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Pyridine, 3-methyl-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
RCD - Robert C. Dunbar

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Individual Reactions

C6H6N- + Hydrogen cation = Pyridine, 3-methyl-

By formula: C6H6N- + H+ = C6H7N

Quantity Value Units Method Reference Comment
Deltar1581. ± 13.kJ/molG+TSDePuy, Kass, et al., 1988gas phase; Acid: 3-methylpyridine. Comparable to EtOH.; B
Quantity Value Units Method Reference Comment
Deltar1552. ± 13.kJ/molIMRBDePuy, Kass, et al., 1988gas phase; Acid: 3-methylpyridine. Comparable to EtOH.; B

Lithium ion (1+) + Pyridine, 3-methyl- = (Lithium ion (1+) bullet Pyridine, 3-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar197. ± 15.kJ/molCIDTRodgers, 2001RCD

Sodium ion (1+) + Pyridine, 3-methyl- = (Sodium ion (1+) bullet Pyridine, 3-methyl-)

By formula: Na+ + C6H7N = (Na+ bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar133. ± 4.2kJ/molCIDTRodgers, 2001RCD

Potassium ion (1+) + Pyridine, 3-methyl- = (Potassium ion (1+) bullet Pyridine, 3-methyl-)

By formula: K+ + C6H7N = (K+ bullet C6H7N)

Quantity Value Units Method Reference Comment
Deltar100. ± 3.kJ/molCIDTRodgers, 2001RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

DePuy, Kass, et al., 1988
DePuy, C.H.; Kass, S.R.; Bean, G.P., Formation and Reactions of Heteroaromatic Anions in the Gas Phase, J. Org. Chem., 1988, 53, 19, 4427, https://doi.org/10.1021/jo00254a001 . [all data]

Rodgers, 2001
Rodgers, M.T., Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Methylpyridines, J. Phys. Chem. A, 2001, 105, 11, 2374, https://doi.org/10.1021/jp004055z . [all data]


Notes

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