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diacetyl peroxide


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Glushko Thermocenter, Russian Academy of Sciences, Moscow

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
13.1350.Dorofeeva O.V., 1997p=1 bar.
18.46100.
22.27150.
25.801200.
32. ± 1.298.15
32.612300.
38.967400.
44.541500.
49.257600.
53.217700.
56.554800.
59.376900.
61.7761000.
63.8221100.
65.5741200.
67.0751300.
68.3681400.
69.4841500.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-127.9 ± 2.4kcal/molCcbJaffe, Prosen, et al., 1957 
Quantity Value Units Method Reference Comment
Deltacliquid-453.3 ± 2.2kcal/molCcbJaffe, Prosen, et al., 1957Corresponding «DELTA»fliquid = -127.9 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert L. Brown and Stephen E. Stein

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference
336.20.028Weast and Grasselli, 1989

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dorofeeva O.V., 1997
Dorofeeva O.V., Unpublished results. Thermocenter of Russian Academy of Science, Moscow, 1997. [all data]

Jaffe, Prosen, et al., 1957
Jaffe, L.; Prosen, E.J.; Szwarc, M., Heats of combustion of some peroxides and the heats of formation of acetate, propionate, and butyrate radicals, J. Chem. Phys., 1957, 27, 416-420. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References