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n-Hexane

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Critical temperature

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director

Tc (K) Reference Comment
507.6 ± 0.2Ambrose and Tsonopoulos, 1995 
504.7Nikitin, Pavlov, et al., 1994Uncertainty assigned by TRC = 2. K; TRC; Data excluded from overall average
504.5Nikitin, Pavlov, et al., 1993Uncertainty assigned by TRC = 4. K; TRC; Data excluded from overall average
507.2Steele, 1992Uncertainty assigned by TRC = 1. K; TRC
507.5Quadri, Khilar, et al., 1991Uncertainty assigned by TRC = 0.4 K; TRC
507.3Anselme, Gude, et al., 1990Uncertainty assigned by TRC = 0.3 K; TRC
507.4Rosenthal and Teja, 1989Uncertainty assigned by TRC = 0.6 K; TRC
507.3Teja, Lee, et al., 1989TRC
507.53Brunner, 1988Uncertainty assigned by TRC = 0.1 K; Visual, optical cell 30cm high. TE cal. vs PRT; TRC
507.33Grigor'ev, Rastorguev, et al., 1988Uncertainty assigned by TRC = 0.4 K; TRC
507.4Majer and Svoboda, 1985 
507.4Mandlekar, Kay, et al., 1985Uncertainty assigned by TRC = 0.3 K; TRC
507.33Zawisza, 1985Uncertainty assigned by TRC = 0.4 K; TRC
507.86Genco, Teja, et al., 1980Uncertainty assigned by TRC = 0.15 K; TRC
507.68Mousa, 1977Uncertainty assigned by TRC = 0.2 K; TRC
507.55Kay and Young, 1975Uncertainty assigned by TRC = 0.2 K; TRC
507.85Kay and Young, 1975, 2Uncertainty assigned by TRC = 0.2 K; TRC
508.Young, 1975Uncertainty assigned by TRC = 0.5 K; TRC
507.4Young, 1975, 2Uncertainty assigned by TRC = 0.3 K; TRC
507.8Young, 1975, 3Uncertainty assigned by TRC = 0.3 K; TRC
507.7Young, 1975, 4Uncertainty assigned by TRC = 0.3 K; TRC
507.4Bone and Young, 1974Uncertainty assigned by TRC = 0.3 K; TRC
507.4Young, 1974Uncertainty assigned by TRC = 0.3 K; TRC
507.4Young, 1974, 2Uncertainty assigned by TRC = 0.3 K; TRC
507.4Young, 1974, 3Uncertainty assigned by TRC = 0.3 K; TRC
507.4Young, 1974, 4Uncertainty assigned by TRC = 0.3 K; TRC
507.4Young, 1974, 5Uncertainty assigned by TRC = 0.3 K; TRC
507.4Young, 1974, 6Uncertainty assigned by TRC = 0.3 K; TRC
507.68Mousa, Kay, et al., 1972Uncertainty assigned by TRC = 0.2 K; TRC
507.3Pak and Kay, 1972Uncertainty assigned by TRC = 0.4 K; TRC
508.5Raetzsch and Strauch, 1972Uncertainty assigned by TRC = 0.6 K; TRC; Data excluded from overall average
508.Tashmukhamedov, 1972Uncertainty assigned by TRC = 0.6 K; TRC
507.85Kreglewski and Kay, 1969Uncertainty assigned by TRC = 0.25 K; TRC
507.6Kay and Hissong, 1967Uncertainty assigned by TRC = 0.2 K; TRC
507.9Kay, 1964Uncertainty assigned by TRC = 0.4 K; TRC
507.3Ambrose, Cox, et al., 1960Uncertainty assigned by TRC = 0.2 K; Visual, PRT, IPTS-48; TRC
507.65Partington, Rowlinson, et al., 1960Uncertainty assigned by TRC = 0.1 K; Visual, THg; TRC
507.95Glaser and Ruland, 1957Uncertainty assigned by TRC = 1.5 K; TRC
509.85Kreglewski, 1957Uncertainty assigned by TRC = 0.2 K; TRC; Data excluded from overall average
507.9Nichols, Reamer, et al., 1957Uncertainty assigned by TRC = 2.22 K; TRC
507.9Kay, 1946Uncertainty assigned by TRC = 0.3 K; TRC
500.7Ipatieff and Monroe, 1942Uncertainty assigned by TRC = 7. K; TRC; Data excluded from overall average
508.0Young, 1910Uncertainty assigned by TRC = 1. K; TRC
507.7Altschul, 1893Uncertainty assigned by TRC = 1. K; TRC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Critical temperature, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ambrose and Tsonopoulos, 1995
Ambrose, D.; Tsonopoulos, C., Vapor-Liquid Critical Properties of Elements and Compounds. 2. Normal Alkenes, J. Chem. Eng. Data, 1995, 40, 531-546. [all data]

Nikitin, Pavlov, et al., 1994
Nikitin, E.D.; Pavlov, P.A.; Bessonova, N.V., Critical constants of n-alkanes with from 17 to 24 carbon atoms, J. Chem. Thermodyn., 1994, 26, 177-82. [all data]

Nikitin, Pavlov, et al., 1993
Nikitin, E.D.; Pavlov, P.A.; Skripov, P.V., Measurement of the critical properties of thermally unstable substances and mixtures by the pulse-heating method, J. Chem. Thermodyn., 1993, 25, 869-80. [all data]

Steele, 1992
Steele, W.V., Personal Commun. 1992 1992, 1992. [all data]

Quadri, Khilar, et al., 1991
Quadri, S.K.; Khilar, K.C.; Kudchadker, A.P.; Patni, M.J., Measurement of the critical temperatures and critical pressures of some thermally stable or mildly unstable alkanols, J. Chem. Thermodyn., 1991, 23, 67-76. [all data]

Anselme, Gude, et al., 1990
Anselme, M.J.; Gude, M.; Teja, A.S., The Critical Temperatures and Densities of the n-Alkanes from Pentane to Octadecane, Fluid Phase Equilib., 1990, 57, 317-26. [all data]

Rosenthal and Teja, 1989
Rosenthal, D.J.; Teja, A.S., The Critical Properties of n-Alkanes Using a Low-Residence Time Flow Apparatus, AIChE J., 1989, 35, 1829. [all data]

Teja, Lee, et al., 1989
Teja, A.S.; Lee, R.J.; Rosenthal, D.J.; Anselme, M.J., Correlation of the Critical Properties of Alkanes and Alkanols in 5th IUPAC Conference on Alkanes and AlkanolsGradisca, 1989. [all data]

Brunner, 1988
Brunner, E., Fluid Mixtures at High Pressures VI. Phase Separation and Critical Phenomena in 18 (n-Alkane + Ammonia) and 4 (n-Alkane _ Methanol) Mixtures, J. Chem. Thermodyn., 1988, 20, 273. [all data]

Grigor'ev, Rastorguev, et al., 1988
Grigor'ev, B.A.; Rastorguev, Yu.L.; Gerasimov, A.A.; Kurumov, D.S.; Plotnikov, S.A., Thermodynamic properties of n-hexane, Int. J. Thermophys., 1988, 9, 439. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Mandlekar, Kay, et al., 1985
Mandlekar, A.V.; Kay, W.B.; Smith, R.L.; Teja, A.S., Phase equilibria in the n-hexane + diethylamine system, Fluid Phase Equilib., 1985, 23, 79. [all data]

Zawisza, 1985
Zawisza, A., High-pressure liquid-vapour equilibria, critical state, and p(Vm,T,x) to 44 8.15 K and 4.053 MPa for {xC6H14 + (1-x)CH3OH}., J. Chem. Thermodyn., 1985, 17, 941-947. [all data]

Genco, Teja, et al., 1980
Genco, J.M.; Teja, A.S.; Kay, W.B., Study of the critical and azeotropic behavior of binary mixtures I critical states of perfluoromethylcyclohexane + isomeric hexane systems, J. Chem. Eng. Data, 1980, 25, 350. [all data]

Mousa, 1977
Mousa, A.H.N., The Physical properties of highly purified purified samnples of propane and n-hexane, J. Chem. Thermodyn., 1977, 9, 1063-5. [all data]

Kay and Young, 1975
Kay, W.B.; Young, C.L., Gas-liquid critical properties. 2-Butanone (methyl ethyl Ketone)-n-hexane system, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, No. 2, 155. [all data]

Kay and Young, 1975, 2
Kay, W.B.; Young, C.L., Gas-liquid critical properties. Tetradecafluoromethylcyclohexane( perfluoromethylcyclohexane)-n-hexane system, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, No. 1, 52. [all data]

Young, 1975
Young, C.L., Gas-liquid critical properties. 2-Methylpentane-n-hexane system, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, No. 2, 157. [all data]

Young, 1975, 2
Young, C.L., Gas-liquid critical properties. Diisopropyl ether-n-hexane system, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, No. 2, 159. [all data]

Young, 1975, 3
Young, C.L., Gas-liquid critical properties. Triethylamine-n-hexane system, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, No. 1, 67. [all data]

Young, 1975, 4
Young, C.L., Gas-liquid critical properties. Diethyl ether-n-hexane system, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1975, No. 1, 70. [all data]

Bone and Young, 1974
Bone, K.M.; Young, C.L., Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1974, No. 1, 50. [all data]

Young, 1974
Young, C.L., Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1974, No. 1, 47. [all data]

Young, 1974, 2
Young, C.L., Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1974, No. 1, 48. [all data]

Young, 1974, 3
Young, C.L., Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1974, No. 1, 49. [all data]

Young, 1974, 4
Young, C.L., Gas-Liquid Critical Temperature. 1-Propanol (Propyl Alcohol)-n-Hexane System, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1974, No. 1, 50. [all data]

Young, 1974, 5
Young, C.L., Gas-Liquid Critical Temperature. 1-Butanol (Butyl Alcohol)-n-Hexane System, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1974, No. 1, 53. [all data]

Young, 1974, 6
Young, C.L., Gas-Liquid Critical Temperature. 2-Propanol (Isopropyl Alcohol)-n-Hexane System, Int. DATA Ser., Sel. Data Mixtures, Ser. A, 1974, No. 1, 57. [all data]

Mousa, Kay, et al., 1972
Mousa, A.H.N.; Kay, W.B.; Kreglewski, A., The critical constants of binary mixtures of certain perfluoro-compounds with alkanes, J. Chem. Thermodyn., 1972, 4, 301-11. [all data]

Pak and Kay, 1972
Pak, S.C.; Kay, W.B., Gas-Liquid Critical Temperatures of Mixtures. Benzene + n-Alkanes and Hexafluorobenzene + n-Alkanes, Ind. Eng. Chem. Fundam., 1972, 11, 255. [all data]

Raetzsch and Strauch, 1972
Raetzsch, M.T.; Strauch, G., Gas-Liquid Critical Temperatures of Binary Mixtures, Z. Phys. Chem. (Leipzig), 1972, 249, 243-252. [all data]

Tashmukhamedov, 1972
Tashmukhamedov, F., Determination of Critical Temperatures from Ultrasonic Data in Azeotropic Hexane-Ethanol Mixtures, Sov. Phys. - Acoust. (Engl. Transl.), 1972, 17, 527-8. [all data]

Kreglewski and Kay, 1969
Kreglewski, A.; Kay, W.B., The Critical Constants of Conformal Mixtures, J. Phys. Chem., 1969, 73, 3359. [all data]

Kay and Hissong, 1967
Kay, W.B.; Hissong, D.W., The Critical Properties of Hydrocarbons I. Simple Mixtures, Proc. - Am. Pet. Inst., Div. Refin., 1967, 47, 653. [all data]

Kay, 1964
Kay, W.B., P-T-x Diagrams in the Critical Region. Acetone-n-Alkane Systems, J. Phys. Chem., 1964, 68, 827-31. [all data]

Ambrose, Cox, et al., 1960
Ambrose, D.; Cox, J.D.; Townsend, R., The critical temperatures of forty organic compounds, Trans. Faraday Soc., 1960, 56, 1452. [all data]

Partington, Rowlinson, et al., 1960
Partington, E.J.; Rowlinson, J.S.; Weston, J.F., The Gas-Liquid Critical Temperatures of Binary Mixtures. Part 1., Trans. Faraday Soc., 1960, 56, 479. [all data]

Glaser and Ruland, 1957
Glaser, F.; Ruland, H., Untersuchungsen über dampfdruckkurven und kritische daten einiger technisch wichtiger organischer substanzen, Chem. Ing. Techn., 1957, 29, 772. [all data]

Kreglewski, 1957
Kreglewski, A., Critical temperatures of the mixtures of acetic acid and pyridine with n-paraffins, Rocz. Chem., 1957, 31, 1001. [all data]

Nichols, Reamer, et al., 1957
Nichols, W.B.; Reamer, H.H.; Sage, B.H., Volumetric and Phase Behavior in the Hydrogen-Hexane System, AIChE J., 1957, 3, 262. [all data]

Kay, 1946
Kay, W.B., The Vapor Pressures and Saturated Liquid and Vapor Densities of the Isomeric Hexanes, J. Am. Chem. Soc., 1946, 68, 1336. [all data]

Ipatieff and Monroe, 1942
Ipatieff, V.N.; Monroe, G.S., Determination of Critical Temperatures by the Rotating Bomb, Ind. Eng. Chem., Anal. Ed., 1942, 14, 171-4. [all data]

Young, 1910
Young, S., The Internal Heat of Vaporization constants of thirty pure substances, Sci. Proc. R. Dublin Soc., 1910, 12, 374. [all data]

Altschul, 1893
Altschul, M., The critical values of some organic compounds, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1893, 11, 577. [all data]


Notes

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