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Cyclohexanol

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-290. ± 8.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
gas353.83J/mol*KN/AKabo G.J., 1988Other entropy value at 298.15 K obtained from calorimetric data is 327.69 J/mol*K [ Stull D.R., 1969].; GT

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
132.70298.15Kabo G.J., 1988Statistically calculated S(T) and Cp(T) values given in [ Thermodynamics Research Center, 1997] are 1-10 and 5-10 J/mol*K, respectively, lower than those of [ Kabo G.J., 1988].; GT
133.53300.
176.60400.
216.42500.
250.18600.
278.37700.
301.73800.
320.77900.
337.321000.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-352.0 ± 0.67kJ/molCacWiberg, Wasserman, et al., 1985Trifluoroacetolysis; ALS
Deltafliquid-350. ± 2.kJ/molCcbRabinovoch, Tel'noy, et al., 1962ALS
Deltafliquid-347.4 ± 2.2kJ/molCcbSellers and Sunner, 1962Reanalyzed by Cox and Pilcher, 1970, Original value = -348.2 kJ/mol; ALS
Deltafliquid-349.2 ± 0.2kJ/molCcbParks, Mosley, et al., 1950ALS
Deltafliquid-359.2kJ/molCcbKelley, 1929ALS
Quantity Value Units Method Reference Comment
Deltacliquid-3730. ± 20.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
liquid203.87J/mol*KN/AAdachi, Suga, et al., 1968DH
liquid199.6J/mol*KN/AKelley, 1929Average of values derived from measurements on both low and high temperature crystal forms down to 13 K, plus entropy of transition and fusion. Debye extrapolation below 13.5 K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
214.06298.15Mayer, Rachwalska, et al., 1990T = 170 to 320 K. Cp(liq) = -2223.2606 + 22.0059595T - 0.0691686793T2 + 0.0000763592T3 J/mol*K (298 to 320 K). Cp value caluculated from equation.; DH
209.99298.15Caceres-Alonso, Costas, et al., 1988DH
220.1298.Conti, Gianni, et al., 1976DH
212.297.95Petit and TerMinassian, 1974T = 297 to 428 K. Value is unsmoothed experimental datum.; DH
213.59300.Adachi, Suga, et al., 1968T = 14 to 320 K.; DH
202.5305.1Phillip, 1939DH
209.03298.15Kelley, 1929T = 13 to 300 K. Value is unsmoothed experimental datum.; DH
174.9290.Herz and Bloch, 1924DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil433. ± 3.KAVGN/AAverage of 20 out of 21 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus296. ± 5.KAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple299.09KN/AAdachi, Suga, et al., 1968, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple297.0KN/AKelley, 1929, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tc645. ± 20.KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Pc40.80barN/ASteele, Chirico, et al., 1997Uncertainty assigned by TRC = 1.50 bar; derived from fit of obs. vapor pressure; TRC
Pc44.01barN/AWilson, Wilson, et al., 1996Uncertainty assigned by TRC = 0.25 bar; TRC
Pc42.6 ± 0.5barN/AGude and Teja, 1995 
Pc42.60barN/AAmbrose and Ghiassee, 1987Uncertainty assigned by TRC = 0.50 bar; TRC
Pc37.4902barN/AGlaser and Ruland, 1957Uncertainty assigned by TRC = 1.5199 bar; TRC
Quantity Value Units Method Reference Comment
rhoc3.00mol/lN/ASteele, Chirico, et al., 1997Uncertainty assigned by TRC = 0.10 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap62. ± 1.kJ/molAVGN/AAverage of 10 out of 11 values; Individual data points

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
60.1337.N/ASteyer and Sundmacher, 2004Based on data from 322. - 433. K.; AC
49.8405.N/ASwiatek and Malanowski, 2002Based on data from 390. - 430. K.; AC
61.2 ± 0.6308.GSVerevkin, 1998Based on data from 288. - 328. K.; AC
55.0365.EBAmbrose and Ghiassee, 1987, 2Based on data from 350. - 456. K.; AC
59.9333.AStephenson and Malanowski, 1987Based on data from 318. - 434. K.; AC
62.7315.AStephenson and Malanowski, 1987Based on data from 300. - 434. K.; AC
49.3418.N/ACastellari, Francesconi, et al., 1984Based on data from 404. - 432. K.; AC
58.4318.N/ASipowska and Wieczorek, 1984Based on data from 303. - 373. K.; AC
60.4309.N/ACabani, Conti, et al., 1975Based on data from 299. - 319. K.; AC
52.6382.N/ANovák, Matous, et al., 1960Based on data from 367. - 433. K. See also Novák, Matous, et al., 1960, 2.; AC
54.8322.N/AThomson, 1946Based on data from 307. - 422. K.; AC
45.44431.7VMathews and Fehlandt, 1931ALS

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
366.88 - 433.93.08077777.363-182.037Novak, Matous, et al., 1960Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
60.7285.AStephenson and Malanowski, 1987Based on data from 272. - 298. K. See also Nitta and Seki, 1948.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
1.73298.2DSCSingh and Murthy, 2009AC
1.7297.N/APingel, Poser, et al., 1984See also Adachi, Suga, et al., 1968 and Domalski and Hearing, 1996.; AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
31.14263.5Domalski and Hearing, 1996CAL
5.72297.

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.3784220.9crystaline, IIIcrystaline, IIMayer, Rachwalska, et al., 1990DH
8.620244.5crystaline, IIIcrystaline, IMayer, Rachwalska, et al., 1990DH
8.662264.86crystaline, IIcrystaline, IMayer, Rachwalska, et al., 1990DH
1.806297.92crystaline, IliquidMayer, Rachwalska, et al., 1990DH
8.640244.8crystaline, IIIcrystaline, IAdachi, Suga, et al., 1968DH
8.827265.50crystaline, IIcrystaline, IAdachi, Suga, et al., 1968DH
1.783299.09crystaline, IliquidAdachi, Suga, et al., 1968DH
8.205263.5crystaline, IIcrystaline, IKelley, 1929Excess enthalpy over extrapolated heat capacity curves.; DH
1.699297.0crystaline, IliquidKelley, 1929Tm is 23.87°C from 16RIC/SHI.; DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
1.713220.9crystaline, IIIcrystaline, IIMayer, Rachwalska, et al., 1990DH
35.3244.5crystaline, IIIcrystaline, IMayer, Rachwalska, et al., 1990DH
32.70264.86crystaline, IIcrystaline, IMayer, Rachwalska, et al., 1990DH
6.06297.92crystaline, IliquidMayer, Rachwalska, et al., 1990DH
35.29244.8crystaline, IIIcrystaline, IAdachi, Suga, et al., 1968DH
33.25265.50crystaline, IIcrystaline, IAdachi, Suga, et al., 1968DH
5.96299.09crystaline, IliquidAdachi, Suga, et al., 1968DH
31.14263.5crystaline, IIcrystaline, IKelley, 1929Excess; DH
5.72297.0crystaline, IliquidKelley, 1929Tm; DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Cyclohexanone + Hydrogen = Cyclohexanol

By formula: C6H10O + H2 = C6H12O

Quantity Value Units Method Reference Comment
Deltar-75.86 ± 0.50kJ/molCmWiberg, Crocker, et al., 1991liquid phase
Deltar-63.51 ± 0.63kJ/molChydConn, Kistiakowsky, et al., 1939gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -64.5 ± 0.3 kJ/mol; At 355 K

Cyclohexanol + Acetic acid, trifluoro-, anhydride = Acetic acid, trifluoro-, cyclohexyl ester + Trifluoroacetic acid

By formula: C6H12O + C4F6O3 = C8H11F3O2 + C2HF3O2

Quantity Value Units Method Reference Comment
Deltar-90.06 ± 0.15kJ/molCacWiberg, Wasserman, et al., 1985liquid phase; Trifluoroacetolysis

Cyclohexanol = Cyclohexanone + Hydrogen

By formula: C6H12O = C6H10O + H2

Quantity Value Units Method Reference Comment
Deltar63.4 ± 2.3kJ/molEqkKabo, Yursha, et al., 1988gas phase; Dehydrogenation

Cyclohexanol + Acetone = Cyclohexanone + Isopropyl Alcohol

By formula: C6H12O + C3H6O = C6H10O + C3H8O

Quantity Value Units Method Reference Comment
Deltar9.9 ± 1.9kJ/molEqkFedoseenko, Yursha, et al., 1983gas phase; At 503 K

Cyclohexanol = Cyclohexane + Hydrogen

By formula: C6H12O = C6H12 + H2

Quantity Value Units Method Reference Comment
Deltar63.4 ± 2.3kJ/molEqkFedoseenko, Yursha, et al., 1983gas phase; At 502 K

Cyclohexanone + Cyclopentanol = Cyclohexanol + Cyclopentanone

By formula: C6H10O + C5H10O = C6H12O + C5H8O

Quantity Value Units Method Reference Comment
Deltar-11.6 ± 1.7kJ/molEqkFedoseenko, Yursha, et al., 1984gas phase

Cyclohexanone + Isopropyl Alcohol = Cyclohexanol + Acetone

By formula: C6H10O + C3H8O = C6H12O + C3H6O

Quantity Value Units Method Reference Comment
Deltar-9.9 ± 1.9kJ/molEqkKabo, Yursha, et al., 1988gas phase

Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/kg*bar)
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/kg*bar) d(ln(kH))/d(1/T) (K) Method Reference
170. VN/A

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
9.75EIRabbih and Selim, 1983LBLHLM
10.0 ± 0.2EIDerrick, Holmes, et al., 1975LLK
10.0EIWard and Williams, 1969RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H5O+11.5?EIWard and Williams, 1969RDSH
C5H7+10.9CH3+H2OEIWard and Williams, 1969RDSH
C6H10+10.4 ± 0.05H2OEIGreen, Bafus, et al., 1975LLK
C6H10+10.2 ± 0.2H2OEIDerrick, Holmes, et al., 1975LLK
C6H10+9.47H2OEILewis and Hamill, 1970RDSH
C6H10+10.4 ± 0.05H2OEIGreen, 1980Vertical value; LLK

IR Spectrum

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Data compiled by: Coblentz Society, Inc.

Data compiled by: Tanya L. Myers, Russell G. Tonkyn, Ashley M. Oeck, Tyler O. Danby, John S. Loring, Matthew S. Taubman, Stephen W. Sharpe, Jerome C. Birnbaum, and Timothy J. Johnson

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1998.
NIST MS number 291439

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedC78, Branched paraffin130.851.1Dallos, Sisak, et al., 2000He; Column length: 3.3 m
CapillaryOV-101150.921.1Cha and Lee, 1994Column length: 20. m; Column diameter: 0.5 mm
PackedC78, Branched paraffin130.852.9Reddy, Dutoit, et al., 1992Chromosorb G HP; Column length: 3.3 m
PackedApolane130.855.Dutoit, 1991Column length: 3.7 m
PackedSE-30150.885.Tiess, 1984Ar, Gas Chrom Q (80-100 mesh); Column length: 3. m
PackedSE-30100.891.Winskowski, 1983Gaschrom Q; Column length: 2. m
PackedApiezon L120.880.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedApiezon L160.900.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedApiezon L130.880.Bogoslovsky, Anvaer, et al., 1978 
PackedSE-30120.874.Pascal, Heintz, et al., 1974Column length: 2. m
PackedSE-30140.879.Pascal, Heintz, et al., 1974Column length: 2. m
PackedSE-30160.883.Pascal, Heintz, et al., 1974Column length: 2. m
PackedApiezon L130.878.Paris and Alexandre, 1972Chromosorb W AW
PackedApiezon L100.863.Brown, Chapman, et al., 1968N2, DCMS-treated Chromosorb W; Column length: 2.3 m
PackedApiezon L130.880.Wehrli and Kováts, 1959Celite; Column length: 2.25 m
PackedApiezon L190.898.Wehrli and Kováts, 1959Celite; Column length: 2.25 m

Kovats' RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-5MS869.Asuming, Beauchamp, et al., 200530. m/0.25 mm/0.25 «mu»m, He, 50. C @ 10. min, 3. K/min, 250. C @ 5. min
CapillaryCBP-1872.Shimadzu, 200325. m/0.2 mm/0.25 «mu»m, He, 50. C @ 5. min, 4. K/min; Tend: 200. C

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedCarbowax 20M120.1377.Pascal, Heintz, et al., 1974Column length: 2. m
PackedCarbowax 20M140.1386.Pascal, Heintz, et al., 1974Column length: 2. m
PackedCarbowax 20M160.1396.Pascal, Heintz, et al., 1974Column length: 2. m
CapillaryCarbowax 20M130.1430.Hedin, Thopson, et al., 1972N2; Column length: 15.24 m; Column diameter: 0.5 mm

Kovats' RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryCBP-201403.Shimadzu, 200325. m/0.2 mm/0.25 «mu»m, He, 50. C @ 5. min, 4. K/min; Tend: 200. C

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-5MS886.Pino, Mesa, et al., 200530. m/0.25 mm/0.25 «mu»m, He, 60. C @ 2. min, 4. K/min, 250. C @ 20. min
CapillaryCP Sil 5 CB856.Pino and Marbot, 200150. m/0.32 mm/0.4 «mu»m, He, 60. C @ 10. min, 3. K/min, 280. C @ 60. min
PackedSE-30885.Buchman, Cao, et al., 1984He, Chromosorb AW, 40. C @ 10. min, 10. K/min, 210. C @ 30. min; Column length: 3.05 m

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryMethyl Silicone881.Peng, Yang, et al., 1991Program: not specified
PackedSE-30881.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)

Van Den Dool and Kratz RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryAT-Wax1386.Pino and Marbot, 200160. m/0.32 mm/0.25 «mu»m, He, 65. C @ 10. min, 2. K/min, 250. C @ 60. min
CapillaryDB-Wax1410.Shimoda, Wu, et al., 199660. m/0.25 mm/0.25 «mu»m, He, 3. K/min; Tstart: 50. C; Tend: 230. C
CapillaryDB-Wax1375.Fröhlich, Duque, et al., 198930. m/0.25 mm/0.25 «mu»m, He, 50. C @ 3. min, 4. K/min; Tend: 250. C
CapillaryDB-Wax1376.Fröhlich, Duque, et al., 198930. m/0.25 mm/0.25 «mu»m, He, 50. C @ 3. min, 4. K/min; Tend: 250. C
PackedCarbowax 20M1414.Buchman, Cao, et al., 1984He, Supelcoport, 40. C @ 10. min, 10. K/min, 210. C @ 30. min; Column length: 3.05 m

Van Den Dool and Kratz RI, polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillarySupelcowax-101407.Bianchi, Careri, et al., 200730. m/0.25 mm/0.25 «mu»m, He; Program: 35C(8min) => 4C/min => 60C => 6C/min => 160C => 20C/min => 200C(1min)
CapillaryCarbowax 20M1408.Whitfield, Shea, et al., 1981Column length: 150. m; Column diameter: 0.75 mm; Program: not specified

Normal alkane RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
CapillaryPolydimethyl siloxane105.872.Tello, Lebron-Aguilar, et al., 2009 
CapillaryPolydimethyl siloxane75.866.Tello, Lebron-Aguilar, et al., 2009 
CapillaryPolydimethyl siloxane90.869.Tello, Lebron-Aguilar, et al., 2009 
CapillaryMethyl Silicone100.870.Lebrón-Aguilar, Quintanilla-López, et al., 2007 
CapillaryMethyl Silicone120.875.Lebrón-Aguilar, Quintanilla-López, et al., 2007 
CapillaryMethyl Silicone140.881.Lebrón-Aguilar, Quintanilla-López, et al., 2007 
CapillaryMethyl Silicone80.866.Lebrón-Aguilar, Quintanilla-López, et al., 2007 
CapillaryDB-160.861.Shimadzu, 2003, 260. m/0.32 mm/1. «mu»m, He

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryVF-5 MS889.Leffingwell and Alford, 201160. m/0.32 mm/0.25 «mu»m, Helium, 2. K/min, 260. C @ 28. min; Tstart: 30. C
CapillaryVF-5 MS891.Leffingwell and Alford, 201160. m/0.32 mm/0.25 «mu»m, Helium, 2. K/min, 260. C @ 28. min; Tstart: 30. C
CapillaryHP-5 MS880.Kim and Chung, 200930. m/0.25 mm/0.25 «mu»m, Helium, 35. C @ 5. min, 2. K/min, 195. C @ 30. min
CapillaryHP-5870.Wang, Yang, et al., 200630. m/0.25 mm/0.25 «mu»m, He, 60. C @ 2. min, 10. K/min, 250. C @ 10. min
CapillaryHP-5867.Figuérédo, Cabassu, et al., 200530. m/0.25 mm/0.25 «mu»m, He, 50. C @ 5. min, 5. K/min, 300. C @ 5. min
CapillaryDB-5849.Ruberto, Biondi, et al., 200230. m/0.25 mm/0.25 «mu»m, He, 2. K/min; Tstart: 60. C; Tend: 300. C
CapillaryOV-101880.Egolf and Jurs, 19932. K/min; Column length: 50. m; Column diameter: 0.22 mm; Tstart: 80. C; Tend: 200. C
CapillaryOV-101880.Anker, Jurs, et al., 19902. K/min; Column length: 50. m; Column diameter: 0.28 mm; Tstart: 80. C; Tend: 200. C
PackedApiezon L928.Dahlmann, Köser, et al., 1979Chromosorb G-AW-DMCS, 10. K/min; Column length: 2. m; Tstart: 25. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryHP-5876.Splivallo, Bossi, et al., 2007He; Program: 50C => 3C/min => 200C(10min) => 10C/min => 290C(10min)
CapillarySE-30880.Vinogradov, 2004Program: not specified
CapillaryOV-101880.Krings, Banavara, et al., 2003Program: not specified
CapillaryHP-5MS881.Ansorena, Gimeno, et al., 200130. m/0.25 mm/0.25 «mu»m, He; Program: 40C (10min) => 3C/min => 120C => 10C/min => 250C (5min)
CapillarySPB-1874.Flanagan, Streete, et al., 199760. m/0.53 mm/5. «mu»m, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillarySPB-1874.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 «mu»m, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C
CapillarySPB-1899.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 «mu»m, Helium; Program: not specified
CapillaryOV-101880.Shibamoto, 1987Program: not specified
CapillaryOV-1913.Ramsey and Flanagan, 1982Program: not specified

Normal alkane RI, polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryHP-Innowax1378.Puvipirom and Chaisei, 201215. m/0.32 mm/0.50 «mu»m, Helium, 3. K/min; Tstart: 40. C; Tend: 250. C
CapillaryCarbowax 20M1410.de la Fuente, Martinez-Castro, et al., 200550. m/0.25 mm/0.25 «mu»m, Helium, 40. C @ 2. min, 4. K/min, 190. C @ 30. min
CapillaryDB-Wax1403.Lee, Umano, et al., 200530. m/0.25 mm/0.25 «mu»m, He, 3. K/min, 180. C @ 40. min; Tstart: 50. C
CapillaryDB-Wax1403.Dregus and Engel, 200360. m/0.32 mm/0.25 «mu»m, H2, 40. C @ 5. min, 4. K/min, 230. C @ 25. min
CapillaryDB-Wax1403.Fu, Yoon, et al., 200230. m/0.25 mm/0.25 «mu»m, He, 40. C @ 5. min, 8. K/min, 250. C @ 5. min
CapillaryDB-Wax1393.Ito, Sugimoto, et al., 200260. C @ 4. min, 3. K/min; Column length: 60. m; Column diameter: 0.25 mm; Tend: 180. C
CapillaryDB-Wax1375.Parada, Duque, et al., 200030. m/0.25 mm/0.25 «mu»m, He, 50. C @ 3. min, 4. K/min, 240. C @ 10. min
CapillaryDB-Wax1392.Parada, Duque, et al., 200030. m/0.25 mm/0.25 «mu»m, He, 50. C @ 3. min, 4. K/min, 240. C @ 10. min
CapillaryCarbowax 20M1375.Egolf and Jurs, 19932. K/min; Column length: 80. m; Column diameter: 0.2 mm; Tstart: 70. C; Tend: 170. C
CapillaryCarbowax 20M1375.Anker, Jurs, et al., 19902. K/min; Column length: 80. m; Column diameter: 0.2 mm; Tstart: 70. C; Tend: 170. C

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryCarbowax 20M1375.Vinogradov, 2004Program: not specified
CapillaryCarbowax 20M1375.Krings, Banavara, et al., 2003Program: not specified
CapillaryNukol1394.López and Dufour, 2001N2; Column length: 25. m; Column diameter: 0.25 mm; Program: 45C(5min) => 20C/min => 100C(1min) => 3C/min => 190C(40min)
CapillaryDB-Wax1375.Miranda, Nogueira, et al., 200130. m/0.25 mm/0.25 «mu»m, He; Program: 25 0C (0.5 min) 50 K/min -> 50 0C 3.5 K/min -> 150 0C 7.5 K/min -> 240 0C
CapillaryDB-Wax1392.Peng, Yang, et al., 1991, 2Program: not specified
CapillaryDB-Wax1400.Peng, Yang, et al., 1991, 2Program: not specified
CapillaryCarbowax 20M1375.Shibamoto, 1987Program: not specified
CapillaryCarbowax 20M1375.Ramsey and Flanagan, 1982Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Gas Chromatography, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

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