Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Benzene, bromo-

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid14.0kcal/molCmHolm, 1973Grignard Rx; ALS
Deltafliquid14.55 ± 0.99kcal/molCmChernick, Skinner, et al., 1956Reanalyzed by Cox and Pilcher, 1970, Original value = 14.1 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-743.75 ± 0.16kcal/molCcbSmith and Bjellerup, 1947ALS
Quantity Value Units Method Reference Comment
liquid5239.5cal/mol*KN/AMasi and Scott, 1975DH
liquid49.69cal/mol*KN/AStull, 1937Extrapolation below 91 K, 55.86 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
37.26303.15Reddy, 1986T = 303.15, 313.15 K.; DH
36.876298.15Masi and Scott, 1975T = 11 to 300 K.; DH
37.139298.1Stull, 1937T = 90 to 320 K.; DH
34.80302.6de Kolossowsky and Udowenko, 1934DH
34.80302.6Kolosovskii and Udovenko, 1934DH
30.50231.7Andrews and Haworth, 1928T = 101 to 232 K. Value is unsmoothed experimental datum.; DH
36.21293.2Williams and Daniels, 1925T = 20 to 80°C.; DH
36.09298.von Reis, 1881T = 291 to 444 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Holm, 1973
Holm, T., Thermochemistry of Grignard reagents. Enthalpies of formation of alkylmagnesium bromides and of alkyl bromides, J. Organomet. Chem., 1973, 56, 87-93. [all data]

Chernick, Skinner, et al., 1956
Chernick, C.L.; Skinner, H.A.; Wadso, I., Thermochemistry of metallic alkyls. Part 7.-The heat of formation of mercury diphenyl, and of mercury phenyl chloride, Trans. Faraday Soc., 1956, 52, 1088-1093. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Smith and Bjellerup, 1947
Smith, L.; Bjellerup, L., Neue Versuche mit beweglicher calorimetrischer Bombe, Acta Chem. Scand., 1947, 1, 566-570. [all data]

Masi and Scott, 1975
Masi, J.F.; Scott, R.B., Some thermodynamic properties of bromobenzene from 0 to 1500K, J. Res., 1975, NBS 79A, 619-628. [all data]

Stull, 1937
Stull, D.R., A semi-micro calorimeter for measuring heat capacities at low temperatures, J. Am. Chem. Soc., 1937, 59, 2726-2733. [all data]

Reddy, 1986
Reddy, K.S., Isentropic compressibilities of binary liquid mixtures at 303.15 and 313.15 K, J. Chem. Eng. Data, 1986, 31, 238-240. [all data]

de Kolossowsky and Udowenko, 1934
de Kolossowsky, N.; Udowenko, W.W., Determination des chaleurs specifiques des liquides, Compt. rend., 1934, 198, 1394-1395. [all data]

Kolosovskii and Udovenko, 1934
Kolosovskii, N.A.; Udovenko, W.W., Specific heat of liquids. II., Zhur. Obshchei Khim., 1934, 4, 1027-1033. [all data]

Andrews and Haworth, 1928
Andrews, D.H.; Haworth, E., An application of the rule of Dulong and Petit to molecules, J. Am. Chem. Soc., 1928, 50, 2998-3002. [all data]

Williams and Daniels, 1925
Williams, J.W.; Daniels, F., The specific heats of binary mixtures, J. Am. Chem. Soc., 1925, 47, 1490-1503. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, References