Pyridine, 2-methyl-

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Kovats' RI, non-polar column, isothermal

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type PackedCapillaryCapillaryPackedCapillary
Active phase C78, Branched paraffinOV-101OV-101C78, Branched paraffinHP-1
Column length (m) 3.3 50.3.325.
Carrier gas HeHeHe N2
Substrate    Chromosorb G HP 
Column diameter (mm)   0.3 0.20
Phase thickness (μm)  0.40.4  
Temperature (C) 130.110.110.130.60.
I 802.3814.804.802.2799.
ReferenceDallos, Sisak, et al., 2000Golovnya, Kuz'menko, et al., 2000Zhuravleva, 2000Reddy, Dutoit, et al., 1992Zhang, Li, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPackedCapillaryCapillaryCapillary
Active phase HP-1ApolaneSE-30SE-30OV-101
Column length (m) 25.3.725.25.20.
Carrier gas N2 HeHeN2
Substrate      
Column diameter (mm) 0.20 0.320.320.23
Phase thickness (μm)   1.1. 
Temperature (C) 60.130.110.80.150.
I 800.803.804.800.814.
ReferenceZhang, Li, et al., 1992Dutoit, 1991Samusenko and Golovnya, 1988Samusenko and Golovnya, 1988Morishita, Morimoto, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101OV-101OV-101
Column length (m) 25.35.35.35.50.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.1560.1250.1250.1250.125
Temperature (C) 80.80.80.80.80.
I 800.799.799.801.802.
ReferenceSamusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Apiezon LH + KFApiezon LH + KFApiezon LH + KFApiezon LH + KFApiezon LH + KF
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.0630.0630.0630.0630.063
Temperature (C) 100.100.100.100.100.
I 816.818.818.819.819.
ReferenceSamusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Apiezon LH + KFApiezon LH + KFApiezon L + KFApiezon L + KFApiezon L + KF
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.0630.0630.0630.0630.063
Temperature (C) 100.100.100.100.100.
I 819.819.816.816.816.
ReferenceSamusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Apiezon L + KFApiezon L + KFApiezon L + KFApiezon L + KFApiezon L + KF
Column length (m) 30.30.30.30.30.
Carrier gas HeHeHeHe 
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.0630.0630.0630.0630.06
Temperature (C) 100.100.100.100.100.
I 817.818.818.818.816.
ReferenceSamusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Samusenko, Svetlova, et al., 1986Svetlova, Samusenko, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Apiezon L + KFApiezon L + KFApiezon L + KFApiezon L + KFApiezon L + KF
Column length (m) 30.30.30.30.30.
Carrier gas      
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.060.060.060.060.06
Temperature (C) 100.100.100.100.100.
I 816.818.818.819.819.
ReferenceSvetlova, Samusenko, et al., 1986Svetlova, Samusenko, et al., 1986Svetlova, Samusenko, et al., 1986Svetlova, Samusenko, et al., 1986Svetlova, Samusenko, et al., 1986
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase SE-30Apiezon LApolaneApiezon LApiezon L
Column length (m) 3.2.42.42.72.
Carrier gas ArHeHeN2 or HeN2
Substrate Gas Chrom Q (80-100 mesh)Chromosorb W AW-DMCSChromosorbChromosorb G, AWChromosorb W AW-DCMS
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 150.130.70.100.110.
I 820.837.786.6811.808.
ReferenceTiess, 1984Shatts, Avots, et al., 1977Riedo, Fritz, et al., 1976Zhuravleva, Kapustin, et al., 1976Bark and Wheatstone, 1974
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type PackedPackedPackedPackedPacked
Active phase Apiezon LApiezon LPMS-100PMS-100PMS-100
Column length (m) 2.2.3.3.3.
Carrier gas N2N2HeHeHe
Substrate Chromosorb W AW-DCMSChromosorb W AW-DCMSCelite 545 (44-60 mesh)Celite 545 (44-60 mesh)Celite 545 (44-60 mesh)
Column diameter (mm)      
Phase thickness (μm)      
Temperature (C) 130.150.130.150.180.
I 815.825.799.792.792.
ReferenceBark and Wheatstone, 1974Bark and Wheatstone, 1974Anderson, Jurel, et al., 1973Anderson, Jurel, et al., 1973Anderson, Jurel, et al., 1973
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Kovats' RI, non-polar column, isothermal, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E., Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups, J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0 . [all data]

Golovnya, Kuz'menko, et al., 2000
Golovnya, R.V.; Kuz'menko, T.E.; Krikunova, N.I., The influence of alkyl substituents on the chromatographic indicator of self-association of N-containing heterocyclic compounds, Russ. Chem. Bull. (Engl. Transl.), 2000, 49, 2, 321-324, https://doi.org/10.1007/BF02494681 . [all data]

Zhuravleva, 2000
Zhuravleva, I.L., Evaluation of the polarity and boiling points of nitrogen-containing heterocyclic compounds by gas chromatography, Russ. Chem. Bull. (Engl. Transl.), 2000, 49, 2, 325-328, https://doi.org/10.1007/BF02494682 . [all data]

Reddy, Dutoit, et al., 1992
Reddy, K.S.; Dutoit, J.-Cl.; Kovats, E. sz., Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups, J. Chromatogr., 1992, 609, 1-2, 229-259, https://doi.org/10.1016/0021-9673(92)80167-S . [all data]

Zhang, Li, et al., 1992
Zhang, M.J.; Li, S.D.; Chen, B.J., Compositional studies of high-temperature coal tar by GC/FTIR analysis of light oil fractions, Chromatographia, 1992, 33, 3/4, 138-146, https://doi.org/10.1007/BF02275894 . [all data]

Dutoit, 1991
Dutoit, J., Gas chromatographic retention behaviour of some solutes on structurally similar polar and non-polar stationary phases, J. Chromatogr., 1991, 555, 1-2, 191-204, https://doi.org/10.1016/S0021-9673(01)87179-X . [all data]

Samusenko and Golovnya, 1988
Samusenko, A.L.; Golovnya, R.V., Prediction of the retention indices of methyl pyridines and pyrazines in capillary gas chromatography based on the non-linear additivity of the sorption energy, Chromatographia, 1988, 25, 6, 531-535, https://doi.org/10.1007/BF02324828 . [all data]

Morishita, Morimoto, et al., 1986
Morishita, F.; Morimoto, S.; Kojima, T., Prediction of molecular structures of aza-arenes by retention indices and fluorescence spectra, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 11, 688-692, https://doi.org/10.1002/jhrc.1240091120 . [all data]

Samusenko, Svetlova, et al., 1986
Samusenko, A.L.; Svetlova, N.I.; Golovnya, R.V., Reproducible and durable glass capillary columns with hydrogenated apiezon-l and OV-101 for the analysis of polar substances, Zh. Anal. Khim., 1986, 61, 1, 127-133. [all data]

Svetlova, Samusenko, et al., 1986
Svetlova, N.I.; Samusenko, A.L.; Golovnya, R.V., Advantage of the universal equation over the linear equation for the calculation of retention parameters of homologous series in capillary chromatography, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 12, 737-740, https://doi.org/10.1002/jhrc.1240091205 . [all data]

Tiess, 1984
Tiess, D., Gaschromatographische Retentionsindices von 125 leicht- bis mittelflüchtigen organischen Substanzen toxikologisch-analytischer Relevanz auf SE-30, Wiss. Z. Wilhelm-Pieck-Univ. Rostock Math. Naturwiss. Reihe, 1984, 33, 6-9. [all data]

Shatts, Avots, et al., 1977
Shatts, V.D.; Avots, A.A.; Belikov, V.A., Retention indices of alkylpyridines, Zh. Anal. Khim., 1977, 32, 4, 631-638. [all data]

Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Chromatogr., 1976, 126, 63-83, https://doi.org/10.1016/S0021-9673(01)84063-2 . [all data]

Zhuravleva, Kapustin, et al., 1976
Zhuravleva, I.L.; Kapustin, Yu.P.; Golovnya, P.B., Retention indices of some isoaliphatic and heterocyclic nitrogenous bases, Zh. Anal. Khim., 1976, 31, 1378-1380. [all data]

Bark and Wheatstone, 1974
Bark, L.S.; Wheatstone, K.C., Studies in the relationship between molecular structure and chromatographic behaviour. Gas chromatographic study of monoalkylpyridines, J. Chromatogr., 1974, 92, 2, 281-289, https://doi.org/10.1016/S0021-9673(00)85738-6 . [all data]

Anderson, Jurel, et al., 1973
Anderson, A.; Jurel, S.; Shymanska, M.; Golender, L., Gas-liquid chromatography of some aliphatic and heterocyclic mono- and pollyfunctional amines. VII. Retention indices of amines in some polar and unpolar stationary phases, Latv. PSR Zinat. Akad. Vestis Kim. Ser., 1973, 1, 51-63. [all data]


Notes

Go To: Top, Kovats' RI, non-polar column, isothermal, References