 2Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ bullet 2Water bullet 2Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ bullet H2O bullet 2C4H10O2) + H2O = (C4H11O2+ bullet 2H2O bullet 2C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar9.8kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.4cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

(C4H11O2+ bullet Water bullet Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ bullet 2Water bullet Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ bullet H2O bullet C4H10O2) + H2O = (C4H11O2+ bullet 2H2O bullet C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar10.4kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.9cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C5H6N+ + Ethane, 1,2-dimethoxy- = (C5H6N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C5H6N+ + C4H10O2 = (C5H6N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar25.4kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; glyme; M
Quantity Value Units Method Reference Comment
Deltar31.4cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; glyme; M

(NH4+ bullet Ethane, 1,2-dimethoxy-) + Ammonia = (NH4+ bullet Ammonia bullet Ethane, 1,2-dimethoxy-)

By formula: (H4N+ bullet C4H10O2) + H3N = (H4N+ bullet H3N bullet C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar14.0kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar19.4cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M

(C4H11O2+ bullet Ethane, 1,2-dimethoxy-) + Water = (C4H11O2+ bullet Water bullet Ethane, 1,2-dimethoxy-)

By formula: (C4H11O2+ bullet C4H10O2) + H2O = (C4H11O2+ bullet H2O bullet C4H10O2)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar13.7kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.4cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

C4H11O2+ + Ethane, 1,2-dimethoxy- = (C4H11O2+ bullet Ethane, 1,2-dimethoxy-)

By formula: C4H11O2+ + C4H10O2 = (C4H11O2+ bullet C4H10O2)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
Deltar27.4kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.9cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1994gas phase; M

NH4+ + Ethane, 1,2-dimethoxy- = (NH4+ bullet Ethane, 1,2-dimethoxy-)

By formula: H4N+ + C4H10O2 = (H4N+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar38. ± 3.kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; possible ether decomposition; M
Quantity Value Units Method Reference Comment
Deltar36.cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; possible ether decomposition; M

C3H10N+ + Ethane, 1,2-dimethoxy- = (C3H10N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C3H10N+ + C4H10O2 = (C3H10N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar26.7kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar34.8cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

C6H14N+ + Ethane, 1,2-dimethoxy- = (C6H14N+ bullet Ethane, 1,2-dimethoxy-)

By formula: C6H14N+ + C4H10O2 = (C6H14N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar29.4kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar35.5cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

CH6N+ + Ethane, 1,2-dimethoxy- = (CH6N+ bullet Ethane, 1,2-dimethoxy-)

By formula: CH6N+ + C4H10O2 = (CH6N+ bullet C4H10O2)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity Value Units Method Reference Comment
Deltar30.1kcal/molPHPMSMeot-Ner (Mautner), 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.1cal/mol*KPHPMSMeot-Ner (Mautner), 1983gas phase; M

(NH4+ bullet 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (NH4+ bullet 3Ethane, 1,2-dimethoxy-)

By formula: (H4N+ bullet 2C4H10O2) + C4H10O2 = (H4N+ bullet 3C4H10O2)

Quantity Value Units Method Reference Comment
Deltar14. ± 3.kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar27.3cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M

(NH4+ bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (NH4+ bullet 2Ethane, 1,2-dimethoxy-)

By formula: (H4N+ bullet C4H10O2) + C4H10O2 = (H4N+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar23.2kcal/molPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
Deltar33.5cal/mol*KPHPMSMeot-Ner (Mautner), Sieck, et al., 1996gas phase; M

(Sodium ion (1+) bullet 2Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Sodium ion (1+) bullet 3Ethane, 1,2-dimethoxy-)

By formula: (Na+ bullet 2C4H10O2) + C4H10O2 = (Na+ bullet 3C4H10O2)

Quantity Value Units Method Reference Comment
Deltar23.2kcal/molHPMSCastleman, Peterson, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar42.2cal/mol*KHPMSCastleman, Peterson, et al., 1983gas phase; M

Ethane, 1,2-dimethoxy- + Water = 2Methyl Alcohol + Acetaldehyde

By formula: C4H10O2 + H2O = 2CH4O + C2H4O

Quantity Value Units Method Reference Comment
Deltar8.6 ± 0.2kcal/molEqkWiberg, Morgan, et al., 1994liquid phase; ALS

2Methyl Alcohol + Acetaldehyde = Ethane, 1,2-dimethoxy- + Water

By formula: 2CH4O + C2H4O = C4H10O2 + H2O

Quantity Value Units Method Reference Comment
Deltar-14.8 ± 0.3kcal/molCmWiberg, Morgan, et al., 1994gas phase; ALS

(Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Li+ bullet C4H10O2) + C4H10O2 = (Li+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar33.2 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Cesium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Cs+ bullet C4H10O2) + C4H10O2 = (Cs+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar12.9 ± 1.7kcal/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Rubidium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Rb+ bullet C4H10O2) + C4H10O2 = (Rb+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar11.7 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Potassium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (K+ bullet C4H10O2) + C4H10O2 = (K+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar21.3 ± 2.9kcal/molCIDTRodgers and Armentrout, 2000RCD

(Copper ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Copper ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Cu+ bullet C4H10O2) + C4H10O2 = (Cu+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
Deltar43.0 ± 1.4kcal/molCIDTKoizumi, 2001RCD

Lithium ion (1+) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Li+ + C4H10O2 = (Li+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar37.8 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD

Cesium ion (1+) + Ethane, 1,2-dimethoxy- = (Cesium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Cs+ + C4H10O2 = (Cs+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar13.6 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Rubidium ion (1+) + Ethane, 1,2-dimethoxy- = (Rubidium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Rb+ + C4H10O2 = (Rb+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar22.5 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Copper ion (1+) + Ethane, 1,2-dimethoxy- = (Copper ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Cu+ + C4H10O2 = (Cu+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
Deltar63.1 ± 1.9kcal/molCIDTKoizumi, 2001RCD

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 114591

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, Chirico, et al., 1996
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Smith, N.K., Thermodynamic properties and ideal-gas enthalpies of formation for butyl vinyl ether, 1,2-dimethoxyethane, methyl glycolate, bicyclo[2.2.1]hept-2-ene, 5-vinylbicyclo[2.2.1]hept-2-ene, trans-azobenzene, butyl acrylate, di-tert-butyl ether, and hexane-1,6-diol, J. Chem. Eng. Data, 1996, 41, 1285-1302. [all data]

Wiberg, Morgan, et al., 1994
Wiberg, K.B.; Morgan, K.M.; Maltz, H., Thermochemistry of carbonyl reactions. 6. A study of hydration equilibria, J. Am. Chem. Soc., 1994, 116, 11067-11077. [all data]

Loucks and Laidler, 1967
Loucks, L.F.; Laidler, K.J., Thermochemistry of the methoxymethyl radical, Can. J. Chem., 1967, 45, 2785-2793. [all data]

Trejo, Costas, et al., 1991
Trejo, L.M.; Costas, M.; Patterson, D., Excess heat capacity of organic mixtures, Internat. DATA Series, Selected Data Mixt., 1991, Ser. [all data]

Kusano, Suurkuusk, et al., 1973
Kusano, K.; Suurkuusk, J.; Wads, I., Thermochemistry of solutions of biochemical model compounds. 2. Alkoxyethanols and 1,2-dialkoxyethanes in water, J. Chem. Thermodynam. 5,757-767 (1973).73LEB/TSV Lebedev, B.V., Tsvetkova, L.Ya., and Rabinovich, I.B., Specific heat and thermodynamic functions of poly(vinyltrimethylsilane), Tr. Khim. Khim. Tekhnol., 1973, (1), 17-18. [all data]

Guanquan, Ott, et al., 1986
Guanquan, C.; Ott, J.B.; Goates, J.R., (Solid+liquid) phase equilibria and solid-compound formation in 1,2-dimethoxyethane+tetrachloromethane, +trichlorofluoromethane, and +trichloromethane, J. Chem. Thermodyn., 1986, 18, 31. [all data]

Anonymous, 1982
Anonymous, X., Glymes Grant Chemical, 1982, Baton Rouge, LA 1982. [all data]

Quadri and Kudchadker, 1991
Quadri, S.K.; Kudchadker, A.P., Measurement of the critical temperatures and critical pressures of some thermally stable or mildly unstable esters, ketones, and ethers, J. Chem. Thermodyn., 1991, 23, 129-34. [all data]

Kobe, Ravicz, et al., 1956
Kobe, K.A.; Ravicz, A.E.; Vohra, S.P., Critical Properties and Vapor Pressures of Some Ethers and Heterocyclic Compounds, J. Chem. Eng. Data, 1956, 1, 50. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Li, Fang, et al., 2009
Li, Dan; Fang, Wenjun; Xie, Wenjie; Xing, Yan; Guo, Yongsheng; Lin, Ruisen, Measurements on Vapor Pressure and Thermal Conductivity for Pseudo-binary Systems of a Hydrocarbon Fuel with Ethylene and Diethylene Glycol Dimethyl Ethers, Energy Fuels, 2009, 23, 2, 794-798, https://doi.org/10.1021/ef8007163 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Stull, 1947
Stull, Daniel R., Vapor Pressure of Pure Substances. Organic and Inorganic Compounds, Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1994
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S.; Duan, X., The Ionic Hydrogen Bond. 5. Polydentate and Solvent-Bridged Structures. Complexing of the Proton and the Hydronium Ions by Polyethers, J. Am. Chem. Soc., 1994, 116, 17, 7848, https://doi.org/10.1021/ja00096a047 . [all data]

Armentrout and Rodgers, 2000
Armentrout, P.B.; Rodgers, M.T., An Absolute Sodium Cation Affinity Scale: Threshold Collision-Induced Dissociation Experiments and ab Initio Theory, J. Phys. Chem A, 2000, 104, 11, 2238, https://doi.org/10.1021/jp991716n . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

More, Ray, et al., 1997
More, M.B.; Ray, D.; Armentrout, P.B., Cation-ether complexes in the gas phase: Bond dissociation energies of Na+(dimethyl ether)(x), x=1-4; Na+(1,2-dimethoxyethane)(x), x=1 and 2; and Na+(12-crown-4), J. Phys. Chem. AJOURNAL OF PHYSICAL CHEMISTRY A 101 (5): 831-839 JAN 30 1997, 1997, 101, 831. [all data]

Castleman, Peterson, et al., 1983
Castleman, A.W.; Peterson, K.I.; Upschulte, B.L.; Schelling, F.J., Energetics and Structure of Na+ Cluster Ions, Int. J. Mass Spectrom. Ion Phys., 1983, 47, 203, https://doi.org/10.1016/0020-7381(83)87171-X . [all data]

McMahon and Ohanessian, 2000
McMahon, T.B.; Ohanessian, G., An Experimental and Ab Initio Study of the Nature of the Binding in Gas-Phase Complexes of Sodium Ions, Chem. Eur. J., 2000, 6, 16, 2931, https://doi.org/10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 . [all data]

Davidson and Kebarle, 1976
Davidson, W.R.; Kebarle, P., Binding Energies and Stabilities of Potassium Ion Complexes with Ethylene Diamine and Dimethoxyethane (Glyme) from Measurements of the Complexing Equilibria in the Gas Phase, Can. J. Chem., 1976, 54, 16, 2594, https://doi.org/10.1139/v76-368 . [all data]

Meot-Ner (Mautner), 1983
Meot-Ner (Mautner), M., The Ionic Hydrogen Bond. 3. Multiple and -CH+...O- Bonds. Complexes of Ammonium Ions with Polyethers and Crown Ethers, J. Am. Chem. Soc., 1983, 105, 15, 4912, https://doi.org/10.1021/ja00353a012 . [all data]

Meot-Ner (Mautner), Sieck, et al., 1996
Meot-Ner (Mautner), M.; Sieck, L.W.; Liebman, J.F.; Scheiner, S., Complexing of the Ammonium Ion by Polyethers. Comparative Complexing Thermochemistry of Ammonium, Hydronium, and Alkali Cations, J. Phys. Chem., 1996, 100, 16, 6445, https://doi.org/10.1021/jp9514943 . [all data]

Koizumi, 2001
Koizumi, H., Collision-Induced Dissociation and Theoretical Studies of Cu+-Dimethoxyethane Complexes, J. Am. Soc. Mass Spectrom., 2001, 12, 5, 480, https://doi.org/10.1016/S1044-0305(01)00242-2 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References