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Ethanamine, N-ethyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Deltafgas-99.8kJ/molN/ALemoult, 1907Value computed using «DELTA»fHliquid° value of -131 kj/mol from Lemoult, 1907 and «DELTA»vapH° value of 31.18±0.06 kj/mol from missing citation.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-131.kJ/molCcbLemoult, 1907ALS
Quantity Value Units Method Reference Comment
Deltacliquid-3035.kJ/molCcbLemoult, 1907ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
178.1298.15Costas and Patterson, 1985T = 283.15, 298.15, 313.15 K.; DH
178.1298.15Costas and Patterson, 1985, 2DH
106.3290.Kurnakov and Voskresenskaya, 1936DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C3H9Sn+ + Ethanamine, N-ethyl- = (C3H9Sn+ bullet Ethanamine, N-ethyl-)

By formula: C3H9Sn+ + C4H11N = (C3H9Sn+ bullet C4H11N)

Quantity Value Units Method Reference Comment
Deltar194.kJ/molPHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar140.J/mol*KN/AStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
122.525.PHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH, Entropy change calculated or estimated; M

N,N'-Dithiobisdiethylamine + 2Diethylamine, hydrochloride = Sulfur monochloride + 4Ethanamine, N-ethyl-

By formula: C8H20N2S2 + 2C4H12ClN = Cl2S2 + 4C4H11N

Quantity Value Units Method Reference Comment
Deltar365.3 ± 2.9kJ/molCmClaydon and Mortimer, 1962liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 368. ± 3. kJ/mol; ALS

Tetraethyl sulphamide + 2Diethylamine, hydrochloride = 4Ethanamine, N-ethyl- + sulphuryl dichloride

By formula: C8H20N2O2S + 2C4H12ClN = 4C4H11N + Cl2O2S

Quantity Value Units Method Reference Comment
Deltar543.9 ± 7.1kJ/molCmClaydon and Mortimer, 1962liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 543.1 ± 7.1 kJ/mol; ALS

sulphinylbis(diethylamide) + 2Diethylamine, hydrochloride = 4Ethanamine, N-ethyl- + Thionyl chloride

By formula: C8H20N2OS + 2C4H12ClN = 4C4H11N + Cl2OS

Quantity Value Units Method Reference Comment
Deltar379.5 ± 4.2kJ/molCmClaydon and Mortimer, 1962liquid phase; Reanalyzed by Cox and Pilcher, 1970, Original value = 393. ± 4.2 kJ/mol; ALS

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lemoult, 1907
Lemoult, M.P., Recherches theoriques et experimentales sur les chaleurs de combustion et de formation des composes organiques, Ann. Chim. Phys., 1907, 12, 395-432. [all data]

Costas and Patterson, 1985
Costas, M.; Patterson, D., Heat capacities of water + organic-solvent mixtures, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 2381-2398. [all data]

Costas and Patterson, 1985, 2
Costas, M.; Patterson, D., Self-association of alcohols in inert solvents, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 635-654. [all data]

Kurnakov and Voskresenskaya, 1936
Kurnakov, N.S.; Voskresenskaya, N.K., Calorimetry of liquid binary systems, Izv. Akad. Nauk SSSR, Otdel. Mat. i Estestv. Nauk. Ser. Khim, 1936, 1936, 439-461. [all data]

Stone and Splinter, 1984
Stone, J.A.; Splinter, D.E., A high-pressure mass spectrometric study of the binding of (CH3)3Sn+ to lewis bases in the gas phase, Int. J. Mass Spectrom. Ion Processes, 1984, 59, 169. [all data]

Claydon and Mortimer, 1962
Claydon, A.P.; Mortimer, C.T., Heats of formation and bond energies. Part VIII. Diethylaminotrimethylsilane, NN'-dithiodiethylamine, NN'-thionylbisdiethylamine, and NN'-sulphurylbisdiethylamine, J. Chem. Soc., 1962, 3212-3216. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]


Notes

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