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1,4-Butanediol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-505.3 ± 5.7kJ/molCcrKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; ALS
Deltafliquid-503. ± 2.kJ/molCcbGardner and Hussain, 1972ALS
Quantity Value Units Method Reference Comment
Deltacliquid-2495.5 ± 5.7kJ/molCcrKnauth and Sabbah, 1990see Knauth and Sabbah, 1989; Corresponding «DELTA»fliquid = -507.7 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-2499.9 ± 2.0kJ/molCcbGardner and Hussain, 1972Corresponding «DELTA»fliquid = -503.25 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid223.4J/mol*KN/ANistratov, Babinkov, et al., 1979DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
200.1298.15Nistratov, Babinkov, et al., 1979T = 5 to 320 K.; DH
178.297.79Petit and TerMinassian, 1974T = 297 to 470 K. Value is unsmoothed experimental datum.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Knauth and Sabbah, 1990
Knauth, P.; Sabbah, R., Energetics of intra- and intermolecular bonds in «omega»-alkanediols (II) Thermochemical study of 1,2-ethanediol, 1,3-propanediol, 1,4-butanediol, and 1,5-pentanediol at 298.15K, Struct. Chem., 1990, 1, 43-46. [all data]

Knauth and Sabbah, 1989
Knauth, P.; Sabbah, R., Combustion calorimetry on milligram samples of liquid substances with a CRMT rocking bomb calorimeter. Application to the study of «omega»-alkanediol at 298.15 K, J. Chem. Thermodyn., 1989, 21, 203-210. [all data]

Gardner and Hussain, 1972
Gardner, P.J.; Hussain, K.S., The standard enthalpies of formation of some aliphatic diols, J. Chem. Thermodyn., 1972, 4, 819-827. [all data]

Nistratov, Babinkov, et al., 1979
Nistratov, V.P.; Babinkov, A.G.; Shvetsova, K.G.; Lapteva, S.A., Heat capacity and termodynamic functions of tetramethyleneglycol, Termodin. Org. Soedin., 1979, (8), 33-36. [all data]

Petit and TerMinassian, 1974
Petit, J.C.; TerMinassian, L., Measurements of (dV/dT)p, (dV/dP)T, and (dH/dT)p by flux calorimetry, J. Chem. Thermodynam., 1974, 6, 1139-1152. [all data]


Notes

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