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2-Butene, 1,4-dichloro-, (E)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
348.20.053Aldrich Chemical Company Inc., 1990BS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
10.9355.AStephenson and Malanowski, 1987Based on data from 340. - 379. K.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2-Butene, 1,4-dichloro-, (Z)- = 2-Butene, 1,4-dichloro-, (E)-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Deltar-0.17kcal/molEqkZakharova, Gul'neva, et al., 1991gas phase; Heat of isomerization at 383 K

2-Butene, 1,4-dichloro-, (E)- = 2-Butene, 1,4-dichloro-, (Z)-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Deltar-1.0kcal/molEqkLevanova, Yanshevskaya, et al., 1986liquid phase; solvent: Naphtha

2-Butene, 1,4-dichloro-, (E)- = 1-Butene, 3,4-dichloro-

By formula: C4H6Cl2 = C4H6Cl2

Quantity Value Units Method Reference Comment
Deltar1.5kcal/molEqkLevanova, Yanshevskaya, et al., 1986liquid phase; solvent: Naphta

IR Spectrum

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Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Phase change data, Reaction thermochemistry data, IR Spectrum, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin RADIAN CORP
NIST MS number 72921

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillarySE-54930.Weber, 198625. m/0.31 mm/0.17 «mu»m, H2, 2. K/min; Tstart: 35. C

References

Go To: Top, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Zakharova, Gul'neva, et al., 1991
Zakharova, L.A.; Gul'neva, I.V.; Shestakov, G.K.; Temkin, O.N.; Levanova, S.V.; Martirosyan, G.T.; Malkhasyan, A.Ts.; Asatryan, E.M., Isomerization of dichlorobutenes, Kinet. Catal., 1991, 32, 1190-1194, In original 1332. [all data]

Levanova, Yanshevskaya, et al., 1986
Levanova, S.V.; Yanshevskaya, I.V.; Asatryan, E.M.; Saakyan, N.L.; Kostand'yan, V.A.; Malkhasyan, A.Ts.; Martirosyan, G.T., Relationships of isomerization of the allylic type, J. Appl. Chem. USSR, 1986, 59, 790-793. [all data]

Weber, 1986
Weber, L., Utilization of the Sadtler standard RI system in micropollution analyses, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 8, 446-451, https://doi.org/10.1002/jhrc.1240090806 . [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, References