Pyrazine, methyl-

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5MSSPB-5CP Sil 8 CBHP-5
Column length (m) 60.30.60.50.25.
Carrier gas  HeHe He
Substrate      
Column diameter (mm) 0.320.250.320.320.2
Phase thickness (μm) 1.0.251. 1.
Tstart (C) 40.50.40.60.40.
Tend (C) 260.260.230.220.280.
Heat rate (K/min) 4.10.3.4.5.
Initial hold (min) 2.5.5.5. 
Final hold (min) 10. 5.30.5.
I 827.826.823.816.839.
ReferenceMethven L., Tsoukka M., et al., 2007Cerny and Guntz-Dubini, 2006Deport, Ratel, et al., 2006Mahadevan and Farmer, 2006Solina, Baumgartner, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5CP-Sil 8CB-MSHP-5BPX-5DB-5
Column length (m) 25.60.30.50.30.
Carrier gas He   He
Substrate      
Column diameter (mm) 0.20.250.250.320.25
Phase thickness (μm) 1.0.250.10.51.
Tstart (C) 40.40.-30.60.50.
Tend (C) 280.280.250.250.200.
Heat rate (K/min) 5.4.10.4.2.5
Initial hold (min)  2.1.5. 
Final hold (min) 5.5.5.20. 
I 839.833.825.843.825.
ReferenceSolina, Baumgartner, et al., 2005Hierro, de la Hoz, et al., 2004Siegmund and Murkovic, 2004Bredie, Mottram, et al., 2002Dallüge, van Stee, et al., 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP Sil 8 CBCP Sil 8 CBBPX-5BPX-5BPX-5
Column length (m) 60.60.50.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.320.320.32
Phase thickness (μm) 0.250.250.50.50.25
Tstart (C) 40.40.60.60.60.
Tend (C) 250.250.250.250.250.
Heat rate (K/min) 4.4.4.4.4.
Initial hold (min) 8.8.5.5.5.
Final hold (min) 10.10.10.10.10.
I 837.838.830.830.839.
ReferenceDuckham, Dodson, et al., 2002Duckham, Dodson, et al., 2002Ames, Guy, et al., 2001Ames, Guy, et al., 2001Ames, Guy, et al., 2001, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BPX-5DB-1BPX-5BPX-5BPX-5
Column length (m) 50.60.50.50.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.320.320.320.32
Phase thickness (μm) 0.251.0.250.250.25
Tstart (C) 60.40.35.35.35.
Tend (C) 250.220.250.250.250.
Heat rate (K/min) 4.2.4.4.4.
Initial hold (min) 5.5.3.3.3.
Final hold (min) 10. 10.10.10.
I 839.795.836.837.837.
ReferenceAmes, Guy, et al., 2001, 2Kim, 2001Oruna-Concha, Duckham, et al., 2001Oruna-Concha, Duckham, et al., 2001Oruna-Concha, Duckham, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BPX-5BP-5SE-54CP Sil 8 CBDB-1
Column length (m) 50.50.25.60.60.
Carrier gas He  HeN2
Substrate      
Column diameter (mm) 0.320.320.310.250.25
Phase thickness (μm) 0.25  0.251.
Tstart (C) 35.60.35.40.30.
Tend (C) 250.250.230.280.200.
Heat rate (K/min) 4.4.4.4.5.
Initial hold (min) 3. 3.2. 
Final hold (min) 10. 10. 30.
I 837.825.823.19829.802.
ReferenceOruna-Concha, Duckham, et al., 2001Whitfield and Mottram, 2001Yin, Xiu, et al., 2001Elmore, Mottram, et al., 2000Wu, Wang, et al., 2000
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase BPX-5BPX-5BPX-5DB-1DB-1
Column length (m) 50.50.50.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.3250.3250.3250.2480.248
Phase thickness (μm) 0.50.50.50.250.25
Tstart (C) 20.20.50.50.50.
Tend (C) 250.250.250.250.250.
Heat rate (K/min) 4.4.4.5.5.
Initial hold (min) 2.2.2.5.5.
Final hold (min) 10.10.10.  
I 833.835.833.796.798.
ReferenceHill, Isaacs, et al., 1999Hill, Isaacs, et al., 1999Ames, Defaye, et al., 1997DeMilo, Lee, et al., 1996DeMilo, Lee, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-1OV-1SPB-1SE-30DB-1
Column length (m) 30. 30.50.60.
Carrier gas He HeHeHe
Substrate      
Column diameter (mm) 0.248 0.250.320.25
Phase thickness (μm) 0.25 0.250.251.0
Tstart (C) 50.35.50.50.40.
Tend (C) 250.300.250.250.260.
Heat rate (K/min) 5.8.5.8.2.
Initial hold (min) 5. 5. 5.
Final hold (min)     60.
I 798.794.7799.800.792.
ReferenceDeMilo, Lee, et al., 1996Gautzsch and Zinn, 1996Lee, DeMilo, et al., 1995Misharina, Golovnya, et al., 1994Yu, Lin, et al., 1994
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-1HP-1HP-1OV-101OV-101
Column length (m) 50.50.50.50.50.
Carrier gas HeHe HeHe
Substrate      
Column diameter (mm) 0.320.320.320.250.25
Phase thickness (μm) 1.051.051.5  
Tstart (C) 40.40.40.100.70.
Tend (C) 260.260.220.  
Heat rate (K/min) 2.2.2.2.8.
Initial hold (min)      
Final hold (min) 10.40.30.  
I 805.799.799.805.1802.5
ReferenceOh, Hartman, et al., 1992Oh, Shu, et al., 1992Zhang, Dorjpalam, et al., 1992Golovnya, Samusenko, et al., 1991Golovnya, Samusenko, et al., 1991
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101DB-1SE-30HP-1DB-1
Column length (m) 50.50.50.50.60.
Carrier gas HeHe HeHe
Substrate      
Column diameter (mm) 0.250.320.320.320.25
Phase thickness (μm)  1.050.251.050.25
Tstart (C) 80.40.50.40.40.
Tend (C)  260.240.260.220.
Heat rate (K/min) 4.2.4.2.2.
Initial hold (min)      
Final hold (min)  40. 10.10.
I 802.8798.799.798.799.
ReferenceGolovnya, Samusenko, et al., 1991Izzo and Ho, 1991Misharina, Golovnya, et al., 1991Oh, Shu, et al., 1991Zhang and Ho, 1991
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase SPB-1SPB-1OV-1
Column length (m) 60.60.183.
Carrier gas HeHeN2
Substrate    
Column diameter (mm) 0.250.25 
Phase thickness (μm) 0.250.25 
Tstart (C) 35.35.0.
Tend (C) 235.235.230.
Heat rate (K/min) 2.2.1.
Initial hold (min) 10.10. 
Final hold (min) 40.40. 
I 807.807.798.
ReferenceHuang, Bruechert, et al., 1987Huang, Bruechert, et al., 1987Schreyen, Dirinck, et al., 1976
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Methven L., Tsoukka M., et al., 2007
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Dallüge, van Stee, et al., 2002
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Duckham, Dodson, et al., 2002
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Ames, Guy, et al., 2001, 2
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Kim, 2001
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Oruna-Concha, Duckham, et al., 2001
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Whitfield, F.B.; Mottram, D.S., Heterocyclic volatiles formed by heating cysteine or hydrogen sulfide with 4-hydroxy-5-methyl-3(2H)-furanone at pH 6.5, J. Agric. Food Chem., 2001, 49, 2, 816-822, https://doi.org/10.1021/jf0008644 . [all data]

Yin, Xiu, et al., 2001
Yin, W.; Xiu, Z.; Aijin, H., Analysis of the volatile components in trogopterorum feces by capillary gas chromatography and gas chromatography/mass spectrometry, Fenxi Huaxue, 2001, 29, 2, 195-198. [all data]

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Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References