Benzene, bromo-

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Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-5DB-1CP Sil 8 CBOV-1DB-5
Column length (m) 60.30.50. 30.
Carrier gas  He  N2
Substrate      
Column diameter (mm) 0.320.250.32 0.53
Phase thickness (μm) 1.0.25  1.5
Tstart (C) 40.40.60.35.50.
Tend (C) 230.325.220.300. 
Heat rate (K/min) 3.3.4.8.2.
Initial hold (min) 2. 5.  
Final hold (min) 10. 30.  
I 941.903.9926.909.5919.67
ReferenceEngel and Ratel, 2007Sun and Stremple, 2003Chevance and Farmer, 1999Gautzsch and Zinn, 1996Gerbino, Garbarino, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-1DB-1DB-1
Column length (m) 30.30.30.30.30.
Carrier gas N2N2N2N2N2
Substrate      
Column diameter (mm) 0.530.530.2350.2350.235
Phase thickness (μm) 1.51.50.250.250.25
Tstart (C) 50.50.100.100.50.
Tend (C)      
Heat rate (K/min) 2.2.10.5.10.
Initial hold (min)   0.0.0.
Final hold (min)      
I 921.35926.64927.927.918.
ReferenceGerbino, Garbarino, et al., 1996Gerbino, Garbarino, et al., 1996Gerbino and Castello, 1995Gerbino and Castello, 1995Gerbino and Castello, 1995
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryPacked
Active phase DB-1SE-30
Column length (m) 30.3.05
Carrier gas N2He
Substrate  Chromosorb AW
Column diameter (mm) 0.235 
Phase thickness (μm) 0.25 
Tstart (C) 50.40.
Tend (C)  210.
Heat rate (K/min) 5.10.
Initial hold (min) 0.10.
Final hold (min)  30.
I 915.930.
ReferenceGerbino and Castello, 1995Buchman, Cao, et al., 1984
Comment MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Engel and Ratel, 2007
Engel, E.; Ratel, J., Correction of the data generated by mass spectrometry analyses of biological tissues: Application to food authentication, J. Chromatogr. A, 2007, 1154, 1-2, 331-341, https://doi.org/10.1016/j.chroma.2007.02.012 . [all data]

Sun and Stremple, 2003
Sun, G.; Stremple, P., Retention index characterization of flavor, fragrance, and many other compounds on DB-1 and DB-XLB, 2003, retrieved from http://www.chem.agilent.com/cag/cabu/pdf/b-0279.pdf. [all data]

Chevance and Farmer, 1999
Chevance, F.F.V.; Farmer, L.J., Identification of major volatile odor compounds in frankfurters, J. Agric. Food Chem., 1999, 47, 12, 5151-5160, https://doi.org/10.1021/jf990515d . [all data]

Gautzsch and Zinn, 1996
Gautzsch, R.; Zinn, P., Use of incremental models to estimate the retention indexes of aromatic compounds, Chromatographia, 1996, 43, 3/4, 163-176, https://doi.org/10.1007/BF02292946 . [all data]

Gerbino, Garbarino, et al., 1996
Gerbino, T.C.; Garbarino, G.; Petit-Bon, P., Programmed temperature retention indices: calculation of linear programmed temperature retention indices of halogenated benzenes from isothermal data, Ann. Chim. (Rome), 1996, 86, 63-75. [all data]

Gerbino and Castello, 1995
Gerbino, T.C.; Castello, G., Prediction of programmed temperature retention indices on capillary columns of different polarities, J. Chromatogr. A, 1995, 699, 1-2, 161-171, https://doi.org/10.1016/0021-9673(95)00024-H . [all data]

Buchman, Cao, et al., 1984
Buchman, O.; Cao, G.-Y.; Peng, C.T., Structure assignment by retention index in gas-liquid radiochromatography of substituted cyclohexenes, J. Chromatogr., 1984, 312, 75-90, https://doi.org/10.1016/S0021-9673(01)92765-7 . [all data]


Notes

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