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Butane, 1-bromo-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-148.kJ/molCmHolm, 1973Grignard Rx; ALS
Deltafliquid-143.8 ± 1.3kJ/molCcrBjellerup, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -144.2 ± 1.3 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-2716.5 ± 1.3kJ/molCcrBjellerup, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -2716.1 ± 1.3 kJ/mol; ALS
Quantity Value Units Method Reference Comment
liquid327.02J/mol*KN/ADeese, 1931Extrapolation below 100 K, 42.84 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
162.2298.15Shehatta, 1993DH
151.0298.Kurbatov, 1948T = 13 to 100°C, mean Cp, two temperatures.; DH
152.21292.3Deese, 1931T = 94 to 293 K. Value is unsmoothed experimental datum.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Holm, 1973
Holm, T., Thermochemistry of Grignard reagents. Enthalpies of formation of alkylmagnesium bromides and of alkyl bromides, J. Organomet. Chem., 1973, 56, 87-93. [all data]

Bjellerup, 1961
Bjellerup, L., Heats of combustion and formation of the 1-bromoalkanes from C4 through C8, Acta Chem. Scand., 1961, 15, 231-241. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Deese, 1931
Deese, R.F., Jr., Thermal energy studies. IV. Comparison of continuous and discontinuous methods of measuring heat capacities. Heat capacities of some alphatic bromides, J. Am. Chem. Soc., 1931, 53, 3673-3683. [all data]

Shehatta, 1993
Shehatta, I., Heat capacity at constant pressure of some halogen compounds, Thermochim. Acta, 1993, 213, 1-10. [all data]

Kurbatov, 1948
Kurbatov, V.Ya., Heat capacity of liquids. 2. Heat capacity and the temperature dependence of heat capacity from halogen derivatives of acylic hydrocarbons, Zh. Obshch. Kim., 1948, 18, 372-389. [all data]


Notes

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