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Fumaric Acid

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tfus560.45KN/AWilhoit and Shiao, 1964Uncertainty assigned by TRC = 4. K; TRC
Tfus562.55KN/AWilhoit and Shiao, 1964Uncertainty assigned by TRC = 0.5 K; TRC
Tfus375.KN/ATimmermans, 1935Uncertainty assigned by TRC = 2. K; TRC
Tfus473.KN/AKern, Shriner, et al., 1925Uncertainty assigned by TRC = 4. K; TRC
Tfus557.15KN/AWeiss and Downs, 1923Uncertainty assigned by TRC = 4. K; TRC

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
29.54 ± 0.48381.TE,MEDe Kruif and Van Ginkel, 1977Based on data from 371. - 391. K.; AC
32.5 ± 1.5365.QFWolf and Weghofer, 1938See also Trieschmann, 1935 and Jones, 1960.; AC
32.5 ± 1.5365.VWolf and Weghofer, 1938, 2ALS
32.0 ± 1.0358. - 371.N/AWolf and Trieschmann, 1934AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wilhoit and Shiao, 1964
Wilhoit, R.C.; Shiao, D., Thermochemistry of Biologically Important Compounds. Heats of Combustion of Solid Organic Acids, J. Chem. Eng. Data, 1964, 9, 595. [all data]

Timmermans, 1935
Timmermans, J., Researches in Stoichiometry. I. The Heat of Fusion of Organic Compounds., Bull. Soc. Chim. Belg., 1935, 44, 17-40. [all data]

Kern, Shriner, et al., 1925
Kern, J.W.; Shriner, R.L.; Adams, R., Platinum and Palladium Oxides as Catalysts in the Reduction of Organic Compounds IX. The Reduction of Olefins, J. Am. Chem. Soc., 1925, 47, 1147. [all data]

Weiss and Downs, 1923
Weiss, J.M.; Downs, C.R., The Physical Properties of Maleic, Fumaric and Malic Acids, J. Am. Chem. Soc., 1923, 45, 1003. [all data]

De Kruif and Van Ginkel, 1977
De Kruif, C.G.; Van Ginkel, C.H.D., Torsion-weighing effusion vapour-pressure measurements on organic compounds, The Journal of Chemical Thermodynamics, 1977, 9, 8, 725-730, https://doi.org/10.1016/0021-9614(77)90015-5 . [all data]

Wolf and Weghofer, 1938
Wolf, K.L.; Weghofer, H.Z., Z. Phys. Chem. Abt. B, 1938, 39, 194. [all data]

Trieschmann, 1935
Trieschmann, H.G., , Ph.D. Dissertation, Inst. Fur Phys. Chem. and Electrochem. der Universitat Kiel, Germany, 1935. [all data]

Jones, 1960
Jones, A.H., Sublimation Pressure Data for Organic Compounds., J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019 . [all data]

Wolf and Weghofer, 1938, 2
Wolf, K.L.; Weghofer, H., Uber sublimationswarmen, Z. Phys. Chem., 1938, 39, 194-208. [all data]

Wolf and Trieschmann, 1934
Wolf, K.L.; Trieschmann, H.G., Z. Phys. Chem. Abt. B, 1934, 27, 376. [all data]


Notes

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