Ethanol, 2-(methylamino)-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil431.2KN/AWeast and Grasselli, 1989BS
Tboil428. to 429.KN/ABuckingham and Donaghy, 1982BS
Quantity Value Units Method Reference Comment
Tc630.KN/ASteele, Chirico, et al., 1997Uncertainty assigned by TRC = 10. K; derived from fit of obs. vapor pressure; TRC
Quantity Value Units Method Reference Comment
Pc53.00barN/ASteele, Chirico, et al., 1997Uncertainty assigned by TRC = 5.00 bar; derived from fit of obs. vapor pressure; TRC
Quantity Value Units Method Reference Comment
ρc3.86mol/lN/ASteele, Chirico, et al., 1997Uncertainty assigned by TRC = 0.27 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap57.8 ± 0.2kJ/molGSKapteina, Slowik, et al., 2005Based on data from 275. to 320. K.; AC
Δvap57.9kJ/molN/ANoll, Valtz, et al., 1998Based on data from 269. to 401. K. See also Kapteina, Slowik, et al., 2005.; AC
Δvap57.0 ± 0.5kJ/molEBSteele, Chirico, et al., 1997, 2Based on data from 340. to 461. K.; AC
Δvap57.6kJ/molEBSmirnova, Tereshchenko, et al., 1987Based on data from 351. to 410. K. See also Kapteina, Slowik, et al., 2005.; AC
Δvap57.5kJ/molN/ATouhara, Okazaki, et al., 1982Based on data from 298. to 308. K. See also Kapteina, Slowik, et al., 2005.; AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
388. to 391.0.007Buckingham and Donaghy, 1982BS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C3H9NO+ (ion structure unspecified)

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H7N+8.99CH2OHEILossing, Lam, et al., 1981 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Steele, Chirico, et al., 1997
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A., Vapor Pressure, Heat Capacity, and Density along the Saturted Line, Measurements for Cyclohexanol, 2-Cyclohexen-1-one, 1,2-Dichloropropane, 1,4-Di-tert-butylbenzene, (±)-2-Ethylhexanoic Acid, 1-(m, J. Chem. Eng. Data, 1997, 42, 1021-36. [all data]

Kapteina, Slowik, et al., 2005
Kapteina, Simon; Slowik, Krzysztof; Verevkin, Sergey P.; Heintz, Andreas, Vapor Pressures and Vaporization Enthalpies of a Series of Ethanolamines, J. Chem. Eng. Data, 2005, 50, 2, 398-402, https://doi.org/10.1021/je049761y . [all data]

Noll, Valtz, et al., 1998
Noll, O.; Valtz, A.; Richon, D.; Getachew-Sawaya, T.; Mokbel, I.; Jose, J., Vapor pressures and liquid densities of N-methylethanolamine, diethanolamine, and N-methyldiethanolamine, ELDATA: Int. Electron. J. Phys. Chem. Data, 1998, 4, 3, 105. [all data]

Steele, Chirico, et al., 1997, 2
Steele, W.V.; Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A., Vapor Pressure, Heat Capacity, and Density along the Saturation Line, Measurements for Cyclohexanol, 2-Cyclohexen-1-one, 1,2-Dichloropropane, 1,4-Di- tert -butylbenzene, (±)-2-Ethylhexanoic Acid, 2-(Methylamino)ethanol, Perfluoro- n -heptane, and Sulfolane, J. Chem. Eng. Data, 1997, 42, 6, 1021-1036, https://doi.org/10.1021/je9701036 . [all data]

Smirnova, Tereshchenko, et al., 1987
Smirnova, G.G.; Tereshchenko, G.F.; Blagushina, M.A., Zh. Prikl. Khim. (S.-Peterburg), 1987, 62, 182. [all data]

Touhara, Okazaki, et al., 1982
Touhara, H.; Okazaki, S.; Okino, F.; Tanaka, H.; Ikari, K.; Nakanishi, K., Thermodynamic properties of aqueous mixtures of hydrophilic compounds 2. Aminoethanol and its methyl derivatives, The Journal of Chemical Thermodynamics, 1982, 14, 2, 145-156, https://doi.org/10.1016/0021-9614(82)90026-X . [all data]

Lossing, Lam, et al., 1981
Lossing, F.P.; Lam, Y.-T.; Maccoll, A., Gas phase heats of formation of alkyl immonium ions, Can. J. Chem., 1981, 59, 2228. [all data]


Notes

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